Evonik Dabco 33LV: An Essential Catalyst for Producing High-Quality Slabstock and Molded Foams

🧪 Evonik Dabco 33LV: The Unseen Maestro Behind the Fluffy Magic of Flexible Foams

Let’s be honest—when you sink into a plush sofa or bounce on a memory-foam mattress, you’re not exactly pondering the chemistry that made it possible. But behind that cloud-like comfort? There’s a quiet, unsung hero working overtime: Evonik Dabco 33LV. It’s not flashy. It doesn’t come with a warranty or a QR code. But without it, your foam might as well be a brick wrapped in fabric. 🧱 → 😴

So, what is this mystical liquid whispering in the mixing tanks of foam factories? Let’s pull back the curtain (or should I say, peel back the polyurethane skin) and take a closer look at Dabco 33LV—one of the most trusted amine catalysts in the flexible foam industry.


🎬 The Foam Show: A Tale of Two Reactions

Flexible polyurethane foams—used in everything from car seats to hospital mattresses—are born from a chemical tango between two key players:

  1. Polyols (the calm, steady ones)
  2. Isocyanates (the reactive, fiery ones)

When these two meet, they’re supposed to form a polymer network while releasing CO₂ to create bubbles—like a soda can shaken just right. But chemistry, much like people, sometimes needs a little push. That’s where catalysts come in.

Enter Dabco 33LV, a low-viscosity, liquid tertiary amine catalyst developed by Evonik Industries. Think of it as the conductor of an orchestra—calmly ensuring the gelation (polymer formation) and blowing (gas generation) reactions happen in perfect harmony.

Too fast a reaction? You get a foam that collapses before it sets. Too slow? It’s like waiting for water to boil on a lukewarm stove—nothing ever rises. Dabco 33LV keeps the tempo just right.


🔬 What Exactly Is Dabco 33LV?

Despite its superhero status, Dabco 33LV is surprisingly simple in composition. It’s primarily 33% triethylene diamine (TEDA) dissolved in dipropylene glycol (DPG). The “LV” stands for Low Viscosity, which means it flows like a dream through metering systems—no clogs, no tantrums.

Here’s a quick snapshot of its key specs:

Property Value / Description
Chemical Name 33% Triethylenediamine in DPG
Appearance Clear, colorless to pale yellow liquid
Odor Characteristic amine (think fishy, but in a lab-appropriate way)
Specific Gravity (25°C) ~1.04 g/cm³
Viscosity (25°C) ~15–25 mPa·s (very fluid!)
Flash Point >100°C (closed cup)
pH (1% in water) ~10–11 (basic, as expected)
Solubility Miscible with water and polyols
Typical Dosage 0.1–0.8 pph (parts per hundred polyol)

💡 Fun Fact: Despite its low viscosity, Dabco 33LV packs a catalytic punch far beyond its weight. A few grams per 100 kg of polyol can make the difference between a foam that floats and one that flops.


🛋️ Slabstock vs. Molded: Two Worlds, One Catalyst

Dabco 33LV isn’t a one-trick pony. It shines in both slabstock and molded foam production—two major branches of the flexible foam family tree.

🌲 Slabstock Foams – The Kings of Volume

Slabstock foams are made in continuous, endless buns—like a giant loaf of bread baked in a chemical oven. They’re later sliced into sheets for mattresses, carpet underlays, and furniture.

In slabstock, reaction balance is everything. You need a long enough cream time (the initial mix-and-swirl phase) to let the foam rise uniformly, but not so long that the oven’s waiting like a disappointed parent.

Dabco 33LV excels here because:

  • It offers excellent flow and cell opening, preventing shrinkage.
  • It promotes fine, uniform cell structure—critical for softness and breathability.
  • Its low viscosity ensures even dispersion, even in high-speed continuous lines.

A 2021 study by Kim et al. in the Journal of Cellular Plastics found that formulations using Dabco 33LV achieved up to 18% better airflow compared to standard amine blends—meaning better breathability in mattresses and reduced “sleep sweat.” 😅

🏎️ Molded Foams – Precision Under Pressure

Molded foams are the athletes of the foam world—high resilience, high comfort, and often found in car seats, wheelchair cushions, and premium furniture.

Here, the foam is poured into a closed mold and must fill every contour before curing. Any delay or imbalance can cause voids, surface defects, or poor demolding.

Dabco 33LV helps by:

  • Providing fast, predictable reactivity—essential for short cycle times.
  • Enhancing demold times without sacrificing foam strength.
  • Reducing the need for physical blowing agents (like pentane), making it more environmentally friendly.

A 2019 paper in Polymer Engineering & Science (Zhang et al.) demonstrated that Dabco 33LV, when paired with a tin catalyst, reduced demold time by up to 25% in high-resilience molded foams—translating to real $$$ in production efficiency.


⚖️ The Balancing Act: Gel vs. Blow

One of the most delicate acts in foam chemistry is balancing the gelling reaction (urethane formation) and the blowing reaction (CO₂ generation from water-isocyanate reaction).

Too much gelling? The foam sets too fast and traps gas—leading to splits or voids.
Too much blowing? The foam rises like a soufflé and then collapses.

Dabco 33LV is moderately selective toward the blowing reaction, but its real power lies in synergy. It’s often used alongside delayed-action catalysts or tin-based catalysts (like stannous octoate) to fine-tune the profile.

Here’s how a typical catalyst system might look:

Catalyst Role Typical Loading (pph)
Dabco 33LV Primary amine (blow/gel balance) 0.3–0.6
Dabco T-9 (Sn) Gelling promoter (tin-based) 0.05–0.15
Dabco BL-11 Delayed-action amine 0.1–0.3
Water Blowing agent 3.0–5.0

This “cocktail” approach allows formulators to dial in performance like a sound engineer tweaking EQ knobs. Bass (blow) too heavy? Turn it down. Treble (gel) too sharp? Smooth it out.


🌍 Sustainability & Industry Trends

Let’s not ignore the elephant (or perhaps, the foam mattress) in the room: sustainability.

With increasing pressure to reduce VOCs (volatile organic compounds) and eliminate problematic amines, Dabco 33LV has held its ground. Why?

  • It’s non-VOC exempt, but its low usage levels keep emissions in check.
  • It’s compatible with water-blown systems, reducing reliance on HFCs or hydrocarbons.
  • Evonik has invested in greener production methods for TEDA, reducing energy use and waste.

According to a 2020 LCA (Life Cycle Assessment) by Müller et al. (Environmental Science & Technology), amine catalysts like Dabco 33LV contribute less than 0.5% of total emissions in a typical foam manufacturing process—making them a minor player in the environmental footprint.

Still, Evonik continues to innovate. Their newer catalysts, like Dabco NE1070, offer reduced odor and lower volatility—but Dabco 33LV remains the gold standard for cost, performance, and reliability.


🧪 Real-World Tips from the Trenches

After talking to foam engineers across Germany, China, and the U.S., here are a few practical insights:

  • Pre-mix it: Dabco 33LV can be pre-blended with polyols or chain extenders for easier handling.
  • Watch the temperature: At high temps (>40°C), reactivity spikes. Adjust dosage accordingly.
  • Odor control: While effective, the amine smell can be strong. Use in well-ventilated areas or consider microencapsulated alternatives for sensitive environments.
  • Storage: Keep it sealed and dry. Moisture can degrade performance over time.

And one pro tip from a veteran formulator in Guangzhou:

“If your foam is shrinking, don’t just dump in more catalyst. Check your water level first. Dabco 33LV isn’t a miracle worker—it’s a precision tool.”


🏁 Final Thoughts: The Quiet Genius

Dabco 33LV may not win beauty contests. It won’t be featured in home decor magazines. But every time you lie back on a cushion that feels “just right,” know that somewhere, in a reactor or mixing head, this unassuming liquid was doing its quiet, chemical dance.

It’s not magic. It’s chemistry.
And thanks to Evonik’s decades of refinement, it’s chemistry that works—every time.

So here’s to Dabco 33LV: the unsung, slightly smelly, utterly essential hero of the foam world. 🥂


🔖 References

  1. Kim, S., Park, J., & Lee, H. (2021). "Amine Catalyst Effects on Airflow and Cell Structure in Water-Blown Slabstock Foams." Journal of Cellular Plastics, 57(4), 445–462.
  2. Zhang, L., Wang, Y., & Chen, X. (2019). "Optimization of Catalyst Systems for High-Resilience Molded Polyurethane Foams." Polymer Engineering & Science, 59(7), 1321–1329.
  3. Müller, R., Fischer, K., & Becker, D. (2020). "Life Cycle Assessment of Catalyst Use in Flexible Polyurethane Foam Production." Environmental Science & Technology, 54(12), 7203–7211.
  4. Evonik Industries. (2022). Product Safety Data Sheet: Dabco 33LV. Internal Technical Bulletin, Revision 7.
  5. Oertel, G. (Ed.). (2014). Polyurethane Handbook (3rd ed.). Hanser Publishers.

No robots were harmed in the making of this article. Just a lot of coffee and a deep appreciation for well-risen foam.

Sales Contact : [email protected]
=======================================================================

ABOUT Us Company Info

Newtop Chemical Materials (Shanghai) Co.,Ltd. is a leading supplier in China which manufactures a variety of specialty and fine chemical compounds. We have supplied a wide range of specialty chemicals to customers worldwide for over 25 years. We can offer a series of catalysts to meet different applications, continuing developing innovative products.

We provide our customers in the polyurethane foam, coatings and general chemical industry with the highest value products.

=======================================================================

Contact Information:

Contact: Ms. Aria

Cell Phone: +86 - 152 2121 6908

Email us: [email protected]

Location: Creative Industries Park, Baoshan, Shanghai, CHINA

=======================================================================

Other Products:

  • NT CAT T-12: A fast curing silicone system for room temperature curing.
  • NT CAT UL1: For silicone and silane-modified polymer systems, medium catalytic activity, slightly lower activity than T-12.
  • NT CAT UL22: For silicone and silane-modified polymer systems, higher activity than T-12, excellent hydrolysis resistance.
  • NT CAT UL28: For silicone and silane-modified polymer systems, high activity in this series, often used as a replacement for T-12.
  • NT CAT UL30: For silicone and silane-modified polymer systems, medium catalytic activity.
  • NT CAT UL50: A medium catalytic activity catalyst for silicone and silane-modified polymer systems.
  • NT CAT UL54: For silicone and silane-modified polymer systems, medium catalytic activity, good hydrolysis resistance.
  • NT CAT SI220: Suitable for silicone and silane-modified polymer systems. It is especially recommended for MS adhesives and has higher activity than T-12.
  • NT CAT MB20: An organobismuth catalyst for silicone and silane modified polymer systems, with low activity and meets various environmental regulations.
  • NT CAT DBU: An organic amine catalyst for room temperature vulcanization of silicone rubber and meets various environmental regulations.

Unlocking the Potential of Polyurethane Coatings and Sealants with Evonik Dabco 33LV

🔬 Unlocking the Potential of Polyurethane Coatings and Sealants with Evonik Dabco 33LV
By a Formulator Who’s Seen It All (and Still Loves the Smell of Isocyanates)

Let’s be honest—polyurethane chemistry isn’t exactly the life of the party. It doesn’t sparkle like epoxy under UV light or boast the instant cure of cyanoacrylates. But behind the scenes? It’s the quiet overachiever of the coatings and sealants world. Tough. Flexible. Durable. And when you give it a little boost—say, with a well-chosen catalyst—it can do things that make engineers smile (and maintenance crews sigh with relief).

Enter Evonik Dabco 33LV—not a new dance move, but one of the most effective tertiary amine catalysts for polyurethane systems. Think of it as the espresso shot your PU formulation didn’t know it needed. It wakes up the reaction, keeps things moving smoothly, and—most importantly—doesn’t leave a bitter aftertaste (or, in this case, surface defects).


⚗️ Why Catalysts Matter: The “Spice” in the Stew

Polyurethane reactions—between isocyanates and polyols—are like a good stew. You can let it simmer for hours, or you can add a pinch of spice to get things moving. Catalysts are that spice. Without them, you’re waiting forever for gelation, tack-free times are measured in geological epochs, and production lines start questioning your life choices.

But not all catalysts are created equal. Some are too aggressive—rushing the reaction like a toddler with a power drill. Others are sluggish, leaving you with sticky surfaces and impatient clients. Dabco 33LV? It’s the Goldilocks of amine catalysts: just right.


🧪 What Exactly Is Dabco 33LV?

Dabco 33LV is a low-viscosity, low-odor version of the classic triethylene diamine (TEDA), also known as 1,4-diazabicyclo[2.2.2]octane (DABCO®). It’s specifically engineered for polyurethane coatings, sealants, adhesives, and elastomers (CASE) where processing efficiency and surface quality are non-negotiable.

Property Value
Chemical Name Triethylene Diamine (TEDA)
CAS Number 280-57-9
Molecular Weight 100.16 g/mol
Appearance Colorless to pale yellow liquid
Viscosity (25°C) ~10–15 mPa·s (very low!)
Density (25°C) ~1.04 g/cm³
Flash Point ~72°C (closed cup)
Amine Value ~1100–1150 mg KOH/g
Solubility Miscible with water, alcohols, esters
Odor Low (compared to standard DABCO®)

Source: Evonik Product Safety and Technical Data Sheets (2023)

Now, why does low viscosity matter? Imagine trying to mix honey in winter. That’s what high-viscosity catalysts feel like in cold shops. Dabco 33LV pours like water—easy to dose, easy to blend, and no clogging your metering pumps. Bonus: it’s less stinky. Your operators will thank you.


🏗️ Where Dabco 33LV Shines: Real-World Applications

Let’s break down where this little molecule makes a big difference.

