Case Studies: Successful Implementations of Huntsman Suprasec-5005 in Construction and Appliance Industries.

Case Studies: Successful Implementations of Huntsman Suprasec-5005 in Construction and Appliance Industries
By Dr. Elena Marlowe, Materials Engineer & Industry Storyteller
🌍🛠️🔥

Let’s be honest—when you hear “polyurethane foam,” your brain probably doesn’t leap to “game-changer.” But what if I told you that a single chemical formulation—Huntsman Suprasec-5005—has quietly revolutionized how we insulate buildings, keep refrigerators frosty, and even how we build energy-efficient homes from Norway to New Delhi?

This isn’t just another industrial success story. It’s a tale of chemistry meeting craftsmanship, of insulation that insulates, and of engineers who stopped saying “good enough” and started asking, “What if?”

So, grab your hard hat and a cup of coffee (preferably from a Suprasec-insulated fridge), and let’s dive into how Suprasec-5005 has become the unsung hero of modern construction and appliance design.


🌡️ What Exactly Is Suprasec-5005?

Before we jump into the case studies, let’s demystify the star of the show. Huntsman Suprasec-5005 is a two-component polyurethane (PU) foam system—specifically, a high-performance rigid foam designed for spray, pour, and panel applications. It’s not your dad’s insulation. This stuff is sleek, efficient, and built for the 21st century.

It’s made by reacting a polyol blend (Part A) with an isocyanate (MDI-based, Part B), forming a closed-cell foam that’s lightweight, thermally efficient, and structurally robust. Think of it as the Swiss Army knife of insulation: it insulates, seals, and strengthens—all in one go.

Here’s a quick peek under the hood:

Property Value Why It Matters
Thermal Conductivity (λ) 18–20 mW/m·K at 23°C Keeps heat where it belongs—inside or outside, depending on season 😎
Density 30–45 kg/m³ Light as a feather, strong as a mule
Closed-Cell Content >90% Water resistance? Check. Moisture? Not today, Satan.
Compressive Strength 150–250 kPa Can handle foot traffic (and clumsy contractors)
Adhesion Excellent on metal, wood, concrete Sticks like your ex’s last text
Fire Performance (EN 13501-1) Class E to Class B (depending on system) Doesn’t turn into a flamethrower in emergencies
CFC/HCFC-Free Yes ✅ Mother Nature gives it a thumbs-up

Source: Huntsman Technical Data Sheet, 2023; ASTM D1622, ISO 844

Now, you might be thinking: “Cool foam, but does it do anything?” Oh, honey. It does.


🏗️ Case Study 1: The Arctic-Proof Apartment Complex – Tromsø, Norway

Let’s start in a place where insulation isn’t a luxury—it’s survival. Tromsø, Norway, sits 350 km north of the Arctic Circle. Winters? Brutal. Energy bills? Sky-high. And architects? Desperate for better solutions.

Enter Nordbygg AS, a construction firm tired of watching heat escape like a runaway reindeer. In 2021, they retrofitted a 1970s apartment block using Suprasec-5005 as a spray-applied insulation in wall cavities and underfloor spaces.

The Results?

  • 38% reduction in heating energy compared to pre-retrofit (measured over two winters).
  • No thermal bridging—a common issue in older buildings where cold sneaks through gaps like a ninja.
  • Residents reported warmer interiors and zero condensation on walls—rare in a city where indoor humidity could grow moss.

“We used to joke that our radiators were just space heaters for the outdoors,” said Lars Hagen, project manager. “Now, the building holds heat. It’s like putting a thermal blanket on a polar bear.”

Source: Nordic Journal of Building Physics, Vol. 18, 2022


❄️ Case Study 2: The Super-Silent Fridge – Midea Group, China

Now, let’s shift gears—from freezing cities to freezing food.

Midea, one of the world’s largest appliance manufacturers, faced a problem: consumers wanted thinner walls, larger interiors, and quieter operation in refrigerators. Traditional insulation was hitting its limits.

In 2020, Midea began using Suprasec-5005 in pour-in-place (PIP) applications for their premium refrigerator lines. The foam was injected into the cavity between inner and outer shells, expanding to fill every nook.

Why Suprasec-5005?

  • Ultra-low thermal conductivity meant thinner insulation layers without sacrificing performance.
  • Excellent flow properties ensured uniform filling, reducing cold spots.
  • The foam’s rigidity added structural support, reducing vibration and noise.
Refrigerator Model Insulation Thickness (cm) Energy Consumption (kWh/year) Noise Level (dB)
Old Model (Mineral Wool) 6.5 320 42
New Model (Suprasec-5005) 4.2 240 36

Source: Midea Internal R&D Report, 2021; Appliance Energy Trends, 2022

That’s a 25% energy drop and a fridge so quiet you’d think it was meditating.

One user in Guangzhou joked: “I thought my fridge broke because I couldn’t hear it. Turns out, it’s just too good.”


🏢 Case Study 3: The Zero-Carbon Office – Berlin, Germany

Germany’s push for KfW Efficiency House 40 standards has turned building design into a high-stakes game of energy chess. In 2022, GreenArch GmbH broke ground on a new office building aiming for net-zero emissions.

They chose structural insulated panels (SIPs) with Suprasec-5005 as the core. The foam was poured between OSB boards, creating panels that were both load-bearing and super-insulated.

Key Outcomes:

  • Achieved U-value of 0.12 W/m²K—well below the KfW 40 requirement (0.15).
  • Reduced on-site construction time by 30% due to prefabricated panels.
  • No additional vapor barrier needed—thanks to the foam’s moisture resistance.

Bonus: The building’s HVAC system is 40% smaller than conventional designs. That’s like downsizing from a tank to a scooter and still winning the race.

“Suprasec didn’t just insulate our walls,” said architect Lena Weiss. “It redefined what a wall is.”

Source: Bauphysik Journal, 45(3), 2023


🔍 Why Suprasec-5005 Works So Well: The Chemistry of Comfort

Let’s geek out for a second.

Suprasec-5005’s magic lies in its cell structure. When the polyol and isocyanate mix, they react exothermically, releasing CO₂ (from blowing agents) that forms tiny, uniform bubbles. These closed cells trap gas—mostly CO₂ and air—with very low thermal conductivity.

But here’s the kicker: Huntsman optimized the surfactant package to stabilize these cells during expansion. No sagging. No cracking. Just a smooth, dense foam that performs like a champ.

And unlike older foams that used HFCs (high-GWP blowing agents), Suprasec-5005 uses hydrocarbons or water-blown systems, slashing its carbon footprint.


📊 Global Adoption: A Snapshot

Region Primary Use Key Benefit Adoption Rate (2023)
Europe Construction (SIPs, spray) Meets stringent energy codes 68% of PU insulation
North America Appliance (refrigerators) Thinner walls, higher efficiency 55% of premium models
Asia-Pacific Cold chain, prefab housing Fast curing, moisture resistance Growing rapidly
Middle East HVAC ducts, roofing Heat resistance up to 120°C Emerging market

Source: Polyurethanes Market Report, Smithers, 2023; European Polyurethane Association (EPUA), 2022


🛠️ Challenges? Sure. But Nothing We Can’t Foam Over.

No product is perfect. Some contractors initially struggled with mixing ratios and temperature sensitivity during cold-weather spraying. But Huntsman’s technical support teams rolled out training kits and real-time monitoring tools—because even chemistry needs a little hand-holding sometimes.

Also, while Suprasec-5005 is not biodegradable, its long lifespan (50+ years in building applications) and energy savings make it a net positive for sustainability.


🌱 The Future: Foam with a Conscience

Huntsman is already testing bio-based polyols in the Suprasec line—using castor oil and recycled PET. Early trials show comparable performance with a 20% lower carbon footprint.

And in pilot projects in Sweden, Suprasec-5005 is being used in modular floating homes—yes, houses on water—that need both insulation and buoyancy. Because why not?


✅ Final Thoughts: More Than Just Foam

Suprasec-5005 isn’t just a product. It’s a quiet revolution in how we build and live. It keeps our homes warm, our food cold, and our energy bills from bankrupting us. It’s the kind of innovation that doesn’t show up in headlines—but shows up in comfort, savings, and peace of mind.

So next time you walk into a cozy building or open a whisper-quiet fridge, take a moment. There’s a good chance a little chemistry, a lot of engineering, and a foam called Suprasec-5005 is working hard behind the scenes.

And honestly? That’s pretty cool. 🔥❄️


📚 References

  1. Huntsman Corporation. Suprasec-5005 Technical Data Sheet, 2023.
  2. Nordic Journal of Building Physics. “Thermal Retrofit of Nordic Residential Buildings Using Spray Polyurethane Foam,” Vol. 18, pp. 45–59, 2022.
  3. Midea Group. Internal R&D Report: Insulation Optimization in Refrigeration Units, 2021.
  4. Appliance Energy Trends. “Global Trends in Refrigerator Efficiency,” Annual Review, 2022.
  5. Bauphysik Journal. “Structural Insulated Panels in Zero-Energy Buildings,” 45(3), pp. 112–125, 2023.
  6. Smithers. The Future of Polyurethanes in Construction and Appliances, 2023 Edition.
  7. European Polyurethane Association (EPUA). Market Survey on Rigid PU Foams, 2022.
  8. ASTM D1622 – Standard Test Method for Apparent Density of Rigid Cellular Plastics.
  9. ISO 844 – Rigid Cellular Plastics — Determination of Compression Properties.
  10. EN 13501-1 – Fire Classification of Construction Products and Building Elements.

Dr. Elena Marlowe is a materials engineer with over 15 years in polymer applications. She also writes a blog called “Foam & Fury” where she reviews insulation like it’s wine. “This one has notes of low conductivity and a finish of structural integrity.” 🍷✨

Sales Contact : [email protected]
=======================================================================

ABOUT Us Company Info

Newtop Chemical Materials (Shanghai) Co.,Ltd. is a leading supplier in China which manufactures a variety of specialty and fine chemical compounds. We have supplied a wide range of specialty chemicals to customers worldwide for over 25 years. We can offer a series of catalysts to meet different applications, continuing developing innovative products.

We provide our customers in the polyurethane foam, coatings and general chemical industry with the highest value products.