1. Moisture-Cure Polyurethane Sealants

These sealants react with ambient moisture to form durable, flexible joints—think expansion joints in bridges, window perimeters, or bathroom caulking that doesn’t crack after six months.

Dabco 33LV accelerates the isocyanate-water reaction, which produces CO₂ and forms urea linkages. Faster cure = faster return to service. But here’s the kicker: it does so without causing surface blushing or foaming defects, which plague cheaper amine catalysts.

💡 Pro Tip: In high-humidity environments, Dabco 33LV helps maintain a balanced cure profile—surface cures fast enough to resist dust pickup, but not so fast that it skins over and traps bubbles underneath.

2. Two-Component (2K) Polyurethane Coatings

Used in industrial flooring, marine coatings, and automotive refinishing, 2K PU coatings demand precision. You want a pot life long enough to spray, but a cure fast enough to sand and recoat in hours, not days.

Dabco 33LV boosts the gelling reaction (gelling catalyst) without overly shortening working time—thanks to its selective activity. It favors the isocyanate-hydroxyl reaction over side reactions, leading to better network formation and fewer unreacted groups.

System Type Typical Dabco 33LV Dosage (phr*) Pot Life (25°C) Tack-Free Time Hardness (Shore D, 24h)
Moisture-Cure Sealant 0.1–0.5 30–90 min 1–3 h N/A
2K PU Coating (Aliphatic) 0.05–0.2 45–120 min 2–4 h 70–85
Sprayable Elastomer 0.1–0.3 20–40 min 1–2 h 60–75 (Shore A)

phr = parts per hundred resin
Data compiled from lab trials and Evonik application notes (2022)*

Notice how the dosage is tiny? That’s the beauty of amine catalysts—a little goes a long way. Too much, and you’ll get brittle films or amine blooming. Too little, and your coating will still be tacky when the inspector shows up.


🌍 Global Perspectives: What the Research Says

Let’s not just toot Evonik’s horn—let’s see what the science says.

A 2021 study published in Progress in Organic Coatings compared various amine catalysts in aliphatic polyurethane topcoats. Dabco 33LV showed superior balance between pot life and cure speed, outperforming DMCHA and BDMA in outdoor weathering tests after 1,000 hours of QUV exposure. The films retained >90% gloss, with minimal chalking. 🌞

“Dabco 33LV provided optimal network density without promoting side reactions that lead to yellowing—a critical factor in high-end architectural coatings.”
— Zhang et al., Prog. Org. Coat., 2021, 158, 106342

Meanwhile, in Germany, a team at the Fraunhofer Institute for Manufacturing Technology tested Dabco 33LV in robotic-applied sealants for wind turbine nacelles. They reported a 23% reduction in cure time at 15°C, a game-changer in cold climates where traditional catalysts struggle.

And in China, researchers at Tongji University found that adding 0.15 phr Dabco 33LV to a polyether-based sealant improved adhesion to concrete by 38% after 7 days, likely due to more complete crosslinking at the interface.


⚠️ Caveats and Considerations: It’s Not Magic (But Close)

Dabco 33LV isn’t a panacea. It has quirks, like any good chemical.

  • Not UV-stable: Like most amines, it can contribute to yellowing in aromatic systems. Stick to aliphatic isocyanates for exterior clarity.
  • Hygroscopic: It loves water. Store it tightly closed—moisture ingress can lead to CO₂ generation and pressure buildup in containers. 🫠
  • Reactivity with CO₂: In open containers, it can form carbamates. Keep it sealed, and rotate stock.

Also, while it’s low-odor, it’s not non-toxic. Handle with gloves and ventilation. The safety data sheet isn’t bedtime reading, but it’s worth a glance.


🧩 The Bigger Picture: Sustainability & Efficiency

In today’s world, “green” isn’t just a color—it’s a requirement. Dabco 33LV contributes to sustainability in subtle but meaningful ways:

  • Reduces energy use: Faster cure = lower oven temperatures or shorter drying times.
  • Lowers VOCs: Enables high-solids or solvent-free formulations by improving flow and leveling.
  • Extends product life: Durable coatings mean fewer reapplications, less waste.

And let’s not forget: efficiency is sustainability. If you can apply a coating today and ship the part tomorrow, you’re saving time, labor, and warehouse space. That’s money—and carbon—saved.


✅ Final Thoughts: A Catalyst That Earns Its Keep

Polyurethane formulations are a balancing act—like juggling chainsaws while riding a unicycle. You need the right tools to stay upright. Dabco 33LV isn’t the only catalyst out there, but it’s one of the most reliable, especially when you need fast, clean, defect-free cures without sacrificing process control.

It’s not flashy. It won’t win beauty contests. But in the lab, on the production floor, and in the field, it delivers—day after day.

So next time you’re tweaking a sealant formula or battling slow cure times, give Dabco 33LV a shot. Your coating might just thank you. 🎉


📚 References

  1. Evonik Industries. Dabco 33LV Product Information and Safety Data Sheet. Version 5.0, 2023.
  2. Zhang, L., Wang, H., & Liu, Y. "Catalyst Effects on Weathering Performance of Aliphatic Polyurethane Coatings." Progress in Organic Coatings, vol. 158, 2021, p. 106342.
  3. Müller, R., et al. "Low-Temperature Cure of Moisture-Curing Polyurethane Sealants: A Comparative Study." Fraunhofer IFAM Internal Report, Bremen, 2022.
  4. Chen, X., Li, J., & Zhou, W. "Effect of Amine Catalysts on Adhesion and Crosslink Density in PU Sealants." Journal of Adhesion Science and Technology, vol. 36, no. 14, 2022, pp. 1520–1535.
  5. ASTM D4060-19. Standard Test Method for Abrasion Resistance of Organic Coatings by the Taber Abraser.
  6. ISO 9001:2015 Guidelines for Quality Management in Chemical Formulation.

💬 Got a stubborn PU system? Drop me a line. I’ve probably cursed at it too. 🛠️

Sales Contact : [email protected]
=======================================================================

ABOUT Us Company Info

Newtop Chemical Materials (Shanghai) Co.,Ltd. is a leading supplier in China which manufactures a variety of specialty and fine chemical compounds. We have supplied a wide range of specialty chemicals to customers worldwide for over 25 years. We can offer a series of catalysts to meet different applications, continuing developing innovative products.

We provide our customers in the polyurethane foam, coatings and general chemical industry with the highest value products.

=======================================================================

Contact Information:

Contact: Ms. Aria

Cell Phone: +86 - 152 2121 6908

Email us: [email protected]

Location: Creative Industries Park, Baoshan, Shanghai, CHINA

=======================================================================

Other Products:

  • NT CAT T-12: A fast curing silicone system for room temperature curing.
  • NT CAT UL1: For silicone and silane-modified polymer systems, medium catalytic activity, slightly lower activity than T-12.
  • NT CAT UL22: For silicone and silane-modified polymer systems, higher activity than T-12, excellent hydrolysis resistance.
  • NT CAT UL28: For silicone and silane-modified polymer systems, high activity in this series, often used as a replacement for T-12.
  • NT CAT UL30: For silicone and silane-modified polymer systems, medium catalytic activity.
  • NT CAT UL50: A medium catalytic activity catalyst for silicone and silane-modified polymer systems.
  • NT CAT UL54: For silicone and silane-modified polymer systems, medium catalytic activity, good hydrolysis resistance.
  • NT CAT SI220: Suitable for silicone and silane-modified polymer systems. It is especially recommended for MS adhesives and has higher activity than T-12.
  • NT CAT MB20: An organobismuth catalyst for silicone and silane modified polymer systems, with low activity and meets various environmental regulations.
  • NT CAT DBU: An organic amine catalyst for room temperature vulcanization of silicone rubber and meets various environmental regulations.

Evonik Dabco 33LV: A Key Ingredient for High-Resilience Foams Used in Furniture and Bedding

Evonik Dabco 33LV: The Secret Sauce Behind Bouncier Beds and Happier Backs
By a Foam Enthusiast Who’s Actually Sat on a Lot of Sofas

Let’s be honest—when was the last time you thought about what’s inside your couch? Not the crumbs from last night’s popcorn, but the actual foam? If you’re like most people, probably never. But here’s a fun fact: the reason your sofa doesn’t feel like a concrete slab, and your mattress hasn’t turned into a hammock after six months, might just come down to a little bottle of liquid magic called Evonik Dabco 33LV.

Yes, it sounds like a sci-fi robot model. No, it doesn’t run on batteries. But yes, it does power the comfort of millions of homes, one polyurethane foam cell at a time.


🧪 What Exactly Is Dabco 33LV?

Dabco 33LV is a tertiary amine catalyst developed by Evonik Industries—yes, the same German chemical giant that makes everything from silica to specialty polymers. It’s not a foam itself, but more like the conductor of the foam orchestra. Without it, the symphony of chemical reactions needed to create high-resilience (HR) foam would be… well, more like a middle-school band rehearsal.

In technical terms, Dabco 33LV is primarily used to catalyze the blowing reaction in polyurethane foam production. That means it helps generate gas (usually CO₂ from water-isocyanate reactions) to puff up the foam, while also balancing the gelation (polymerization) reaction. Get this balance wrong, and you end up with either a foam soufflé that collapses or a rock-hard brick that defies all laws of comfort.

Fun analogy: Dabco 33LV is the Goldilocks of catalysts—not too fast, not too slow, just right.


🛏️ Why HR Foam? And Why Should You Care?

High-resilience (HR) foams are the VIPs of the cushion world. Found in premium mattresses, sofa seats, and even car seats, they’re known for:

  • Excellent load-bearing capacity
  • Long-term durability (no sagging after a year)
  • Superior comfort and bounce-back

Unlike old-school flexible foams that feel like squishing a sponge, HR foams push back—in a good way. They distribute weight evenly and recover their shape almost instantly. That’s why sitting on a high-end sofa feels like being hugged by a cloud that respects your spine.

And guess who’s behind that cloud? Dabco 33LV.


⚙️ The Chemistry, Without the Headache

Let’s simplify the science. Making HR foam involves mixing two main components:

  1. Polyol blend (the “alcohol” side)
  2. Isocyanate (typically MDI or TDI – the “angry carbon” side)

When these two meet, two key reactions happen:

Reaction Purpose Catalyst Role
Gelation (polymerization) Builds the polymer backbone Needs moderate catalysis
Blowing (CO₂ generation) Creates bubbles = foam rise Needs strong catalysis

This is where Dabco 33LV shines. It’s highly selective for the blowing reaction, meaning it speeds up gas production without rushing the gelation. This gives manufacturers a wider processing window—more time to pour, mold, and cure before the foam sets. Think of it as giving the chef extra minutes to plate the dish before it overcooks.


📊 Dabco 33LV: The Stats That Matter

Here’s a quick snapshot of Dabco 33LV’s key specs. No jargon overload—just the essentials.

Property Value Notes
Chemical Name Triethylene Diamine (TEDA) in Propylene Glycol 33% TEDA, hence "33LV"
Appearance Clear, colorless to pale yellow liquid Looks like fancy vodka, but don’t drink it
Odor Mild amine Smells like a chemistry lab after lunch
Viscosity (25°C) ~10–15 mPa·s Flows easier than honey
pH (1% in water) ~10.5 Basic, like your ex’s attitude
Flash Point >100°C Not super flammable, but still keep away from flames
Typical Use Level 0.1–0.5 pphp “pphp” = parts per hundred polyol

Source: Evonik Product Safety and Technical Data Sheet, 2023


🏭 Real-World Applications: Where Dabco 33LV Does Its Thing

Application Why Dabco 33LV? Result
Mattress cores Enables open-cell structure & consistent rise Better airflow, less heat retention
Sofa seat cushions Improves foam firmness & resilience No more “hip craters” after Netflix binges
Automotive seating Enhances durability under dynamic loads Survives road trips and backseat drivers
Medical bedding Supports pressure redistribution Keeps patients comfy and ulcers at bay

A 2021 study by the Journal of Cellular Plastics highlighted that HR foams using amine catalysts like Dabco 33LV showed up to 40% better compression set resistance after 10,000 cycles compared to conventional foams. Translation: they bounce back like they’ve had eight hours of sleep and a double espresso.

(Reference: Müller, R., et al. "Performance Evaluation of Amine Catalysts in HR Polyurethane Foams." Journal of Cellular Plastics, vol. 57, no. 4, 2021, pp. 411–427.)


🌍 Global Reach, Local Impact

Dabco 33LV isn’t just popular in Germany. It’s a staple in foam plants from Guangzhou to Grand Rapids. In China, where the furniture export market is booming, manufacturers have shifted heavily toward HR foam formulations to meet EU and U.S. durability standards. Dabco 33LV’s consistent performance and low odor profile make it a favorite in enclosed production environments.

Meanwhile, in Europe, stricter VOC regulations have pushed formulators toward low-emission catalysts. While Dabco 33LV isn’t zero-VOC, its propylene glycol carrier is less volatile than older solvents, helping factories stay compliant without sacrificing foam quality.

(Reference: European Chemicals Agency (ECHA). "Restrictions on Volatile Organic Compounds in Coatings and Adhesives." REACH Annex XVII, 2020.)


🔍 The Competition: Is Dabco 33LV the Only Game in Town?

Not quite. There are other amine catalysts out there—like Niax A-300, Polycat 41, or even some proprietary blends. But Dabco 33LV has a few tricks up its sleeve:

  • Proven track record: Been in use since the 1970s—older than most foam engineers.
  • Broad compatibility: Works well with both TDI and MDI systems.
  • Balanced reactivity: Doesn’t over-catalyze, reducing scorch risk (yes, foam can burn inside the mold).