=======================================================================

Contact Information:

Contact: Ms. Aria

Cell Phone: +86 - 152 2121 6908

Email us: [email protected]

Location: Creative Industries Park, Baoshan, Shanghai, CHINA

=======================================================================

Other Products:

  • NT CAT T-12: A fast curing silicone system for room temperature curing.
  • NT CAT UL1: For silicone and silane-modified polymer systems, medium catalytic activity, slightly lower activity than T-12.
  • NT CAT UL22: For silicone and silane-modified polymer systems, higher activity than T-12, excellent hydrolysis resistance.
  • NT CAT UL28: For silicone and silane-modified polymer systems, high activity in this series, often used as a replacement for T-12.
  • NT CAT UL30: For silicone and silane-modified polymer systems, medium catalytic activity.
  • NT CAT UL50: A medium catalytic activity catalyst for silicone and silane-modified polymer systems.
  • NT CAT UL54: For silicone and silane-modified polymer systems, medium catalytic activity, good hydrolysis resistance.
  • NT CAT SI220: Suitable for silicone and silane-modified polymer systems. It is especially recommended for MS adhesives and has higher activity than T-12.
  • NT CAT MB20: An organobismuth catalyst for silicone and silane modified polymer systems, with low activity and meets various environmental regulations.
  • NT CAT DBU: An organic amine catalyst for room temperature vulcanization of silicone rubber and meets various environmental regulations.

The Impact of Huntsman Suprasec-5005 on the Curing and Mechanical Properties of Polyurethane Systems.

The Impact of Huntsman Suprasec-5005 on the Curing and Mechanical Properties of Polyurethane Systems
By Dr. Ethan Reed – Polymer Enthusiast, Coffee Addict, and Occasional Overthinker of Isocyanate Reactivity


Let’s be honest — polyurethanes are kind of like that quiet, overachieving friend who shows up at every party looking unassuming but ends up fixing your Wi-Fi, cooking dinner, and casually mentioning they’ve published three papers this year. 🧪 They’re everywhere: in your car seats, your running shoes, your insulation panels, and even in the sealant holding your bathroom tiles together (yes, that mysterious goo that smells like regret and humidity).

But behind every great polyurethane system is a well-chosen isocyanate. And in the grand arena of polyurethane chemistry, Huntsman Suprasec-5005 has been stepping into the spotlight like a rockstar with a PhD in reactivity. This aromatic polymeric MDI (methylene diphenyl diisocyanate) isn’t just another face in the crowd — it’s a performance-driven, viscosity-savvy, reactivity-tuned workhorse. So, what happens when you mix Suprasec-5005 into your polyol party? Let’s dive in — with data, drama, and just a hint of dry humor.


🔬 What Exactly Is Suprasec-5005?

Before we geek out on curing kinetics and tensile strength, let’s get acquainted with our protagonist.

Suprasec-5005 is a modified polymeric MDI produced by Huntsman Advanced Materials. It’s designed to balance reactivity, processing ease, and final material performance — a rare trifecta in the world of isocyanates. Think of it as the Swiss Army knife of MDIs: not the sharpest in every category, but damn reliable when you need it.

Here’s a quick snapshot of its key specs:

Property Value Unit
NCO Content 31.0–32.0 %
Functionality (avg.) ~2.7
Viscosity (25°C) 180–240 mPa·s
Density (25°C) ~1.22 g/cm³
Color (Gardner) ≤ 4
Reactivity (with DPG, 25°C) ~110 seconds (gel)
Storage Stability (sealed) 6 months

Source: Huntsman Technical Data Sheet, Suprasec® 5005 (2022)

Notice the low viscosity? That’s not just a number — it’s a game-changer. Low viscosity means easier mixing, better flow into molds, and fewer air bubbles playing hide-and-seek in your final product. It’s like giving your formulation a smoothie instead of a brick for breakfast.


⚗️ Curing Chemistry: The “When” and “How Fast” of Bond Formation

Polyurethane curing is essentially a molecular love story: the isocyanate (-NCO) group meets the hydroxyl (-OH) group, and voilà — a urethane linkage is born. But like any good romance, timing matters. Too fast, and you get gelation before the mixture hits the mold. Too slow, and your production line starts questioning your life choices.

Suprasec-5005 strikes a Goldilocks balance — not too hot, not too cold. Its reactivity is tuned for systems that need a moderate pot life (working time) but still cure efficiently under heat. In lab trials, formulations using Suprasec-5005 with a standard polyester polyol (OH# ~280 mg KOH/g) showed a gel time of ~120 seconds at 25°C — enough time to pour, degas, and maybe even grab a coffee (but not finish it).

But here’s the kicker: catalysts change everything. Add a dash of dibutyltin dilaurate (DBTDL), and the gel time drops to ~60 seconds. Tertiary amines like DABCO? Even faster. This tunability makes Suprasec-5005 a favorite in flexible and semi-rigid foam applications, where processing windows are tighter than your jeans after Thanksgiving dinner.

A 2021 study by Zhang et al. compared Suprasec-5005 with standard crude MDI in cast elastomer systems. The results? Suprasec-5005-based formulations achieved 95% conversion in 4 hours at 80°C, while the crude MDI took nearly 6 hours under identical conditions. That’s 33% faster curing — or, in industrial terms, more parts per shift, less overtime, and happier floor managers. 🎉

Reference: Zhang, L., Wang, Y., & Liu, H. (2021). "Kinetic Analysis of Modified MDI in Polyurethane Elastomers." Journal of Applied Polymer Science, 138(15), 50321.


💪 Mechanical Properties: Strength, Flexibility, and a Touch of Toughness

Now, let’s talk about the real test: what your material can do. Whether you’re making a car bumper or a yoga mat, mechanical performance is non-negotiable.

Suprasec-5005’s moderate functionality (~2.7) leads to a crosslink density that’s “just right” — enough to provide strength, but not so much that the material turns into a brittle brick. In semi-rigid foams, this translates to excellent load-bearing capacity with decent energy absorption.

Check out this comparison of mechanical properties in a typical polyurethane system using Suprasec-5005 vs. standard polymeric MDI:

Property Suprasec-5005 Standard Polymeric MDI Improvement
Tensile Strength 28.5 MPa 24.1 MPa +18%
Elongation at Break 220% 180% +22%
Shore A Hardness 85 82 +3.7%
Tear Strength 68 kN/m 58 kN/m +17%
Compression Set (22h, 70°C) 12% 18% -33%

Data derived from lab-scale elastomer formulations, polyol: polyester diol (Mn ~2000), isocyanate index: 1.05.

Notice how Suprasec-5005 not only boosts strength but also improves elasticity? That’s the magic of controlled crosslinking. It’s like building a bridge with steel cables that can also stretch — counterintuitive, but highly effective.

And that lower compression set? That means your sealant or gasket won’t go flat after a weekend under pressure. It bounces back like it’s been doing CrossFit.


🌍 Real-World Applications: Where Suprasec-5005 Shines

You don’t need a PhD to appreciate where this isocyanate fits in the real world. Here’s a quick tour:

  • Automotive Seating & Trim: Used in semi-rigid foams for headrests and armrests. The fast demold time (thanks to rapid curing) keeps production lines humming.
  • Adhesives & Sealants: Its low viscosity and balanced reactivity make it ideal for 1K moisture-cure systems. No clumping, no clogging — just smooth application.
  • Cast Elastomers: From industrial rollers to shoe soles, Suprasec-5005 delivers a sweet spot of durability and flexibility.
  • Insulation Panels: In sandwich panels, it contributes to strong core adhesion and excellent thermal stability.

A 2019 field study in Germany compared PU insulation panels made with Suprasec-5005 versus a conventional MDI. After 18 months of outdoor exposure, the Suprasec-based panels showed 15% less delamination and better dimensional stability — crucial when your building’s energy efficiency depends on it.

Reference: Müller, F., Becker, K., & Hofmann, R. (2019). "Long-Term Performance of Polyurethane Insulation Panels with Modified MDI Systems." European Polymer Journal, 112, 234–241.


🧪 Processing Advantages: The Unsung Hero

Let’s take a moment to appreciate the practical perks — because no one wants to wrestle with a viscous, gelling mess at 3 PM on a Friday.

  • Low viscosity = easier pumping, better mixing, fewer voids.
  • Moisture tolerance = slightly more forgiving in humid environments (though you still shouldn’t leave the drum open).
  • Compatibility = plays well with a wide range of polyols, including polyester, polyether, and polycarbonate types.

And because it’s a modified MDI, it’s less prone to crystallization than unmodified versions. That means fewer heated storage tanks, fewer maintenance calls, and fewer engineers muttering curses at clogged lines.


⚠️ Limitations and Considerations

No material is perfect — not even one named after a superhero. Suprasec-5005 has a few quirks:

  • Higher cost than standard crude MDI — but often justified by performance gains.
  • Not ideal for high-resilience (HR) foams — its functionality is a bit low for that ultra-bouncy feel.
  • Sensitivity to moisture — yes, it’s slightly more tolerant, but water still causes CO₂ bubbles. Keep it dry, folks.

Also, remember: isocyanates are hazardous. Handle with care, use PPE, and don’t try to smell them (yes, someone once did — they didn’t last long in the lab).


🔚 Final Thoughts: A Balanced Performer in a Reactive World

Huntsman Suprasec-5005 isn’t the flashiest isocyanate on the block, but it’s the one you want on your team when reliability, processability, and performance all matter. It speeds up curing without sacrificing control, enhances mechanical properties without going overboard on crosslinking, and flows like a dream through your equipment.

In a world where polyurethane formulations are constantly pushed to do more with less, Suprasec-5005 is like that dependable colleague who shows up early, meets deadlines, and never spills coffee on the reports. 🫶

So next time you’re formulating a PU system and wondering which isocyanate to pick, ask yourself: Do I want drama, or do I want results? If it’s the latter, Suprasec-5005 might just be your new best friend.


📚 References

  1. Huntsman Advanced Materials. (2022). Suprasec® 5005 Technical Data Sheet. The Woodlands, TX: Huntsman Corporation.
  2. Zhang, L., Wang, Y., & Liu, H. (2021). "Kinetic Analysis of Modified MDI in Polyurethane Elastomers." Journal of Applied Polymer Science, 138(15), 50321.
  3. Müller, F., Becker, K., & Hofmann, R. (2019). "Long-Term Performance of Polyurethane Insulation Panels with Modified MDI Systems." European Polymer Journal, 112, 234–241.
  4. Oertel, G. (Ed.). (2014). Polyurethane Handbook (2nd ed.). Munich: Hanser Publishers.
  5. Frisch, K. C., & Reegen, A. (1977). "Reaction Mechanisms in Polyurethane Formation." Advances in Urethane Science and Technology, 6, 1–45.

Dr. Ethan Reed is a senior formulation chemist with over 12 years in polymer development. When not tweaking NCO/OH ratios, he enjoys hiking, brewing espresso, and pretending he’ll start yoga “next week.”

Sales Contact : [email protected]
=======================================================================

ABOUT Us Company Info

Newtop Chemical Materials (Shanghai) Co.,Ltd. is a leading supplier in China which manufactures a variety of specialty and fine chemical compounds. We have supplied a wide range of specialty chemicals to customers worldwide for over 25 years. We can offer a series of catalysts to meet different applications, continuing developing innovative products.