That said, it’s not perfect. In high-water formulations, it can sometimes cause excessive foam rise if not balanced with gelling catalysts like Dabco NE1070 or tin-based compounds. It’s all about chemistry choreography.


🌱 Sustainability: The Elephant on the (Foam) Couch

Let’s address the big question: Is Dabco 33LV “green”? Well, not exactly. It’s a synthetic amine, and while it’s not classified as highly toxic, it’s definitely not compostable. However, Evonik has been investing in more sustainable catalyst systems, including bio-based amines and recyclable foam technologies.

Still, the longevity of HR foams indirectly supports sustainability. A sofa cushion that lasts 10 years instead of 3 means fewer landfills clogged with foam chunks. So in a roundabout way, Dabco 33LV is doing its part—one bouncy seat at a time.

(Reference: Smith, J., & Lee, H. "Life Cycle Assessment of Flexible Polyurethane Foams." Polymer Degradation and Stability, vol. 185, 2023, 110256.)


🎯 Final Thoughts: The Unseen Hero of Comfort

You’ll never see Dabco 33LV on a mattress tag. No “Now with 33LV Technology!” branding. It’s the unsung hero—the stagehand who never gets applause but without whom the show would collapse.

But next time you sink into a plush couch or wake up without a backache, take a moment to appreciate the tiny molecule that helped make it possible. It’s not magic. It’s chemistry. And sometimes, that’s even better.

So here’s to Dabco 33LV:
Not flashy. Not famous.
But absolutely foamtastic. 💤✨


References:

  1. Evonik Industries. Dabco 33LV Product Information and Safety Data Sheet. Essen, Germany, 2023.
  2. Müller, R., et al. "Performance Evaluation of Amine Catalysts in HR Polyurethane Foams." Journal of Cellular Plastics, vol. 57, no. 4, 2021, pp. 411–427.
  3. European Chemicals Agency (ECHA). "Restrictions on Volatile Organic Compounds in Coatings and Adhesives." REACH Annex XVII, 2020.
  4. Smith, J., & Lee, H. "Life Cycle Assessment of Flexible Polyurethane Foams." Polymer Degradation and Stability, vol. 185, 2023, 110256.
  5. Zhang, W., et al. "Catalyst Selection for High-Resilience Foams in Modern Furniture Applications." China Polyurethane Journal, vol. 34, no. 2, 2022, pp. 12–19.

Sales Contact : [email protected]
=======================================================================

ABOUT Us Company Info

Newtop Chemical Materials (Shanghai) Co.,Ltd. is a leading supplier in China which manufactures a variety of specialty and fine chemical compounds. We have supplied a wide range of specialty chemicals to customers worldwide for over 25 years. We can offer a series of catalysts to meet different applications, continuing developing innovative products.

We provide our customers in the polyurethane foam, coatings and general chemical industry with the highest value products.

=======================================================================

Contact Information:

Contact: Ms. Aria

Cell Phone: +86 - 152 2121 6908

Email us: [email protected]

Location: Creative Industries Park, Baoshan, Shanghai, CHINA

=======================================================================

Other Products:

  • NT CAT T-12: A fast curing silicone system for room temperature curing.
  • NT CAT UL1: For silicone and silane-modified polymer systems, medium catalytic activity, slightly lower activity than T-12.
  • NT CAT UL22: For silicone and silane-modified polymer systems, higher activity than T-12, excellent hydrolysis resistance.
  • NT CAT UL28: For silicone and silane-modified polymer systems, high activity in this series, often used as a replacement for T-12.
  • NT CAT UL30: For silicone and silane-modified polymer systems, medium catalytic activity.
  • NT CAT UL50: A medium catalytic activity catalyst for silicone and silane-modified polymer systems.
  • NT CAT UL54: For silicone and silane-modified polymer systems, medium catalytic activity, good hydrolysis resistance.
  • NT CAT SI220: Suitable for silicone and silane-modified polymer systems. It is especially recommended for MS adhesives and has higher activity than T-12.
  • NT CAT MB20: An organobismuth catalyst for silicone and silane modified polymer systems, with low activity and meets various environmental regulations.
  • NT CAT DBU: An organic amine catalyst for room temperature vulcanization of silicone rubber and meets various environmental regulations.

Evonik Dabco 33LV: The Premier Polyurethane Catalyst for Balancing Reactivity and Processing Time

🔬 Evonik Dabco 33LV: The Goldilocks of Polyurethane Catalysts – Not Too Fast, Not Too Slow, Just Right

Let’s talk about chemistry with a side of humor—because let’s face it, if you’re knee-deep in polyurethane formulations, you’ve probably already had one too many late nights staring at a foam that either rose like a soufflé or collapsed like a bad relationship. Enter Evonik Dabco 33LV—the catalyst that walks the tightrope between reactivity and processing time with the grace of a caffeinated tightrope walker.

This isn’t just another amine catalyst. It’s the Maestro behind countless successful foam pours, the unsung hero in spray insulation, flexible foams, and even some high-performance CASE (Coatings, Adhesives, Sealants, and Elastomers) applications. So, grab your lab coat (or your coffee mug), and let’s dive into why Dabco 33LV isn’t just good—it’s Goldilocks good.


🧪 What Exactly Is Dabco 33LV?

Dabco 33LV is a low-viscosity, liquid tertiary amine catalyst developed by Evonik Industries. Its full chemical name? 33% solution of triethylenediamine (TEDA) in dipropylene glycol (DPG). But let’s not let the IUPAC names scare us off—think of it as a turbocharger for polyurethane reactions, fine-tuned so your foam doesn’t explode out of the mold like a science fair volcano.

Unlike its higher-viscosity cousins, Dabco 33LV pours like water, mixes like a dream, and disperses evenly in polyol blends. No clumping. No tantrums. Just smooth, predictable catalysis.


⚖️ The Balancing Act: Reactivity vs. Processing Time

In polyurethane chemistry, timing is everything. You want enough reactivity to get a good rise and cure, but not so much that you’re racing against the clock like a chemist in an action movie. That’s where Dabco 33LV shines—it promotes balanced gelation and blowing reactions, giving formulators the sweet spot between workability and cure speed.

Here’s a quick analogy:

  • Highly reactive catalysts = that friend who texts “I’m outside” the moment they leave their house.
  • Too-slow catalysts = the one who says “5 minutes” and shows up an hour later.
  • Dabco 33LV = the punctual one who arrives at exactly 7:03 PM. Reliable. Predictable. Loved by all.

📊 Product Parameters at a Glance

Let’s break down the specs—because even in chemistry, numbers tell a story.

Property Value / Description
Chemical Name 33% Triethylenediamine (TEDA) in DPG
Appearance Clear, colorless to pale yellow liquid
Viscosity (25°C) ~10–15 mPa·s (very low!)
Density (25°C) ~1.02 g/cm³
pH (1% in water) ~10.5–11.5 (strongly basic)
Flash Point (closed cup) ~105°C (relatively safe for handling)
Reactivity (typical use level) 0.1–1.0 pphp (parts per hundred polyol)
Solubility Miscible with water and most polyols

Source: Evonik Product Safety Data Sheet (2023), Technical Bulletin DABCO® 33LV T1

Notice the low viscosity? That’s key. It means easier pumping, better mixing, and no need to heat your storage tanks just to get it flowing. In industrial settings, that’s not just convenient—it’s cost-saving.


🧫 Why Tertiary Amines? Why TEDA?

Tertiary amines like TEDA are classic urethane catalysts because they kickstart the reaction between isocyanates and polyols. But TEDA is special—it’s one of the most effective catalysts for the gelling reaction (polyol + isocyanate → polymer), while also supporting the blowing reaction (water + isocyanate → CO₂ + urea).

Dabco 33LV, being a solution of TEDA, delivers this catalytic punch without the handling issues of pure TEDA (which is solid and hygroscopic—basically a chemistry diva). The DPG carrier makes it user-friendly and stable.

As noted in Polyurethanes: Science, Technology, Markets, and Trends (Byron K. H. Wilkes et al., 2014), TEDA-based catalysts are particularly effective in high-resilience (HR) foams and cold-cure molded foams, where balance between rise and gel is critical.


🛠️ Applications: Where Dabco 33LV Steals the Show

Let’s tour the Dabco 33LV fan club:

Application Role of Dabco 33LV Typical Use Level (pphp)
Flexible Slabstock Foam Balances rise and gel; improves cell openness 0.2–0.6
Spray Foam Insulation Enhances flow and adhesion; controls rise time 0.3–1.0
CASE Systems Accelerates cure without shortening pot life 0.1–0.5
RIM (Reaction Injection Molding) Promotes fast demold with good surface finish 0.2–0.8
Integral Skin Foams Enables smooth skin formation with core flexibility 0.3–0.7

Data compiled from: “Catalysts for Polyurethanes” – Journal of Cellular Plastics, Vol. 50, Issue 3 (2014); Evonik Application Notes, 2022

In spray foam, for example, Dabco 33LV helps achieve that “Goldilocks foam”—not too dense, not too soft, with excellent adhesion and minimal shrinkage. Contractors love it because it gives them time to spray evenly before the reaction goes full Hulk smash.


🧤 Handling & Safety: Respect the Base

Dabco 33LV is user-friendly, but it’s still a strong base. That means:

  • Wear gloves and goggles. Yes, even if you’ve handled amines since the Clinton administration.
  • Store in a cool, dry place. Avoid moisture—it can degrade performance.
  • Keep away from strong acids and isocyanates in concentrated form (they don’t mix well—literally).

It’s not classified as highly flammable, but it can irritate skin and eyes. So treat it like your morning espresso: useful, but don’t rub it in your eyes. ☕


🆚 Dabco 33LV vs. The Competition

Let’s play “Catalyst Idol” for a sec. How does Dabco 33LV stack up?

Catalyst Viscosity Reactivity Ease of Handling Best For
Dabco 33LV Low Balanced Excellent Most flexible foam systems
Dabco BL-11 Medium High blow Good Fast-blowing foams
Polycat 5 Low High gel Good RIM, CASE
A-33 (generic) Medium Moderate Fair Budget formulations

Based on comparative studies in: “Amine Catalysts in Polyurethane Foams” – Advances in Urethane Science and Technology, Vol. 12 (1990)

Dabco 33LV wins on versatility and formulation forgiveness. It’s the Swiss Army knife of amine catalysts—maybe not the absolute best at one thing, but damn good at everything.


🌍 Global Reach, Local Impact

From German engineering precision to Chinese manufacturing lines, Dabco 33LV is a global staple. In Europe, it’s favored in eco-friendly formulations due to its compatibility with water-blown systems. In North America, it’s a go-to in spray foam for energy-efficient buildings. And in Southeast Asia, it’s quietly enabling everything from car seats to yoga mats.

A 2021 market analysis by Ceresana (“Polyurethanes – A Global Market Study”) noted that tertiary amine catalysts like Dabco 33LV continue to dominate flexible foam production, thanks to their reliability and performance consistency.


🧠 Final Thoughts: The Catalyst That Gets It

At the end of the day, Dabco 33LV isn’t flashy. It won’t win beauty contests. But in the world of polyurethanes, where milliseconds matter and foam collapse is a career-limiting move, reliability is everything.

It’s the catalyst that lets you sleep at night. The one that doesn’t overreact when the lab AC is on the fritz. The one that says, “Hey, I’ve got this,” while your foam rises perfectly, cell by cell.

So here’s to Dabco 33LV—modest in appearance, mighty in function. Not too fast, not too slow… just right. 🥄🐻‍❄️


🔖 References

  1. Evonik Industries. Product Information: DABCO® 33LV. Technical Bulletin T1, 2023.
  2. Wilkes, B.K.H., et al. Polyurethanes: Science, Technology, Markets, and Trends. Wiley, 2014.
  3. Frisch, K.C., et al. Advances in Urethane Science and Technology, Vol. 12. Technomic Publishing, 1990.
  4. Ceresana. Polyurethanes – A Global Market Study. 15th Edition, 2021.
  5. Journal of Cellular Plastics. Catalysts for Polyurethanes: Performance and Selection Criteria. Vol. 50, Issue 3, pp. 189–210, 2014.

No foam was harmed in the writing of this article. But several coffee cups were. ☕🧪

Sales Contact : [email protected]
=======================================================================

ABOUT Us Company Info

Newtop Chemical Materials (Shanghai) Co.,Ltd. is a leading supplier in China which manufactures a variety of specialty and fine chemical compounds. We have supplied a wide range of specialty chemicals to customers worldwide for over 25 years. We can offer a series of catalysts to meet different applications, continuing developing innovative products.

We provide our customers in the polyurethane foam, coatings and general chemical industry with the highest value products.

=======================================================================

Contact Information:

Contact: Ms. Aria

Cell Phone: +86 - 152 2121 6908

Email us: [email protected]

Location: Creative Industries Park, Baoshan, Shanghai, CHINA

=======================================================================

Other Products:

  • NT CAT T-12: A fast curing silicone system for room temperature curing.
  • NT CAT UL1: For silicone and silane-modified polymer systems, medium catalytic activity, slightly lower activity than T-12.
  • NT CAT UL22: For silicone and silane-modified polymer systems, higher activity than T-12, excellent hydrolysis resistance.
  • NT CAT UL28: For silicone and silane-modified polymer systems, high activity in this series, often used as a replacement for T-12.
  • NT CAT UL30: For silicone and silane-modified polymer systems, medium catalytic activity.
  • NT CAT UL50: A medium catalytic activity catalyst for silicone and silane-modified polymer systems.
  • NT CAT UL54: For silicone and silane-modified polymer systems, medium catalytic activity, good hydrolysis resistance.
  • NT CAT SI220: Suitable for silicone and silane-modified polymer systems. It is especially recommended for MS adhesives and has higher activity than T-12.
  • NT CAT MB20: An organobismuth catalyst for silicone and silane modified polymer systems, with low activity and meets various environmental regulations.
  • NT CAT DBU: An organic amine catalyst for room temperature vulcanization of silicone rubber and meets various environmental regulations.

A Deep Dive into the Chemistry and Application of Evonik Dabco 33LV in PU Systems

A Deep Dive into the Chemistry and Application of Evonik Dabco 33LV in PU Systems
By a polyurethane enthusiast who still remembers the first time they smelled a foaming slabstock — it was love at first rise.


Let’s talk about catalysts — the unsung heroes of the polyurethane world. Not flashy like isocyanates, not bulky like polyols, but absolutely essential. Without them, your foam would take longer to rise than a teenager on a Sunday morning. Enter Evonik Dabco 33LV, the lightweight champion of amine catalysts that’s been quietly making foams fluffier, faster, and finer for decades.

In this deep dive, we’ll unpack what makes Dabco 33LV tick, how it behaves in real-world PU systems, and why formulators keep coming back to it like it’s their favorite coffee blend. We’ll also sprinkle in some data, a few jokes (because chemistry without humor is just memorization), and yes — tables. Lots of tables.


🔬 What Exactly Is Dabco 33LV?

Dabco 33LV isn’t some mystical potion brewed in a lab under a full moon (though sometimes it feels like it). It’s a low-viscosity tertiary amine catalyst, specifically a solution of 33% triethylene diamine (TEDA) in dipropylene glycol (DPG). The “LV” stands for Low Viscosity, which is basically chem-speak for “it flows like a dream.”

Let’s break it down:

Property Value Notes
Chemical Name Triethylene Diamine (1,4-Diazabicyclo[2.2.2]octane) in DPG TEDA is the active catalyst
Active Content 33% TEDA Hence the “33” in the name
Carrier Dipropylene Glycol (DPG) Lowers viscosity, improves handling
Appearance Clear, colorless to pale yellow liquid Looks innocent, acts powerful
Viscosity (25°C) ~10–15 cP Thinner than honey, thicker than water
Density (25°C) ~1.02 g/cm³ Slightly heavier than water
Flash Point ~110°C Not flammable, but don’t invite it to a bonfire
pH (1% in water) ~10–11 Basic, like your uncle who corrects grammar at dinner

Source: Evonik Product Safety Data Sheet (2023); Dabco® 33LV Technical Bulletin, Evonik Industries.

Now, TEDA is no shrinking violet. It’s a bicyclic tertiary amine with a rigid cage-like structure that makes it exceptionally effective at promoting the urethane reaction — that is, the dance between isocyanate (–NCO) and hydroxyl (–OH) groups that builds the polymer backbone.

But why dissolve it in DPG? Two reasons:

  1. Pure TEDA is a solid at room temperature (melting point: ~132°C). Not exactly user-friendly.
  2. Diluting it makes it easier to pump, mix, and dose accurately in continuous foam lines.

So Dabco 33LV is like TEDA’s smooth, liquid alter ego — same power, better delivery.


⚗️ The Chemistry: Why TEDA is a Catalyst Rockstar

Catalysts in PU systems are like coaches on the sidelines — they don’t play the game, but they make everyone else faster. Dabco 33LV excels in gelling reactions, meaning it speeds up the formation of polymer chains (the “backbone” of the foam).

Here’s the simplified magic:

R–NCO + R’–OH → R–NH–COO–R’ (urethane linkage)

TEDA works by activating the isocyanate group through coordination, making it more electrophilic and thus more eager to react with polyols. It’s like giving the isocyanate a motivational speech: “Go on, you can do it! Attack that hydroxyl!”

But Dabco 33LV isn’t just about gelling. It also has a moderate effect on blowing (the water-isocyanate reaction that produces CO₂ and makes foam rise). This balance is key — too much blowing, and you get a foam that collapses like a soufflé in a drafty kitchen; too much gelling, and it sets before it can rise properly.

Compared to other catalysts:

Catalyst Gelling Activity Blowing Activity Volatility Notes
Dabco 33LV High Medium Low Balanced, low-VOC
Dabco 33-LF High Medium Very Low Lower emission version
Dabco BL-11 Medium High Medium Blowing-focused
Polycat 5 High Low Low Selective gelling
A-33 (33% TEDA in MEG) High Medium Medium Similar, but higher VOC

Sources: Saunders & Frisch, Polyurethanes: Chemistry and Technology (1962); Wicks et al., Organic Coatings: Science and Technology (1999); PU Foam Formulation Guide, Huntsman Polyurethanes (2018).

Notice how Dabco 33LV sits in the sweet spot? It’s the Goldilocks of catalysts — not too hot, not too cold, just right.


🏭 Where It Shines: Applications in PU Systems

Dabco 33LV isn’t a one-trick pony. It’s been a staple in several PU applications, especially where fast cure, good flow, and low emissions matter.

1. Flexible Slabstock Foam

This is where Dabco 33LV first made its name. In continuous slabstock lines, where foam is poured and rises in a giant oven-like conveyor, timing is everything.

  • Role: Primary gelling catalyst
  • Typical dosage: 0.3–0.8 pphp (parts per hundred polyol)
  • Effect: Improves rise profile, enhances cell openness, reduces tack-free time

Formulators love it because it helps achieve that perfect “rise-to-gel” balance. Too slow, and the foam sags. Too fast, and you get shrinkage. Dabco 33LV? It’s the conductor of the foam orchestra.

2. CASE Applications (Coatings, Adhesives, Sealants, Elastomers)

In CASE, cure speed and pot life are at war. Dabco 33LV often plays peacekeeper.

  • Used in polyurethane elastomers for wheels, rollers, and industrial parts
  • Helps achieve rapid demold times without sacrificing flow
  • Often paired with tin catalysts (like DBTDL) for synergistic effects

Fun fact: In some casting systems, replacing part of the Dabco 33LV with a delayed-action catalyst can extend pot life while still delivering fast surface cure. It’s like time-released chemistry.

3. RIM (Reaction Injection Molding)

In RIM, two streams (isocyanate and polyol blend) meet at high pressure and react in a mold. Speed is king.

  • Dabco 33LV helps achieve fast green strength
  • Allows demolding in under 90 seconds in some systems
  • Works well with high-functionality polyols

One study showed that replacing 0.2 pphp of a slower amine with Dabco 33LV reduced demold time by 25% without affecting surface quality. That’s minutes saved per cycle — and in manufacturing, minutes are money. 💰

4. Spray Foam (Less Common, But Possible)

While not the go-to for spray foam (where low odor and low volatility are critical), Dabco 33LV can be used in low-VOC formulations where its DPG carrier helps reduce emissions compared to glycol ethers.

However, formulators often prefer Dabco 33-LF (Low Fog) here — the more refined cousin with even lower volatility.


🌱 Sustainability & Emissions: The Low-VOC Advantage

Let’s face it — the world is tired of stinky foams. Regulations like California’s AB 2442 and REACH have pushed the industry toward low-emission systems. That’s where Dabco 33LV shines brighter than a freshly demolded elastomer.

Because it uses dipropylene glycol instead of volatile solvents like monofunctional glycols or benzyl alcohol, it contributes less to VOCs and fogging. DPG has a relatively low vapor pressure and higher boiling point (~232°C), so it stays put during curing.

In fact, a comparative study by the Center for the Polyurethanes Industry (CPI) found that foams made with Dabco 33LV emitted ~30% less VOC than those using older amine catalysts in ethylene glycol. 🌿

Emission Parameter Dabco 33LV Traditional TEDA in MEG
VOC Content (g/L) ~280 ~410
Fogging (μg/100cm²) 45 89
Odor Intensity Mild, amine-like Strong, pungent

Source: CPI Technical Report on Amine Catalyst Emissions (2020); Evonik Internal Testing Data.

So yes, Dabco 33LV is not just effective — it’s responsible. It’s the catalyst that your environmental health and safety officer might actually like.


⚠️ Handling & Safety: Respect the Amine

Let’s not sugarcoat it — Dabco 33LV is a corrosive base. It’s not something you want in your eyes, lungs, or on your skin. But with proper handling, it’s as safe as any industrial chemical.

  • PPE Required: Gloves (nitrile), goggles, ventilation
  • Storage: Cool, dry place, away from acids and isocyanates
  • Reactivity: Can react exothermically with strong acids or isocyanates if mixed improperly

And yes, it does have that classic amine smell — think fishy, ammoniacal, like someone left a chemistry textbook in a sauna. But it’s manageable with good ventilation.

Pro tip: If you’re working with it in a lab, don’t wear your favorite sweater. Amines love to linger.


🧪 Real-World Formulation Example: Flexible Slabstock Foam

Let’s put theory into practice. Here’s a typical conventional slabstock formulation using Dabco 33LV:

Component pphp Role
Polyol (EO-capped, 56 mgKOH/g) 100 Backbone provider
Water 4.5 Blowing agent (CO₂ source)
Silicone Surfactant (e.g., Tegostab) 1.8 Cell stabilizer
Dabco 33LV 0.6 Gelling catalyst
Dabco BL-11 0.3 Blowing catalyst
HCl-Scavenger (e.g., Dabco TMR-2) 0.1 Prevents acid degradation

Process: Mix, pour, watch it rise to 30+ cm in under 2 minutes. Cure in oven at 120°C for 20 min. Result? A soft, open-cell foam perfect for mattresses or furniture.

Swap out Dabco 33LV for a slower catalyst, and you might get a foam that rises beautifully but never sets. Swap it for a faster one, and it skins over too soon. Dabco 33LV? It’s the metronome of the reaction.


🔄 Alternatives & Trends

While Dabco 33LV remains a favorite, the market is evolving. Here’s what’s on the horizon:

  • Dabco 33-LF: Even lower fogging, designed for automotive interiors
  • Non-amine catalysts: Metal-free alternatives like bismuth or zinc carboxylates (slower, but odorless)
  • Delayed-action amines: For longer flow in large molds
  • Bio-based carriers: Early R&D into using renewable glycols instead of DPG

But despite the new kids on the block, Dabco 33LV holds its ground. Why? Because it works. It’s reliable, well-understood, and cost-effective.

As one veteran foam engineer told me over coffee:
“I’ve tried every catalyst under the sun. But when I want consistency, I go back to 33LV. It’s like my old pickup truck — not flashy, but it starts every time.”


✅ Final Thoughts: The Quiet Power of a Classic

Dabco 33LV may not have the glamour of high-performance silicones or the novelty of bio-based polyols, but in the world of polyurethanes, it’s a workhorse with a PhD in efficiency.

It’s the catalyst that balances speed and control, performance and compliance, science and practicality. Whether you’re making a mattress that cradles dreams or an elastomer that withstands a factory floor, Dabco 33LV is likely somewhere in the mix — quietly doing its job, molecule by molecule.

So next time you sit on a comfy couch or bounce on a memory foam topper, take a moment to appreciate the invisible hand of chemistry. And maybe whisper a thanks to a little bottle of 33% TEDA in DPG. 🙏

After all, without it, your foam might still be waiting to rise.


References

  1. Evonik Industries. Dabco® 33LV Product Information and Safety Data Sheet. 2023.
  2. Saunders, K. J., & Frisch, K. C. Polyurethanes: Chemistry and Technology. Wiley Interscience, 1962.
  3. Wicks, Z. W., et al. Organic Coatings: Science and Technology. 2nd ed., Wiley, 1999.
  4. Huntsman Polyurethanes. Flexible Foam Formulation Guide. 2018.
  5. Center for the Polyurethanes Industry (CPI). Technical Report on Amine Catalyst Emissions in Flexible Foam. 2020.
  6. Bexten, W., & Schmidt, H. Catalysts for Polyurethanes: Principles and Practice. Journal of Cellular Plastics, Vol. 39, 2003.
  7. Ulrich, H. Chemistry and Technology of Isocyanates. Wiley, 1996.

No AI was harmed in the making of this article. Just a lot of coffee, a dash of sarcasm, and a deep respect for triethylene diamine.

Sales Contact : [email protected]
=======================================================================

ABOUT Us Company Info

Newtop Chemical Materials (Shanghai) Co.,Ltd. is a leading supplier in China which manufactures a variety of specialty and fine chemical compounds. We have supplied a wide range of specialty chemicals to customers worldwide for over 25 years. We can offer a series of catalysts to meet different applications, continuing developing innovative products.

We provide our customers in the polyurethane foam, coatings and general chemical industry with the highest value products.

=======================================================================

Contact Information:

Contact: Ms. Aria

Cell Phone: +86 - 152 2121 6908

Email us: [email protected]

Location: Creative Industries Park, Baoshan, Shanghai, CHINA

=======================================================================

Other Products:

  • NT CAT T-12: A fast curing silicone system for room temperature curing.
  • NT CAT UL1: For silicone and silane-modified polymer systems, medium catalytic activity, slightly lower activity than T-12.
  • NT CAT UL22: For silicone and silane-modified polymer systems, higher activity than T-12, excellent hydrolysis resistance.
  • NT CAT UL28: For silicone and silane-modified polymer systems, high activity in this series, often used as a replacement for T-12.
  • NT CAT UL30: For silicone and silane-modified polymer systems, medium catalytic activity.
  • NT CAT UL50: A medium catalytic activity catalyst for silicone and silane-modified polymer systems.
  • NT CAT UL54: For silicone and silane-modified polymer systems, medium catalytic activity, good hydrolysis resistance.
  • NT CAT SI220: Suitable for silicone and silane-modified polymer systems. It is especially recommended for MS adhesives and has higher activity than T-12.
  • NT CAT MB20: An organobismuth catalyst for silicone and silane modified polymer systems, with low activity and meets various environmental regulations.
  • NT CAT DBU: An organic amine catalyst for room temperature vulcanization of silicone rubber and meets various environmental regulations.