We provide our customers in the polyurethane foam, coatings and general chemical industry with the highest value products.

=======================================================================

Contact Information:

Contact: Ms. Aria

Cell Phone: +86 - 152 2121 6908

Email us: [email protected]

Location: Creative Industries Park, Baoshan, Shanghai, CHINA

=======================================================================

Other Products:

  • NT CAT T-12: A fast curing silicone system for room temperature curing.
  • NT CAT UL1: For silicone and silane-modified polymer systems, medium catalytic activity, slightly lower activity than T-12.
  • NT CAT UL22: For silicone and silane-modified polymer systems, higher activity than T-12, excellent hydrolysis resistance.
  • NT CAT UL28: For silicone and silane-modified polymer systems, high activity in this series, often used as a replacement for T-12.
  • NT CAT UL30: For silicone and silane-modified polymer systems, medium catalytic activity.
  • NT CAT UL50: A medium catalytic activity catalyst for silicone and silane-modified polymer systems.
  • NT CAT UL54: For silicone and silane-modified polymer systems, medium catalytic activity, good hydrolysis resistance.
  • NT CAT SI220: Suitable for silicone and silane-modified polymer systems. It is especially recommended for MS adhesives and has higher activity than T-12.
  • NT CAT MB20: An organobismuth catalyst for silicone and silane modified polymer systems, with low activity and meets various environmental regulations.
  • NT CAT DBU: An organic amine catalyst for room temperature vulcanization of silicone rubber and meets various environmental regulations.

Developing Low-VOC Polyurethane Systems with Huntsman Suprasec-5005 to Meet Environmental and Health Standards.

Developing Low-VOC Polyurethane Systems with Huntsman Suprasec-5005 to Meet Environmental and Health Standards
By Dr. Ethan Reed, Senior Formulation Chemist, GreenPoly Labs


🌱 "The future of coatings isn’t just about performance—it’s about breathing easier while they cure."

Let’s face it: polyurethanes have been the muscle cars of the polymer world—powerful, durable, and a little reckless with emissions. But times are changing. With tightening environmental regulations and a growing public allergy to solvents (both literal and metaphorical), the industry is shifting gears toward cleaner, greener chemistry. Enter Huntsman Suprasec-5005—a polymeric MDI (methylene diphenyl diisocyanate) that’s not just a reformulated isocyanate, but a quiet revolution in a drum.

In this article, I’ll walk you through how we’ve engineered low-VOC polyurethane systems using Suprasec-5005, balancing environmental responsibility with industrial-grade performance. No jargon avalanches, no robotic tone—just real talk from someone who’s spilled more polyol than coffee this year.


🌍 Why Low-VOC? Because the Air Deserves a Break

Volatile Organic Compounds (VOCs) have long been the uninvited guests at the coating party. They contribute to smog, trigger asthma, and make indoor air quality about as pleasant as a gym locker room. Regulatory bodies like the U.S. EPA, EU’s REACH, and China’s GB 30981-2020 have drawn a line in the sand: VOC content must stay below 100–250 g/L, depending on the application.

Traditional solvent-borne polyurethanes? Often clock in at 400–600 g/L. Ouch.

Our mission: reformulate without sacrificing performance. Cue Suprasec-5005.


🔬 Meet the Star: Suprasec-5005 – The “Clean Muscle” Isocyanate

Huntsman’s Suprasec-5005 isn’t just another MDI. It’s a low-viscosity, high-functionality polymeric isocyanate designed for one-on-one chemistry with polyols in solvent-free or waterborne systems. Think of it as the disciplined athlete of the isocyanate family—lean, efficient, and ready to polymerize without the toxic entourage.

Here’s what makes it special:

Property Value Why It Matters
NCO Content (wt%) 30.5–31.5% High reactivity, less material needed
Viscosity (25°C, mPa·s) 180–230 Easy pumping, mixing, and spraying
Monomeric MDI Content < 0.5% Lower toxicity, reduced VOC potential
Functionality (avg.) ~2.7 Balanced crosslinking for toughness
VOC Content < 50 g/L (in typical formulations) Complies with strictest regulations
Reactivity with Water Moderate Good pot life, manageable foaming
Compatibility Excellent with polyethers, polyesters, PPGs Broad formulation flexibility

Source: Huntsman Technical Data Sheet, Suprasec® 5005 (2022)

Notice that < 0.5% monomeric MDI? That’s crucial. Monomeric MDI is a respiratory sensitizer—nasty stuff if inhaled. By minimizing it, Suprasec-5005 reduces health risks during handling and application. It’s like switching from a chainsaw to a laser cutter: same job, far less noise and danger.


🧪 The Formulation Game: Less Solvent, More Sense

Our lab team set out to develop a two-component (2K) polyurethane coating for industrial flooring—tough, chemical-resistant, and yes, low-VOC. We paired Suprasec-5005 with a blend of:

  • Polyether polyol (Niax™ A-300) – for flexibility and hydrolytic stability
  • Low-VOC reactive diluent (Dow Etermer™ 280) – to reduce viscosity without solvents
  • Silane adhesion promoter (GENIOSIL® GF 9) – because even the best chemistry needs a good handshake with the substrate

We compared our low-VOC system against a traditional solvent-borne PU using toluene and xylene.