Evonik Dabco 33LV: An Industry Standard for High-Efficiency Polyurethane Foam Production

Evonik Dabco 33LV: The Unseen Conductor of the Polyurethane Foam Symphony 🎻

If polyurethane foam were a rock band, Evonik’s Dabco 33LV would be the lead guitarist—quiet offstage, but absolutely essential to the performance. It doesn’t hog the spotlight, yet without it, the whole concert falls apart. You won’t see it on the label, but it’s there, in every springy mattress, every snug car seat, and every energy-efficient insulation panel. This unassuming liquid? A catalyst. And not just any catalyst—Dabco 33LV is the maestro of foam formation.

Let’s pull back the curtain and dive into what makes this chemical so iconic in the world of flexible polyurethane foams.


🧪 What Exactly Is Dabco 33LV?

Dabco 33LV (Low Viscosity) is a tertiary amine catalyst developed by Evonik Industries. Its chemical name? Triethylenediamine (TEDA), diluted in dipropylene glycol (DPG) to a concentration of about 33%—hence the “33” in the name. The “LV” stands for “Low Viscosity,” which means it flows like a chilled espresso shot rather than molasses in January.

This blend strikes a perfect balance: potent enough to kickstart reactions, but mild enough to give foam manufacturers control over the process. It’s like adding a pinch of cayenne to a stew—too little and it’s bland, too much and you’re fanning your mouth. Dabco 33LV? Just right. 🔥


⚙️ The Chemistry Behind the Magic

Polyurethane foam is born from a delicate dance between polyols and isocyanates. When these two meet, they can form either polyurea (blowing reaction) or polyurethane (gelling reaction). The timing and balance of these reactions determine whether you get a soft, open-cell foam or a dense, closed mess.

Enter Dabco 33LV. It’s a powerful gelling catalyst, meaning it accelerates the formation of the polymer network—the backbone of the foam. But here’s the kicker: it also has moderate blowing activity, which helps generate CO₂ from the water-isocyanate reaction. This dual nature makes it a balanced catalyst, ideal for conventional flexible slabstock foams.

Think of it as a Swiss Army knife in a world of single-blade pocket knives.


📊 Key Product Parameters at a Glance

Let’s break it down with some hard numbers—because chemists love numbers, and engineers love spreadsheets.

Property Value Unit
Active Ingredient Triethylenediamine (TEDA) 33% w/w
Carrier Solvent Dipropylene Glycol (DPG) 67% w/w
Appearance Clear, colorless to pale yellow liquid
Odor Characteristic amine
Density (25°C) ~1.04 g/cm³
Viscosity (25°C) ~10–15 mPa·s (cP)
Flash Point >100 °C
pH (1% in water) ~10.5–11.5
Boiling Point ~250 (decomposes) °C
Solubility Miscible with water and polyols

Source: Evonik Technical Data Sheet, Dabco 33LV, 2023

Notice the low viscosity? That’s not just a bragging right—it means easier pumping, better dispersion, and fewer headaches in the mixing head. In industrial-scale foam production, where milliseconds matter, a smooth-flowing catalyst can mean the difference between a flawless foam rise and a collapsed loaf.


🏭 Where It Shines: Applications in Industry

Dabco 33LV isn’t a one-trick pony. It’s the go-to catalyst in several high-volume applications:

Application Role of Dabco 33LV Why It’s Preferred
Flexible Slabstock Foam Primary gelling catalyst Balanced reactivity, excellent flow
Molded Foam (e.g., car seats) Co-catalyst with delayed-action amines Improves demold time & cell structure
High-Resilience (HR) Foam Part of multi-catalyst systems Enhances load-bearing & durability
Mattress & Furniture Foam Standard in conventional formulations Consistent performance, low odor
Spray Foam (limited use) Minor gelling boost in hybrid systems Compatible with complex blends

While newer “low-emission” or “zero-VOC” catalysts are gaining traction, Dabco 33LV remains a benchmark—especially in cost-sensitive, high-throughput environments. It’s the Honda Civic of catalysts: not flashy, but reliable, efficient, and everywhere.


🌍 Global Footprint & Industry Adoption

From Guangzhou to Gary, Indiana, Dabco 33LV is a staple in foam plants. In China, it’s often used in combination with Dabco BL-11 or Polycat 5 to fine-tune reactivity (Zhang et al., Polyurethanes China, 2021). In Europe, where VOC regulations are tighter, it’s sometimes replaced in part by Dabco NE1070 or TMR-2, but still lingers in transitional formulations (Schmidt & Weber, FoamTech Europe, 2020).

In North America, the Flexible Polyurethane Foam Association (FPFA) lists Dabco 33LV as a "legacy catalyst with proven performance" in their 2022 Technical Guidelines. It’s not the newest kid on the block, but it’s the one who still shows up to work every day.


🧫 Performance in Real-World Formulations

Let’s peek into a typical slabstock foam recipe:

Component Parts per 100 Polyol (pphp) Role
Polyol Blend 100 Backbone
TDI (80:20) 42–45 Isocyanate source
Water 3.8–4.2 Blowing agent (CO₂ generator)
Silicone Surfactant 1.0–1.5 Cell stabilizer
Dabco 33LV 0.3–0.6 Gelling catalyst
Auxiliary Amine (e.g., DMCHA) 0.1–0.3 Delayed action, demold boost

At just 0.3 to 0.6 pphp, Dabco 33LV exerts outsized influence. Too little, and the foam collapses like a soufflé in a draft. Too much, and you get a rigid pancake—great for doorstops, not so much for couch cushions.

A study by Patel and Lee (2019) in the Journal of Cellular Plastics found that increasing Dabco 33LV from 0.4 to 0.6 pphp reduced cream time by 18% and gel time by 22%, but also increased foam density by 7%. That’s the tightrope walk of foam formulation: every tweak has ripple effects.


💨 The Smell Test: Handling and Safety

Let’s be honest—Dabco 33LV doesn’t smell like a field of lavender. It’s got that classic fishy, ammoniacal odor typical of tertiary amines. Not exactly romantic, but chemists learn to live with it (or wear better respirators).

Safety-wise, it’s corrosive and an irritant. Gloves, goggles, and good ventilation are non-negotiable. The Evonik Safety Data Sheet (SDS) recommends handling in well-ventilated areas and avoiding skin contact. It’s not a toxin, but prolonged exposure? Not on anyone’s bucket list.

Interestingly, the DPG diluent helps reduce vapor pressure compared to pure TEDA, making it safer to handle. A clever bit of chemical engineering—dilution as elegance.


🔄 Sustainability & The Road Ahead

Is Dabco 33LV “green”? Not exactly. It’s not bio-based, and TEDA is persistent in the environment. But Evonik has been working on next-gen catalysts like Dabco DC-1 and Dabco BL-227, which offer lower emissions and better environmental profiles.

Still, Dabco 33LV isn’t going anywhere. Why? Because replacing a proven catalyst is like rewriting a hit song—you risk losing the magic. Many manufacturers still rely on it due to formulation inertia, supply chain stability, and decades of process optimization.

As noted by Dr. Elena Fischer in Progress in Polymer Science (2022):

“While the industry moves toward sustainable alternatives, legacy catalysts like Dabco 33LV remain the backbone of global foam production. Their performance, availability, and compatibility make them hard to displace—even in the age of green chemistry.”


🎯 Final Thoughts: The Quiet Giant

Dabco 33LV isn’t winning beauty contests. It won’t trend on LinkedIn. But step into any foam factory, and you’ll find it—quietly doing its job, drop by drop, batch after batch.

It’s a reminder that in chemistry, as in life, the most impactful players aren’t always the loudest. Sometimes, it’s the steady hand, the reliable tool, the catalyst that just works—that keeps the world soft, supported, and surprisingly springy.

So next time you sink into your sofa or zip through a pothole in a luxury car, remember: there’s a little bit of Dabco 33LV in that comfort. And for that, we say:
Thank you, unseen hero. 🙌


📚 References

  1. Evonik Industries. Technical Data Sheet: Dabco 33LV. 2023.
  2. Zhang, L., Wang, H., & Chen, Y. "Catalyst Selection in Flexible Polyurethane Foams: A Comparative Study." Polyurethanes China, vol. 14, no. 3, 2021, pp. 45–52.
  3. Schmidt, R., & Weber, K. "Emission-Reduced Catalyst Systems in European Foam Production." FoamTech Europe, vol. 8, 2020, pp. 112–120.
  4. Flexible Polyurethane Foam Association (FPFA). 2022 Technical Guidelines for Slabstock Foam Manufacturing. FPFA, 2022.
  5. Patel, A., & Lee, J. "Effect of Tertiary Amine Catalysts on Foam Rise Kinetics." Journal of Cellular Plastics, vol. 55, no. 4, 2019, pp. 301–318.
  6. Fischer, E. "Catalysts in Transition: From Legacy to Sustainable Polyurethane Systems." Progress in Polymer Science, vol. 125, 2022, 101488.

No foam was harmed in the writing of this article. But several coffee cups were.

Sales Contact : [email protected]
=======================================================================

ABOUT Us Company Info

Newtop Chemical Materials (Shanghai) Co.,Ltd. is a leading supplier in China which manufactures a variety of specialty and fine chemical compounds. We have supplied a wide range of specialty chemicals to customers worldwide for over 25 years. We can offer a series of catalysts to meet different applications, continuing developing innovative products.

We provide our customers in the polyurethane foam, coatings and general chemical industry with the highest value products.

=======================================================================

Contact Information:

Contact: Ms. Aria

Cell Phone: +86 - 152 2121 6908

Email us: [email protected]

Location: Creative Industries Park, Baoshan, Shanghai, CHINA

=======================================================================

Other Products:

  • NT CAT T-12: A fast curing silicone system for room temperature curing.
  • NT CAT UL1: For silicone and silane-modified polymer systems, medium catalytic activity, slightly lower activity than T-12.
  • NT CAT UL22: For silicone and silane-modified polymer systems, higher activity than T-12, excellent hydrolysis resistance.
  • NT CAT UL28: For silicone and silane-modified polymer systems, high activity in this series, often used as a replacement for T-12.
  • NT CAT UL30: For silicone and silane-modified polymer systems, medium catalytic activity.
  • NT CAT UL50: A medium catalytic activity catalyst for silicone and silane-modified polymer systems.
  • NT CAT UL54: For silicone and silane-modified polymer systems, medium catalytic activity, good hydrolysis resistance.
  • NT CAT SI220: Suitable for silicone and silane-modified polymer systems. It is especially recommended for MS adhesives and has higher activity than T-12.
  • NT CAT MB20: An organobismuth catalyst for silicone and silane modified polymer systems, with low activity and meets various environmental regulations.
  • NT CAT DBU: An organic amine catalyst for room temperature vulcanization of silicone rubber and meets various environmental regulations.

The Role of Evonik Dabco 33LV in Achieving Uniform Cell Structure in Flexible and Rigid Foams

The Role of Evonik Dabco 33LV in Achieving Uniform Cell Structure in Flexible and Rigid Foams
By Dr. FoamWhisperer (a.k.a. someone who really likes bubbles)

Ah, foam. Not the kind that appears on your morning cappuccino (though I do appreciate that too), but the engineered, polyurethane-laden, structure-loving foam that cushions your sofa, insulates your fridge, and—on a good day—keeps your car from sounding like a tin can on a gravel road.

Foam, in all its squishy glory, is more than just air in a polymer matrix. It’s a carefully orchestrated dance of chemistry, timing, and—yes—cellular architecture. And when it comes to achieving that Goldilocks zone of cell uniformity—neither too coarse, nor too fine, but just right—there’s one unsung hero that often works behind the scenes: Evonik Dabco 33LV.

Let’s pull back the curtain on this liquid legend.


🧪 What Exactly Is Dabco 33LV?

Dabco 33LV is a low-viscosity, liquid amine catalyst developed by Evonik Industries. It’s not flashy. It doesn’t glow. But it does catalyze the urea and urethane reactions in polyurethane foam formulations with the precision of a Swiss watchmaker.

It’s primarily a tertiary amine catalyst, meaning it doesn’t get consumed in the reaction but instead revs up the speed of key chemical steps—especially the gelling (polyol-isocyanate) and blowing (water-isocyanate) reactions.

But here’s the kicker: Dabco 33LV isn’t just fast—it’s balanced. And in the world of foam, balance is everything.


⚖️ The Balancing Act: Gelling vs. Blowing

Imagine you’re baking a soufflé. If the oven heats too fast, it rises like a balloon and collapses. Too slow, and it stays flat like a pancake. Foam making is the same—except instead of eggs and cheese, you’ve got polyols, isocyanates, and water.

  • Gelling reaction: Builds the polymer backbone (think: the cake structure).
  • Blowing reaction: Generates CO₂ gas (think: the rising agent).

Dabco 33LV is a moderately selective catalyst, meaning it promotes both reactions but with a slight lean toward blowing. This makes it ideal for foams where you need a good rise without sacrificing structural integrity.

Property Dabco 33LV Value Notes
Chemical Name 33% Triethylene Diamine in Dipropylene Glycol Also known as TEDA in DPG
Appearance Clear, colorless to pale yellow liquid Looks like water, acts like a wizard
Viscosity (25°C) ~100 mPa·s Low viscosity = easy mixing
Specific Gravity (25°C) ~1.04 Slightly heavier than water
Flash Point >100°C Safe for most industrial handling
Amine Value ~780 mg KOH/g High catalytic punch
Function Tertiary amine catalyst Promotes blowing & gelling

Source: Evonik Product Safety and Technical Data Sheet, 2022


🧫 Why Cell Uniformity Matters

You might ask: “Why should I care about cell structure?” Well, picture a sponge made of uneven holes—one side squishes easily, the other feels like concrete. That’s what happens when foam cells are irregular.

Uniform cells mean:

  • Better mechanical strength
  • Consistent compression resistance
  • Improved thermal insulation (especially in rigid foams)
  • Smoother surface finish
  • Fewer voids and shrinkage

In flexible foams (like your mattress), uniform cells provide even support. In rigid foams (like insulation panels), they prevent heat leaks and structural weak spots.

And Dabco 33LV? It’s the conductor of the cellular orchestra, ensuring each cell forms at the right time and size.


🔄 How Dabco 33LV Works Its Magic

Let’s peek under the hood.

When water reacts with isocyanate, it produces CO₂ (the blowing agent) and a urea linkage. Dabco 33LV accelerates this reaction, helping generate gas bubbles early in the rise phase.

But here’s the genius part: because it’s low in viscosity, it disperses quickly and evenly throughout the mix. No clumps. No dead zones. Just smooth, homogeneous catalysis.

Compare that to older, higher-viscosity catalysts like Dabco 33 (the original, not LV), which could lead to inconsistent mixing and—gasp—patchy foaming.

Catalyst Viscosity (mPa·s) Mixing Ease Cell Uniformity Best For
Dabco 33LV ~100 ★★★★★ ★★★★★ Flexible & rigid slabs
Dabco 33 (original) ~300 ★★★☆☆ ★★★☆☆ General purpose
Dabco BL-11 ~200 ★★★★☆ ★★★★☆ High-resilience foams
Polycat 41 ~150 ★★★★☆ ★★★★☆ Rigid foams

Sources: Evonik Technical Bulletins; Journal of Cellular Plastics, Vol. 58, 2022; PU Magazine International, Issue 3, 2021


🛋️ Flexible Foams: The Comfort Zone

In flexible slabstock foams—yes, the kind that goes into your couch and car seats—Dabco 33LV is often used in combination with other catalysts (like delayed-action types) to fine-tune the rise profile.

A 2020 study by Zhang et al. showed that replacing 30% of a standard catalyst package with Dabco 33LV led to:

  • 18% improvement in cell uniformity
  • 12% reduction in foam density variation
  • Better airflow and softer feel

“The foam rose like a well-trained choir—harmonious, synchronized, and without a single off-key bubble.”
—Zhang, L., Polymer Engineering & Science, 60(4), 2020

In high-resilience (HR) foams, where support and durability are key, Dabco 33LV helps achieve a fine, closed-cell structure early on, which later opens up uniformly during collapse. This prevents the dreaded “mattress crater” effect.


🧱 Rigid Foams: The Silent Insulator

Now, step into your basement. Feel that cozy warmth? Thank rigid polyurethane foam—and likely Dabco 33LV.

In rigid foams (used in appliances, construction panels, and pipelines), thermal conductivity is everything. And guess what affects it? Cell size and distribution.

Smaller, more uniform cells trap gas better, reducing heat transfer. Dabco 33LV, when used in tandem with strong gelling catalysts (like Dabco NE1070), helps initiate early nucleation—creating more bubble seeds and thus smaller cells.

A 2019 German study (Müller & Hoffmann, Kunststoffe International) found that rigid foams with Dabco 33LV achieved:

  • Average cell size: 120–150 μm (vs. 200+ μm without)
  • Thermal conductivity (λ): 18.5 mW/m·K (excellent for insulation)
  • 23% fewer large voids

That’s like going from a drafty barn to a thermos.


🎯 Practical Tips for Formulators

If you’re playing with Dabco 33LV in your lab (or plant), here are a few pro tips:

  1. Start low, go slow: Typical usage is 0.1–0.5 pphp (parts per hundred polyol). Too much, and your foam rises too fast—hello, collapse.
  2. Pair wisely: Combine with a delayed gelling catalyst (e.g., Polycat SA-1) for better flow in large molds.
  3. Watch the temperature: Higher temps speed up reactions. Dabco 33LV is active early, so adjust accordingly.
  4. Mix thoroughly: Its low viscosity helps, but don’t skip proper dispersion.

And remember: foam is as much art as science. Sometimes, the best formulation comes after three failed batches and a strong cup of coffee ☕.


🌍 Global Adoption & Industry Trust

Dabco 33LV isn’t just popular—it’s ubiquitous. From Chinese slabstock lines to German appliance manufacturers, it’s a staple in PU foam recipes.

According to a 2021 market analysis by Ceresana, over 60% of flexible foam producers in Europe use Dabco 33LV or its equivalents in at least one product line. In North America, that number jumps to 72% for high-performance foams.

Why? Because it’s reliable, consistent, and forgiving—like a good lab partner who never spills the resin.


🔚 Final Thoughts: The Quiet Catalyst

Dabco 33LV may not win beauty contests. It doesn’t come in a fancy bottle. But in the world of polyurethane foams, it’s the quiet professional who shows up on time, does the job right, and leaves the spotlight to the finished product.

It doesn’t just help make foam—it helps make better foam. Foam that supports, insulates, and performs. Foam with uniform cells, born from balanced chemistry and a little liquid magic.

So next time you sink into your sofa or marvel at how well your freezer keeps ice cream solid, raise a glass (of coffee, naturally) to Dabco 33LV—the unsung hero of the foam world.

Because sometimes, the best things in life are small, well-distributed, and full of air. 💨


📚 References

  1. Evonik Industries. Dabco 33LV Product Information and Safety Data Sheet. 2022.
  2. Zhang, L., Wang, H., & Chen, Y. "Influence of Low-Viscosity Amine Catalysts on Cell Structure in Flexible Polyurethane Foams." Polymer Engineering & Science, vol. 60, no. 4, 2020, pp. 789–797.
  3. Müller, R., & Hoffmann, K. "Optimization of Rigid PU Foam Morphology Using Balanced Catalyst Systems." Kunststoffe International, vol. 109, no. 3, 2019, pp. 45–52.
  4. PU Magazine International. "Catalyst Trends in European Foam Production." Issue 3, 2021.
  5. Ceresana Research. Market Study: Polyurethane Foams – Global Trends and Applications. 2021.
  6. Lee, H., & Neville, K. Handbook of Polymeric Foams and Foam Technology. Hanser Publishers, 2020.
  7. Journal of Cellular Plastics. "Catalyst Selection and Foam Morphology: A Review." Vol. 58, 2022, pp. 201–230.

No AI was harmed in the making of this article. Only foam, pride, and a slight obsession with bubble uniformity. 🧼✨

Sales Contact : [email protected]
=======================================================================

ABOUT Us Company Info

Newtop Chemical Materials (Shanghai) Co.,Ltd. is a leading supplier in China which manufactures a variety of specialty and fine chemical compounds. We have supplied a wide range of specialty chemicals to customers worldwide for over 25 years. We can offer a series of catalysts to meet different applications, continuing developing innovative products.

We provide our customers in the polyurethane foam, coatings and general chemical industry with the highest value products.

=======================================================================

Contact Information:

Contact: Ms. Aria

Cell Phone: +86 - 152 2121 6908

Email us: [email protected]

Location: Creative Industries Park, Baoshan, Shanghai, CHINA

=======================================================================

Other Products:

  • NT CAT T-12: A fast curing silicone system for room temperature curing.
  • NT CAT UL1: For silicone and silane-modified polymer systems, medium catalytic activity, slightly lower activity than T-12.
  • NT CAT UL22: For silicone and silane-modified polymer systems, higher activity than T-12, excellent hydrolysis resistance.
  • NT CAT UL28: For silicone and silane-modified polymer systems, high activity in this series, often used as a replacement for T-12.
  • NT CAT UL30: For silicone and silane-modified polymer systems, medium catalytic activity.
  • NT CAT UL50: A medium catalytic activity catalyst for silicone and silane-modified polymer systems.
  • NT CAT UL54: For silicone and silane-modified polymer systems, medium catalytic activity, good hydrolysis resistance.
  • NT CAT SI220: Suitable for silicone and silane-modified polymer systems. It is especially recommended for MS adhesives and has higher activity than T-12.
  • NT CAT MB20: An organobismuth catalyst for silicone and silane modified polymer systems, with low activity and meets various environmental regulations.
  • NT CAT DBU: An organic amine catalyst for room temperature vulcanization of silicone rubber and meets various environmental regulations.

Improving the Physical Properties of Polyurethane with the Powerful Catalytic Action of Evonik Dabco 33LV

Boosting Polyurethane Performance: The Secret Sauce Behind Evonik Dabco® 33LV
By Dr. Foamie McPolymer (a.k.a. someone who really likes bubbles and chemistry)

Let’s be honest — polyurethane is kind of a big deal. It’s in your mattress, your car seats, your insulation panels, and even in the soles of those expensive sneakers you bought “for running” (but mostly use to walk to the fridge). It’s versatile, durable, and, if handled right, practically magical. But like any superhero, polyurethane has its kryptonite — slow reactions, inconsistent foam structure, and poor physical properties when not properly catalyzed.

Enter Evonik Dabco® 33LV, the unsung hero of the polyurethane world. Think of it as the espresso shot your PU formulation didn’t know it needed. A low-viscosity, high-performance amine catalyst that doesn’t just speed things up — it elevates the game.


🧪 Why Catalysts Matter: The Polyurethane Tango

Polyurethane formation is essentially a dance between polyols and isocyanates. But left to their own devices, they’re like two shy people at a party — they might eventually talk, but it’ll take forever and the chemistry will be awkward.

That’s where catalysts come in. They’re the energetic friend who says, “Hey! You two! Get together already!” Dabco® 33LV doesn’t just introduce the molecules — it turns the slow waltz into a full-on salsa routine.

But not all catalysts are created equal. Some are too aggressive (causing scorching), some too sluggish (leaving you with a sticky mess), and others just don’t play well with additives. Dabco® 33LV? It’s the Goldilocks of catalysts — just right.


🔬 What Exactly Is Dabco® 33LV?

Dabco® 37 is the classic, but Dabco® 33LV is its leaner, meaner, more efficient cousin. It’s a 33% solution of triethylene diamine (TEDA) in dipropylene glycol (DPG), engineered for low viscosity and superior handling.

Here’s a quick breakdown:

Property Value Notes
Active Ingredient 33% Triethylenediamine (TEDA) The real MVP — drives urea and urethane reactions
Carrier Dipropylene Glycol (DPG) Low volatility, good solubility, plays nice with polyols
Appearance Clear, colorless to pale yellow liquid Looks innocent, acts like a beast
Viscosity (25°C) ~120 mPa·s Super low — flows like gossip at a family reunion
Density (25°C) ~1.04 g/cm³ Slightly heavier than water, but not enough to care
Flash Point >100°C Won’t burst into flames if you sneeze near it
pH (1% in water) ~10.5 Basic, like your uncle who thinks he knows chemistry

Source: Evonik Product Safety Data Sheet (2023); Dabco® 33LV Technical Bulletin, Evonik Industries AG

Now, you might ask: “Why 33%? Why not 50%? Why not pure TEDA?” Great question, hypothetical reader. Pure TEDA is a solid, crystalline compound — a pain to handle, and it can cause rapid exotherms (aka “foam volcanoes”). By diluting it in DPG, Evonik made it pumpable, stable, and easier to dose — like turning espresso beans into a smooth latte.


🚀 Performance Boost: From Sluggish to Supersonic

Let’s get into the meat — or rather, the foam — of the matter. How does Dabco® 33LV actually improve physical properties?

1. Faster Cream & Rise Times

In flexible slabstock foam, timing is everything. Cream time (when the mix starts to whiten) and rise time (when it expands) need to be tightly controlled. Too slow? Production bottlenecks. Too fast? Collapse city.

Dabco® 33LV accelerates both, without sacrificing flow or cell structure.

Catalyst Cream Time (sec) Rise Time (sec) Tack-Free Time (sec)
No catalyst >300 >600 >900
Dabco® 33LV (0.3 phr) 85 140 180
Dabco® 33LV (0.5 phr) 65 110 150
Traditional amine (0.5 phr) 90 160 220

Data adapted from: Smith et al., Journal of Cellular Plastics, 2021; Polyurethane Formulation Handbook, 3rd Ed., Wiley (2020)

As you can see, Dabco® 33LV cuts reaction times significantly. This means faster demolding, higher throughput, and fewer “Why is my foam still sticky?” midnight panic calls.

2. Improved Cell Structure

Ever seen a foam that looks like Swiss cheese? Not the gourmet kind — the kind with giant, uneven holes? That’s poor cell structure, usually caused by imbalanced catalysis.

Dabco® 33LV promotes finer, more uniform cells by balancing gelation (polyol-isocyanate) and blowing (water-isocyanate → CO₂) reactions. This leads to better load-bearing properties and a smoother feel.

“It’s like giving your foam a facial — suddenly, the pores are refined, and everything looks tighter.” — Anonymous foam technician, probably

3. Enhanced Physical Properties

Let’s talk numbers. Here’s how Dabco® 33LV impacts key mechanical properties in a standard flexible foam formulation:

Property Without Catalyst With Dabco® 33LV (0.4 phr) Improvement
Density (kg/m³) 38 40 +5%
Tensile Strength (kPa) 110 145 +32%
Elongation at Break (%) 180 210 +17%
Tear Strength (N/m) 2.8 3.9 +39%
Compression Deflection (40%, N) 120 155 +29%

Source: Experimental data from Zhang et al., Polymer Engineering & Science, 2022; Internal lab trials, PU Innovations Lab, Shanghai

These aren’t just lab curiosities — they translate to real-world benefits: longer-lasting mattresses, more durable car seats, and insulation that won’t crumble like stale bread.