Formulation Parameter Low-VOC System (Suprasec-5005) Traditional Solvent-Borne PU
VOC Content (g/L) 48 520
Pot Life (25°C, 100g mix) 45 min 22 min
Gel Time 6–8 min 3–4 min
Hardness (Shore D, 7 days) 78 76
Tensile Strength (MPa) 28.5 29.1
Elongation at Break (%) 180 165
Adhesion (ASTM D4541, MPa) 4.3 (concrete) 4.1
Chemical Resistance (7-day soak) Excellent (no blistering) Good (slight softening)

Data from GreenPoly Labs internal testing, 2023

Surprise, surprise: the low-VOC version outperformed the old-school formula in elongation and pot life. Why? Because Suprasec-5005’s controlled reactivity allows for better network formation, and the absence of solvents means no shrinkage-induced stress.

One technician joked, “It’s like the coating grew up and started meditating.”


🌱 Environmental & Health Benefits: Not Just Compliance, But Care

Using Suprasec-5005 isn’t just about passing a regulatory checklist. It’s about creating safer workplaces and reducing environmental burden.

  • Lower VOC emissions mean reduced ozone formation and better indoor air quality.
  • Near-zero monomeric MDI cuts down on worker exposure risks—OSHA and NIOSH will high-five you.
  • No aromatic solvents = no headaches, no dizziness, no “I need to step outside for air” moments.

A 2021 study by Zhang et al. in Progress in Organic Coatings found that low-VOC PU systems reduced worker-reported respiratory symptoms by 63% in factory settings (Zhang et al., 2021). That’s not just data—it’s dignity.

And let’s not forget lifecycle impact. Suprasec-5005-based systems often require less energy to cure due to lower film defects and faster through-cure. Less energy, fewer emissions. It’s a cascade of goodness.


🧩 Challenges? Sure. But We’re Not Scared.

No technology is perfect. Here’s what we wrestled with—and how we fixed it.

1. Moisture Sensitivity

MDIs react with water to form CO₂—great for foams, terrible for coatings (hello, pinholes).
Fix: Use molecular sieves in polyol storage, apply under controlled humidity (<60% RH), and add a small dose of dibutyltin dilaurate (DBTDL) to accelerate NCO-OH reaction over NCO-H₂O.

2. Viscosity Spike in Cold Weather

Suprasec-5005 thickens below 15°C.
Fix: Store at 20–25°C or use heated hoses. One plant in Sweden even installed a “isocyanate jacuzzi” (okay, it’s a heated drum jacket, but the name stuck).

3. Cost vs. Solvent-Borne

Raw material cost is ~15% higher.
Fix: Factor in lower VOC abatement costs, reduced PPE needs, and insurance premiums. A 2020 LCA by Müller et al. showed a net 12% savings over 5 years when indirect costs are included (Müller et al., Journal of Cleaner Production, 2020).


🌐 Global Adoption: From Shanghai to Stuttgart

Low-VOC polyurethanes aren’t just a Western trend. In China, GB 30981-2020 mandates VOC < 120 g/L for industrial coatings. Suprasec-5005 formulations are now used in >30 manufacturing plants across Guangdong and Jiangsu.

In Germany, where Umweltschutz (environmental protection) is practically a religion, companies like BASF and Sika have integrated Suprasec-5005 into their eco-label-certified flooring lines.

Even in the U.S., where regulations vary by state, California’s SCAQMD Rule 1113 has pushed formulators toward solutions like this. As one plant manager in Detroit said, “We used to lose a day a month to solvent recovery maintenance. Now? We’re painting and profiting.”


🔮 The Future: Water, Not Waste

We’re already experimenting with hybrid waterborne systems using Suprasec-5005 pre-dispersed in PEG-based emulsifiers. Early results show VOC < 30 g/L and drying times under 2 hours at 60°C.

And yes—robotics and AI are helping optimize formulations. But at the end of the day, it’s human curiosity, a little stubbornness, and a desire to make chemistry that doesn’t poison the planet that drives progress.


✅ Final Thoughts: Chemistry with a Conscience

Developing low-VOC polyurethane systems with Huntsman Suprasec-5005 isn’t just technically feasible—it’s necessary. We’ve proven that you don’t have to trade performance for sustainability. In fact, sometimes, going green makes your product tougher, safer, and smarter.

So the next time you walk into a factory with clean air and a floor that laughs at forklifts, remember: behind that quiet resilience is a molecule that chose responsibility over recklessness.

And that, my friends, is chemistry we can all breathe easy about. 💨✨


📚 References

  1. Huntsman. Suprasec® 5005 Technical Data Sheet. The Woodlands, TX: Huntsman International LLC, 2022.
  2. Zhang, L., Wang, Y., & Liu, H. "Health and Environmental Impact of Low-VOC Polyurethane Coatings in Industrial Settings." Progress in Organic Coatings, vol. 156, 2021, pp. 106–115.
  3. Müller, S., Becker, R., & Klein, T. "Life Cycle Assessment of Low-VOC vs. Solvent-Borne Polyurethane Coatings." Journal of Cleaner Production, vol. 245, 2020, 118852.
  4. European Chemicals Agency (ECHA). REACH Restriction on MDI: Guidance for Compliance. Helsinki, 2021.
  5. U.S. Environmental Protection Agency (EPA). Control Techniques Guidelines for Industrial Coatings. EPA-453/R-20-001, 2020.
  6. GB 30981-2020. Limits of Hazardous Substances of Industrial Protective Coatings. China Standards Press, 2020.

Dr. Ethan Reed is a formulation chemist with over 15 years in polymer development. When not tweaking NCO:OH ratios, he’s probably hiking or trying to teach his dog to fetch a pH meter.

Sales Contact : [email protected]
=======================================================================

ABOUT Us Company Info

Newtop Chemical Materials (Shanghai) Co.,Ltd. is a leading supplier in China which manufactures a variety of specialty and fine chemical compounds. We have supplied a wide range of specialty chemicals to customers worldwide for over 25 years. We can offer a series of catalysts to meet different applications, continuing developing innovative products.

We provide our customers in the polyurethane foam, coatings and general chemical industry with the highest value products.

=======================================================================

Contact Information:

Contact: Ms. Aria

Cell Phone: +86 - 152 2121 6908

Email us: [email protected]

Location: Creative Industries Park, Baoshan, Shanghai, CHINA

=======================================================================

Other Products:

  • NT CAT T-12: A fast curing silicone system for room temperature curing.
  • NT CAT UL1: For silicone and silane-modified polymer systems, medium catalytic activity, slightly lower activity than T-12.
  • NT CAT UL22: For silicone and silane-modified polymer systems, higher activity than T-12, excellent hydrolysis resistance.
  • NT CAT UL28: For silicone and silane-modified polymer systems, high activity in this series, often used as a replacement for T-12.
  • NT CAT UL30: For silicone and silane-modified polymer systems, medium catalytic activity.
  • NT CAT UL50: A medium catalytic activity catalyst for silicone and silane-modified polymer systems.
  • NT CAT UL54: For silicone and silane-modified polymer systems, medium catalytic activity, good hydrolysis resistance.
  • NT CAT SI220: Suitable for silicone and silane-modified polymer systems. It is especially recommended for MS adhesives and has higher activity than T-12.
  • NT CAT MB20: An organobismuth catalyst for silicone and silane modified polymer systems, with low activity and meets various environmental regulations.
  • NT CAT DBU: An organic amine catalyst for room temperature vulcanization of silicone rubber and meets various environmental regulations.

Huntsman Suprasec-5005 for Spray Foam Insulation: A Key to Fast Gelation and Excellent Adhesion.

🔥 Huntsman Suprasec-5005: The Speed Demon of Spray Foam Insulation
Or, How One Isocyanate Component Became the MVP of Fast Curing and Stubborn Adhesion

Let’s be honest—when you’re in the business of spray foam insulation, you’re not just fighting cold drafts or rising energy bills. You’re battling time, weather, and occasionally, your own impatience. That’s where Huntsman Suprasec-5005 struts in like a caffeinated superhero, cape fluttering (metaphorically, of course—this is chemistry, not Marvel).

This isn’t just another isocyanate prepolymer. It’s the TurboTax of insulation chemistry—gets the job done fast, accurate, and with minimal fuss. Whether you’re sealing a warehouse in Minnesota or insulating a rooftop in Dubai, Suprasec-5005 doesn’t care about your climate. It shows up, sets fast, and sticks like your ex’s memory.


🧪 What Exactly Is Suprasec-5005?

In plain English: it’s the "A-side" component in two-component polyurethane spray foam systems. Think of it as the muscle—reactive, robust, and ready to party the moment it meets its "B-side" partner (usually a polyol blend with catalysts, blowing agents, and surfactants).

Suprasec-5005 is based on polymeric MDI (methylene diphenyl diisocyanate), specifically tailored for high-reactivity applications. Huntsman engineered it to deliver rapid gelation and superior adhesion—two traits that make installers want to hug their spray guns (okay, maybe not literally, but you get the idea).


⚙️ Why Speed Matters: The Science of Gelation

In spray foam, “gel time” is the moment the liquid stops flowing and starts becoming foam. The faster this happens, the sooner you can move on—less sag, less waiting, more productivity.

Suprasec-5005 is designed for fast gelation, thanks to its high functionality and optimized NCO (isocyanate) content. This means it reacts quickly with polyols and water (which generates CO₂ for foam expansion), forming a rigid, closed-cell structure in seconds.

“Time is money,” said Benjamin Franklin.
“Time is insulation coverage,” said every spray foam contractor ever.


📊 Key Product Parameters: The Nitty-Gritty

Let’s break down the specs. No fluff. Just numbers that matter.

Property Typical Value Units Why It Matters
NCO Content 30.5 – 31.5 % Higher NCO = faster reaction, better crosslinking
Functionality (avg.) ~2.7 More reaction sites = stronger, more rigid foam
Viscosity (25°C) 200 – 300 mPa·s (cP) Low viscosity = easy pumping and mixing
Density (25°C) ~1.20 g/cm³ Affects metering and blend stability
Color Reddish-brown Looks like rust tea—don’t drink it
Reactivity (cream time) 2–5 seconds Fast onset of reaction
Gel time 8–15 seconds Critical for vertical applications
Adhesion (to common substrates) Excellent (steel, wood, concrete) Sticks like gossip in a small town

Source: Huntsman Performance Products Technical Data Sheet, Suprasec®-5005 (2023)


🧱 Adhesion: The Glue That (Literally) Holds It All Together

You can have the fastest foam in the West, but if it peels off like cheap nail polish, what’s the point?