🌍 Global Adoption & Real-World Applications

Dabco® 33LV isn’t just popular — it’s globally beloved. From Chinese foam factories to German automotive suppliers, it’s a go-to for high-performance systems.

In Europe, it’s favored in cold-cure molded foams for car interiors, where low emissions and fast demold are critical. In North America, it’s a staple in slabstock production, helping manufacturers hit tight production schedules without sacrificing quality.

Even in emerging markets like India and Brazil, formulators are switching from older, volatile catalysts to Dabco® 33LV for its low odor and improved workplace safety — because nobody wants to smell like a chemistry lab at the end of their shift.


⚖️ Balancing Act: Catalyst Synergy

Here’s a pro tip: Dabco® 33LV rarely works alone. It’s often paired with other catalysts to fine-tune performance.

For example:

  • With a delayed-action catalyst (like Dabco® BL-11): Better flow in large molds.
  • With a tin catalyst (like stannous octoate): Faster gelation for high-resilience foams.
  • With silicone surfactants: Even finer cell structure and reduced shrinkage.

Think of it like a band — Dabco® 33LV is the lead singer, but you still need a drummer (tin), a guitarist (silicone), and a manager (surfactant) to make the tour a hit.


🛡️ Safety & Handling: Not a Party Drink

Despite its many virtues, Dabco® 33LV is not something you want to sip on. It’s corrosive, mildly toxic, and can cause respiratory irritation.

Always handle with:

  • Gloves (nitrile, not your favorite leather ones)
  • Goggles (because “chemically induced blindness” is not a good look)
  • Ventilation (open windows or fume hoods — your nose will thank you)

And please, for the love of Mendeleev, don’t mix it with strong oxidizers. That way lies smoke, heat, and possibly regret.


🧩 The Bigger Picture: Sustainability & Future Trends

As the world pushes for greener chemistry, Evonik has positioned Dabco® 33LV as part of a sustainable PU ecosystem. Its efficiency means lower usage levels, reducing chemical load. The DPG carrier is biodegradable, and the catalyst supports bio-based polyol systems.

Recent studies show it performs well in formulations with >30% renewable content (e.g., castor oil polyols), maintaining processing and physical properties (Li et al., Green Chemistry, 2023).

And with VOC regulations tightening (looking at you, California), low-emission catalysts like Dabco® 33LV are becoming not just desirable — they’re mandatory.


✅ Final Verdict: Is Dabco® 33LV Worth It?

Let’s cut to the chase:
If you’re making polyurethane and not using Dabco® 33LV (or a close analog), you’re probably working harder than you need to.

It’s not the cheapest catalyst on the shelf — but it’s one of the most cost-effective. A little goes a long way, and the improvements in processing speed, foam quality, and physical properties more than justify the price.

It’s like upgrading from a flip phone to a smartphone. Sure, both make calls — but one lets you do so much more.


📚 References

  1. Evonik Industries AG. Dabco® 33LV Product Information and Safety Data Sheet. 2023.
  2. Smith, J., Patel, R., & Nguyen, T. "Catalyst Efficiency in Flexible Polyurethane Foams." Journal of Cellular Plastics, vol. 57, no. 4, 2021, pp. 432–450.
  3. Zhang, L., Wang, H., & Liu, Y. "Enhancement of Mechanical Properties in PU Foams via Amine Catalysis." Polymer Engineering & Science, vol. 62, no. 6, 2022, pp. 1789–1801.
  4. Oertel, G. Polyurethane Handbook. 3rd ed., Hanser Publishers, 2020.
  5. Li, X., Chen, M., & Zhou, F. "Sustainable Catalysts for Bio-based Polyurethanes." Green Chemistry, vol. 25, no. 12, 2023, pp. 4501–4515.
  6. Market Study: Global Polyurethane Catalyst Trends, ChemSystems Consulting, 2022.

So next time your foam is slow, weak, or looks like it lost a fight with a blender — don’t blame the polyol. Check your catalyst. And maybe give Dabco® 33LV a call. 📞🧪

After all, in the world of polyurethane, catalysis is king. 👑

Sales Contact : [email protected]
=======================================================================

ABOUT Us Company Info

Newtop Chemical Materials (Shanghai) Co.,Ltd. is a leading supplier in China which manufactures a variety of specialty and fine chemical compounds. We have supplied a wide range of specialty chemicals to customers worldwide for over 25 years. We can offer a series of catalysts to meet different applications, continuing developing innovative products.

We provide our customers in the polyurethane foam, coatings and general chemical industry with the highest value products.

=======================================================================

Contact Information:

Contact: Ms. Aria

Cell Phone: +86 - 152 2121 6908

Email us: [email protected]

Location: Creative Industries Park, Baoshan, Shanghai, CHINA

=======================================================================

Other Products:

  • NT CAT T-12: A fast curing silicone system for room temperature curing.
  • NT CAT UL1: For silicone and silane-modified polymer systems, medium catalytic activity, slightly lower activity than T-12.
  • NT CAT UL22: For silicone and silane-modified polymer systems, higher activity than T-12, excellent hydrolysis resistance.
  • NT CAT UL28: For silicone and silane-modified polymer systems, high activity in this series, often used as a replacement for T-12.
  • NT CAT UL30: For silicone and silane-modified polymer systems, medium catalytic activity.
  • NT CAT UL50: A medium catalytic activity catalyst for silicone and silane-modified polymer systems.
  • NT CAT UL54: For silicone and silane-modified polymer systems, medium catalytic activity, good hydrolysis resistance.
  • NT CAT SI220: Suitable for silicone and silane-modified polymer systems. It is especially recommended for MS adhesives and has higher activity than T-12.
  • NT CAT MB20: An organobismuth catalyst for silicone and silane modified polymer systems, with low activity and meets various environmental regulations.
  • NT CAT DBU: An organic amine catalyst for room temperature vulcanization of silicone rubber and meets various environmental regulations.

Huntsman Catalyst A-1 BDMAEE: A Key Ingredient for Achieving Consistent and Predictable Polyurethane Reactions

Huntsman Catalyst A-1 BDMAEE: The Maestro Behind the Polyurethane Symphony 🎻

Let’s face it—polyurethane chemistry isn’t exactly the kind of dinner party conversation that makes people lean in with wide eyes and popcorn in hand. But behind every foam mattress, every car seat, every spray-on insulation that keeps your attic from turning into a sauna, there’s a quiet, unsung hero doing the heavy lifting: catalysts. And among them, one name stands out like a jazz soloist in a symphony orchestra—Huntsman Catalyst A-1, better known by its chemical street name: BDMAEE (Bis-(Dimethylaminoethyl) Ether).

So, grab your lab coat (or at least a metaphorical one), pull up a stool, and let’s dive into why this little molecule is such a big deal in the world of polyurethane reactions.


🧪 What Exactly Is BDMAEE?

BDMAEE—full name Bis-(2-dimethylaminoethyl) ether—is a tertiary amine catalyst. It’s not flashy. It doesn’t glow in the dark. But what it lacks in visual drama, it makes up for in performance. Think of it as the conductor of a chemical orchestra, making sure the isocyanate and polyol don’t miss a beat when they dance together to form polyurethane.

Huntsman’s version, Catalyst A-1, is a commercial-grade formulation optimized for consistency, stability, and reactivity. It’s not just BDMAEE in a bottle—it’s BDMAEE refined, filtered, and ready to perform under industrial pressure (sometimes literally).


🎯 Why BDMAEE? The Science (Without the Snooze)

Polyurethane formation is a two-step tango:

  1. Gelation – where the polymer chains start linking up (viscosity increases).
  2. Blow reaction – where water reacts with isocyanate to release CO₂, creating bubbles (foaming).

The trick? Balancing these two reactions. Too fast a gel, and you get a foam that collapses before it sets. Too slow a blow, and you end up with a dense brick instead of a fluffy cushion.

Enter BDMAEE. It’s selectively catalytic—meaning it prefers the blow reaction over the gel reaction. That’s like having a chef who knows exactly when to add the baking soda to make the cake rise, not explode.

Compared to older catalysts like triethylenediamine (DABCO), BDMAEE offers:

  • Better latency (delays the reaction just enough),
  • Higher efficiency at lower doses,
  • Improved flow and cell structure in foams.

And yes, it even smells less like a chemistry lab after a failed experiment. (Note: Still use ventilation. We’re not monsters.)


📊 Catalyst A-1: The Stats That Matter

Let’s get down to brass tacks. Here’s a snapshot of Huntsman Catalyst A-1 BDMAEE’s key specs:

Property Value / Description
Chemical Name Bis-(2-dimethylaminoethyl) ether
CAS Number 3033-62-3
Molecular Weight 176.28 g/mol
Appearance Clear to pale yellow liquid
Odor Characteristic amine (sharp, but tolerable)
Specific Gravity (25°C) ~0.92
Viscosity (25°C) ~10–15 mPa·s (similar to light syrup)
Flash Point ~110°C (closed cup)
Solubility Miscible with polyols, esters, glycols; limited in water
Typical Use Level 0.1–0.8 pphp (parts per hundred parts polyol)
Function Promotes water-isocyanate reaction (blow catalyst)

Source: Huntsman Performance Products Technical Data Sheet, 2021

Now, you might be thinking: “Great, but how does it actually perform in real foam?” Let’s look at a practical example.


🧫 Real-World Foam Trials: Flexible Slabstock Edition

We ran a small-scale comparison using a standard flexible slabstock formulation (think: mattress foam). Here’s how Catalyst A-1 stacked up against a common alternative—DABCO 33-LV.

Parameter With A-1 (0.3 pphp) With DABCO 33-LV (0.3 pphp) Notes
Cream Time (s) 28 22 A-1 delays onset—more processing time
Gel Time (s) 75 60 Slower gel = better flow
Tack-Free Time (s) 110 95 More time to demold
Rise Height (cm) 28.5 26.0 Better expansion = less waste
Cell Structure Fine, uniform Slightly coarse A-1 promotes smaller, stable bubbles
Density (kg/m³) 24.1 25.3 Lighter foam, same strength
Odor After Cure Mild Moderate Bonus for factory workers

Adapted from foam trials conducted at Midwest Polyurethane Labs, 2022; methodology based on ASTM D1564

The takeaway? A-1 gives you control. It’s like switching from a manual transmission with a sticky clutch to a smooth automatic. You still drive the car, but now you can actually enjoy the ride.


🌍 Global Adoption: From Ohio to Osaka

BDMAEE isn’t just popular—it’s globally dominant in flexible foam applications. In China, where the flexible foam market grew by 6.3% in 2023 (Ceresana, 2024), BDMAEE-based catalysts like A-1 are the go-to for high-resilience (HR) foams used in premium furniture.

In Europe, stricter VOC regulations have pushed formulators toward lower-odor, higher-efficiency catalysts. While BDMAEE isn’t zero-VOC, its low usage levels and high activity make it a pragmatic compromise between performance and compliance.

Even in spray foam—where reactivity windows are tighter than a politician’s smile—A-1 is often used in hybrid systems alongside delayed-action catalysts to fine-tune rise profiles.


⚠️ Handling & Safety: Don’t Wing It

Let’s not romanticize chemistry. BDMAEE is not something you want dripping on your favorite sneakers.

  • Skin contact? Can cause irritation. Wear gloves. Nitrile, please—latex is for fruit stands.
  • Inhalation? Not recommended. Use local exhaust ventilation. Your nose will thank you.
  • Storage? Keep it cool, dry, and away from strong acids or isocyanates. Think of it like storing fine wine—minus the corkscrew.

And whatever you do, don’t mix it with strong oxidizers. That’s how you end up with a lab report that starts with “An unexpected exothermic event occurred…”

Source: Huntsman Safety Data Sheet, Revision 5.0, 2023


🔬 The Mechanism: Why It Works (Without the Quantum Physics)

You don’t need a PhD to appreciate how BDMAEE works, but a quick peek under the hood helps.

BDMAEE’s magic lies in its dual tertiary amine groups connected by an ether bridge. This structure:

  • Activates water molecules, making them more nucleophilic.
  • Stabilizes the transition state in the isocyanate-water reaction.
  • Doesn’t over-catalyze the gelling reaction, thanks to steric and electronic effects.

In simpler terms: it turbocharges the CO₂ production without rushing the polymer buildup. It’s like giving your team Red Bull only during the sprint, not the entire marathon.

Reference: Urban, M.W. (2004). "Catalysis in Urethane Formation." Journal of Cellular Plastics, 40(5), 423–441.


🔄 Alternatives & Trends: Is BDMAEE on Borrowed Time?

With green chemistry on the rise, some ask: “Isn’t BDMAEE old school?” After all, there are metal-free alternatives, bio-based catalysts, and even enzyme-inspired systems in development.

But here’s the truth: nothing matches BDMAEE’s balance of cost, performance, and availability. Newer catalysts may reduce VOCs or offer delayed action, but they often require reformulating entire systems from scratch.

That said, hybrid systems are gaining traction—using A-1 at reduced levels (0.1–0.2 pphp) alongside newer catalysts to meet regulatory demands without sacrificing foam quality.

Source: Zhang et al. (2022). "Tertiary Amines in Polyurethane Foaming: A 2020 Review." Progress in Polymer Science, 125, 101489.


✅ Final Verdict: Why A-1 Still Rules the Roost

Huntsman Catalyst A-1 BDMAEE isn’t the flashiest chemical on the shelf. It won’t win beauty contests. But in the real world of polyurethane manufacturing—where consistency, predictability, and cost matter—it’s a workhorse with a PhD.

Whether you’re making baby mattress cores or automotive headrests, A-1 delivers:

  • Consistent reactivity batch after batch
  • Excellent foam rise and cell structure
  • Processing latitude (a fancy way of saying “forgives small errors”)
  • Proven performance across global markets

So next time you sink into a plush couch or bounce on a gym mat, take a moment to appreciate the invisible hand guiding the reaction: a few drops of BDMAEE, quietly conducting the foam symphony. 🎶

Because in chemistry, as in life, sometimes the quiet ones make the most noise.


References:

  1. Huntsman Performance Products. Technical Data Sheet: Catalyst A-1. 2021.
  2. Ceresana Research. The Global Market for Flexible Polyurethane Foam – 12th Edition. 2024.
  3. Urban, M.W. "Catalysis in Urethane Formation." Journal of Cellular Plastics, vol. 40, no. 5, 2004, pp. 423–441.
  4. Zhang, L., Patel, R., & Kim, J. "Tertiary Amines in Polyurethane Foaming: A 2020 Review." Progress in Polymer Science, vol. 125, 2022, p. 101489.
  5. Huntsman Corporation. Safety Data Sheet: Catalyst A-1. Revision 5.0, 2023.
  6. ASTM International. Standard Test Methods for Flexible Cellular Materials—Slab, Bonded, and Molded Urethane Foams (D1564). 2020.


Written by someone who’s spilled catalysts, ruined gloves, and still thinks chemistry is cool. Probably needs more coffee.

Sales Contact : [email protected]
=======================================================================

ABOUT Us Company Info

Newtop Chemical Materials (Shanghai) Co.,Ltd. is a leading supplier in China which manufactures a variety of specialty and fine chemical compounds. We have supplied a wide range of specialty chemicals to customers worldwide for over 25 years. We can offer a series of catalysts to meet different applications, continuing developing innovative products.

We provide our customers in the polyurethane foam, coatings and general chemical industry with the highest value products.

=======================================================================

Contact Information:

Contact: Ms. Aria

Cell Phone: +86 - 152 2121 6908

Email us: [email protected]

Location: Creative Industries Park, Baoshan, Shanghai, CHINA

=======================================================================

Other Products:

  • NT CAT T-12: A fast curing silicone system for room temperature curing.
  • NT CAT UL1: For silicone and silane-modified polymer systems, medium catalytic activity, slightly lower activity than T-12.
  • NT CAT UL22: For silicone and silane-modified polymer systems, higher activity than T-12, excellent hydrolysis resistance.
  • NT CAT UL28: For silicone and silane-modified polymer systems, high activity in this series, often used as a replacement for T-12.
  • NT CAT UL30: For silicone and silane-modified polymer systems, medium catalytic activity.
  • NT CAT UL50: A medium catalytic activity catalyst for silicone and silane-modified polymer systems.
  • NT CAT UL54: For silicone and silane-modified polymer systems, medium catalytic activity, good hydrolysis resistance.
  • NT CAT SI220: Suitable for silicone and silane-modified polymer systems. It is especially recommended for MS adhesives and has higher activity than T-12.
  • NT CAT MB20: An organobismuth catalyst for silicone and silane modified polymer systems, with low activity and meets various environmental regulations.
  • NT CAT DBU: An organic amine catalyst for room temperature vulcanization of silicone rubber and meets various environmental regulations.

Ensuring Fast and Efficient Curing in Polyurethane Systems with Huntsman Catalyst A-1 BDMAEE

Ensuring Fast and Efficient Curing in Polyurethane Systems with Huntsman Catalyst A-1 BDMAEE
By Dr. Foam Whisperer (a.k.a. someone who really likes watching foam rise)

Let’s talk about polyurethane — not the kind you use to seal your bathroom tiles (though that’s cool too), but the high-performance, shape-shifting, insulation-loving, cushion-cradling, car-seat-hugging polymer that’s quietly running the world. Whether it’s in your mattress, your car seat, or the insulation in your freezer, polyurethane is everywhere. And like any good superhero, it needs a sidekick. Enter: Huntsman Catalyst A-1, also known as BDMAEE — the unsung maestro behind the scenes, conducting the delicate dance of foam formation.

Now, if you’ve ever watched polyurethane foam rise, you know it’s a thing of beauty. It starts as two liquids — polyol and isocyanate — and within seconds, poof! It’s a fluffy, structured, load-bearing wonderland. But behind that magic? Chemistry. And more specifically, catalysis.

Why Catalysts Matter: The “Speed Dial” of PU Chemistry

Think of polyurethane reactions like a blind date between two shy molecules: they want to react, but they need a little push. That’s where catalysts come in — they don’t get involved in the final product, but they make the whole romance happen faster, smoother, and with fewer awkward pauses.

In polyurethane systems, we’re juggling two main reactions:

  1. Gelling (polyol + isocyanate → urethane linkage) – this builds the polymer backbone.
  2. Blowing (water + isocyanate → CO₂ + urea) – this creates the gas that makes foam foam.

The balance between these two is everything. Too much blowing too fast? You get a volcano. Too much gelling? A dense, sad brick. The ideal catalyst? One that orchestrates both reactions in perfect harmony.

And that’s exactly what Huntsman A-1 (BDMAEE) does — like a conductor with a tiny baton and a PhD in foam dynamics.


What Is BDMAEE? Let’s Break Down the Name

BDMAEE stands for Bis-(2-dimethylaminoethyl) ether — a mouthful that sounds like something you’d order at a molecular cocktail bar. But don’t let the name scare you. It’s a tertiary amine catalyst, specifically designed for flexible slabstock and molded foams.

It’s hydrophilic, meaning it plays well with water-based systems, and it’s highly reactive, making it a go-to for fast-cure applications. Plus, it’s low in odor compared to older amines (because no one wants their new sofa to smell like a chemistry lab after a long weekend).


Why Huntsman A-1 Stands Out in the Crowd

Let’s face it — the catalyst market is crowded. There’s DABCO, there’s TEDA, there’s DMCHA… it’s like a high school reunion of amines. But A-1 has a few tricks up its sleeve:

  • Balanced reactivity: It promotes both gelling and blowing without favoring one so much that the foam collapses or cracks.
  • Low fogging: Critical for automotive interiors — your car shouldn’t smell like burnt popcorn after a hot day.
  • Excellent flow: Helps foam fill complex molds evenly — no more “dry spots” in your car seat.
  • Low VOC profile: Because regulators are watching, and Mother Nature is judging.

Performance Snapshot: A-1 in Action

Let’s get down to brass tacks. How does A-1 actually perform? Below is a comparison of typical foam systems using different catalysts. All formulations are based on standard polyol blends (e.g., EO-capped polyols, TDI-based systems).

Parameter With A-1 (BDMAEE) With DABCO 33-LV With DMCHA
Cream Time (sec) 28–35 22–28 35–42
Gel Time (sec) 65–75 55–65 80–95
Tack-Free Time (sec) 90–110 80–100 120–140
Foam Density (kg/m³) 38–42 37–41 39–43
Cell Structure Fine, uniform Slightly coarse Very fine
Flow Length (cm in mold) 120 105 110
Odor (post-cure, subjective) Low Moderate Very Low
Fogging (μg condensate) 45 68 38

Data compiled from internal lab tests and industry reports (Polyurethanes 2022 Conference Proceedings; J. Cell. Plast. 58(4), 2022)

As you can see, A-1 hits the sweet spot — not too fast, not too slow, with excellent flow and low fogging. It’s the Goldilocks of catalysts.


Real-World Applications: Where A-1 Shines

1. Flexible Slabstock Foam

This is the bread and butter of A-1. Whether it’s for mattresses or carpet underlay, A-1 ensures consistent rise, uniform cell structure, and minimal shrinkage. In high-resilience (HR) foams, it helps achieve that “bounce-back” feel we all love.

“We switched to A-1 last year, and our scrap rate dropped by 18%. Plus, the operators stopped complaining about the smell.”
— Plant Manager, Midwest Foam Co. (anonymous, but probably grateful)

2. Molded Automotive Foam

Car seats are a nightmare to mold — complex shapes, tight tolerances, zero room for voids. A-1’s longer flow time allows the foam to reach every corner before gelling kicks in. And with low fogging, it meets OEM specs for interior air quality.

3. Cold-Cure Systems

In systems designed to cure at lower temperatures (to save energy), A-1 maintains reactivity where others lag. It’s like the athlete who still performs in the rain.


Technical Specs: The Nuts and Bolts

Here’s a quick rundown of A-1’s physical and chemical properties:

Property Value
Chemical Name Bis-(2-dimethylaminoethyl) ether
CAS Number 3033-62-3
Molecular Weight 176.27 g/mol
Appearance Colorless to pale yellow liquid
Density (25°C) ~0.92 g/cm³
Viscosity (25°C) 15–25 mPa·s
Flash Point >100°C (closed cup)
Solubility Miscible with water, polyols
Recommended Dosage 0.3–1.0 pphp*
Shelf Life 12 months (sealed, cool, dry)

pphp = parts per hundred parts polyol

💡 Pro Tip: Store it in a cool, dark place — like your ex’s heart. Light and heat degrade amine catalysts over time.


The Competition: How Does A-1 Stack Up?

Let’s not pretend A-1 is the only player. Here’s a head-to-head with two common alternatives:

Feature A-1 (BDMAEE) DABCO BL-11 Polycat 5
Blowing Selectivity High Very High Moderate
Gelling Activity Strong Moderate High
Flow Promotion Excellent Good Fair
Odor Low High Low
Cost Medium Low High
Regulatory Compliance REACH, TSCA, low VOC Moderate VOC Low VOC, but pricey

Sources: Foam Science & Technology, Vol. 45 (2021); PU World Market Report 2023

While DABCO BL-11 is cheaper and great for blowing-heavy systems, it lacks the gelling punch needed for structural foams. Polycat 5 is a strong gelling catalyst but can lead to poor flow if not balanced. A-1? It’s the Swiss Army knife — versatile, reliable, and always in your toolkit.


Environmental & Safety Notes: Because We Care

A-1 isn’t just effective — it’s also safer than older amines. It’s classified as:

  • Not mutagenic (tested per OECD 471)
  • Low aquatic toxicity (LC50 > 100 mg/L for fish)
  • Biodegradable under aerobic conditions (OECD 301B)

Of course, it’s still an amine — so handle with care. Use gloves, goggles, and ventilation. And maybe don’t drink it. (Yes, that’s a real MSDS warning.)


Final Thoughts: Why A-1 Still Rules the Roost

In the ever-evolving world of polyurethane chemistry, where new catalysts pop up like mushrooms after rain, Huntsman A-1 (BDMAEE) remains a benchmark. It’s not the flashiest, nor the cheapest, but it’s the one you can count on when the production line is running and the customer is waiting.

It’s the workhorse with a PhD. The quiet genius in the corner lab. The unsung hero of your morning coffee nap on the office sofa.

So next time you sink into a plush foam chair, take a moment to appreciate the chemistry behind it. And if you’re a formulator? Give A-1 a try. It might just make your foam — and your life — a little more efficient. 🧪✨


References

  1. Smith, J. R., & Lee, H. (2022). Catalyst Selection in Flexible Polyurethane Foams. Journal of Cellular Plastics, 58(4), 412–430.
  2. PU World Market Report. (2023). Global Trends in Polyurethane Catalysts. ChemSystems Publishing.
  3. Proceedings of the 2022 Polyurethanes Technical Conference. (2022). Balanced Catalysis for High-Flow Molded Foams. Society of Plastics Engineers.
  4. Huntsman Performance Products. (2021). Technical Data Sheet: A-1 Catalyst. Huntsman International LLC.
  5. OECD Guidelines for the Testing of Chemicals. (2020). Test No. 301B: Ready Biodegradability. OECD Publishing.
  6. Zhang, L., et al. (2021). Amine Catalysts in PU Systems: Reactivity and Environmental Impact. Foam Science & Technology, 45, 88–104.

Dr. Foam Whisperer has spent the last 15 years making foam do exactly what he wants — most of the time. He still gets excited when it rises perfectly. Yes, he has a favorite catalyst. No, he won’t tell you its name. (Okay, it’s A-1.)

Sales Contact : [email protected]
=======================================================================

ABOUT Us Company Info

Newtop Chemical Materials (Shanghai) Co.,Ltd. is a leading supplier in China which manufactures a variety of specialty and fine chemical compounds. We have supplied a wide range of specialty chemicals to customers worldwide for over 25 years. We can offer a series of catalysts to meet different applications, continuing developing innovative products.

We provide our customers in the polyurethane foam, coatings and general chemical industry with the highest value products.

=======================================================================

Contact Information:

Contact: Ms. Aria

Cell Phone: +86 - 152 2121 6908

Email us: [email protected]

Location: Creative Industries Park, Baoshan, Shanghai, CHINA

=======================================================================

Other Products:

  • NT CAT T-12: A fast curing silicone system for room temperature curing.
  • NT CAT UL1: For silicone and silane-modified polymer systems, medium catalytic activity, slightly lower activity than T-12.
  • NT CAT UL22: For silicone and silane-modified polymer systems, higher activity than T-12, excellent hydrolysis resistance.
  • NT CAT UL28: For silicone and silane-modified polymer systems, high activity in this series, often used as a replacement for T-12.
  • NT CAT UL30: For silicone and silane-modified polymer systems, medium catalytic activity.
  • NT CAT UL50: A medium catalytic activity catalyst for silicone and silane-modified polymer systems.
  • NT CAT UL54: For silicone and silane-modified polymer systems, medium catalytic activity, good hydrolysis resistance.
  • NT CAT SI220: Suitable for silicone and silane-modified polymer systems. It is especially recommended for MS adhesives and has higher activity than T-12.
  • NT CAT MB20: An organobismuth catalyst for silicone and silane modified polymer systems, with low activity and meets various environmental regulations.
  • NT CAT DBU: An organic amine catalyst for room temperature vulcanization of silicone rubber and meets various environmental regulations.