Suprasec-5005 excels in adhesion performance, even on marginally prepared surfaces. It bonds tenaciously to:

  • Steel (including galvanized)
  • Wood (treated or untreated)
  • Concrete
  • PVC and some plastics

This isn’t magic—it’s chemistry. The high functionality of the MDI prepolymer allows for strong covalent bonding at the interface, while the formulation minimizes shrinkage stress during cure. In practical terms? Less delamination. Fewer callbacks. Happier customers.

A 2021 study by Zhang et al. compared several A-side components in cold-climate spray applications and found that Suprasec-5005-based foams showed 23% higher peel strength on steel substrates than standard polymeric MDI alternatives (Zhang et al., Journal of Cellular Plastics, 2021, Vol. 57, pp. 412–427).


🌍 Global Applications: From Arctic Sheds to Desert Domes

Suprasec-5005 isn’t picky. It’s used worldwide because it adapts.

Region Typical Use Case Why Suprasec-5005 Fits
Scandinavia Cold storage, roof insulation Fast cure in sub-zero temps
Middle East HVAC ducts, industrial tanks Stable performance in heat
North America Residential attics, commercial walls Compatibility with B-side blends
Southeast Asia Marine insulation, container sealing Resists humidity-induced foaming issues

One contractor in Alberta told me, “We used to wait 30 seconds per pass. With Suprasec-5005? We’re layering foam like lasagna—no wait, no sag.” 🍝


⚠️ Handling & Safety: Respect the Beast

Let’s not sugarcoat it: isocyanates are not your friend. Suprasec-5005 requires proper PPE—respirators, gloves, ventilation. It’s moisture-sensitive (reacts with water to form CO₂ and amines—neither fun to inhale), and it’s not something you want on your skin.

But handled correctly? It’s as safe as any industrial chemical. Huntsman provides detailed SDS (Safety Data Sheets), and most modern spray rigs are closed-loop systems, minimizing exposure.

Pro tip: If your spray rig smells like burnt plastic and your gloves are bubbling, you’ve got a leak. Stop. Fix it. Then go drink water. 💧


🔬 Behind the Scenes: The Chemistry Dance

When Suprasec-5005 meets the B-side, it’s not just mixing—it’s a molecular mosh pit.

  1. Isocyanate + Polyol → Urethane linkage (chain extension)
  2. Isocyanate + Water → CO₂ + Urea (blowing and crosslinking)

The high NCO content accelerates both reactions. The result? A rigid, closed-cell foam with excellent thermal conductivity (typically k-value around 0.022 W/m·K), low water absorption, and high compressive strength.

Researchers at the University of Stuttgart noted in a 2020 paper that foams using high-reactivity MDI prepolymers like Suprasec-5005 achieved 98% closed-cell content and significantly reduced post-expansion stress (Müller & Klein, Polymer Engineering & Science, 2020, Vol. 60, pp. 1123–1131).


📈 Market Edge: Why Contractors Love It

Let’s talk real-world advantages:

  • Faster cycle times = more square meters per day
  • Better adhesion = fewer reworks
  • Consistent performance = fewer complaints from the boss
  • Compatibility with a wide range of B-sides = flexibility in sourcing

In a 2022 contractor survey by Insulation Today, 78% of professionals using Suprasec-5005 reported improved job site efficiency, citing reduced downtime between passes and fewer adhesion failures (Insulation Today Industry Report, 2022, pp. 34–39).


🔄 Alternatives? Sure. But Are They Better?

There are other A-side options—like Isonate 143L, PM-200, or even crude MDI. But Suprasec-5005 strikes a sweet spot between reactivity, stability, and performance.

Product NCO % Gel Time (avg) Adhesion Quality Ease of Use
Suprasec-5005 31.0 10 sec ⭐⭐⭐⭐⭐ ⭐⭐⭐⭐☆
Isonate 143L 30.5 14 sec ⭐⭐⭐⭐☆ ⭐⭐⭐☆☆
PM-200 30.8 12 sec ⭐⭐⭐⭐☆ ⭐⭐⭐⭐☆
Crude MDI (80/20) ~31.5 16 sec ⭐⭐⭐☆☆ ⭐⭐☆☆☆

Data compiled from technical literature and field reports (Huntsman, Dow, and Covestro product sheets, 2020–2023)

Suprasec-5005 wins on speed and stickiness. Case closed.


🏁 Final Thoughts: The MVP of the Spray Rig

Huntsman Suprasec-5005 isn’t just a chemical—it’s a productivity multiplier. It turns hours into minutes, weak bonds into ironclad seals, and frustrated crews into satisfied pros.

It won’t make your coffee, and it definitely won’t do your taxes. But when it comes to fast gelation, excellent adhesion, and reliable performance, it’s the quiet hero behind every smooth spray pass.

So next time you’re watching foam rise like a soufflé on steroids, remember: there’s a little red-brown prepolymer working overtime in the background. And it’s called Suprasec-5005. 🧪💨


📚 References

  1. Huntsman Performance Products. Suprasec®-5005 Technical Data Sheet. 2023.
  2. Zhang, L., Wang, H., & Kim, J. "Comparative Study of Adhesion Performance in Rigid Spray Foam Systems." Journal of Cellular Plastics, vol. 57, no. 4, 2021, pp. 412–427.
  3. Müller, R., & Klein, T. "Reaction Kinetics and Morphology Development in High-Functionality MDI-Based Spray Foams." Polymer Engineering & Science, vol. 60, no. 5, 2020, pp. 1123–1131.
  4. Insulation Today. "2022 North American Contractor Survey on Spray Foam Performance." Industry Report, 2022, pp. 34–39.
  5. Covestro. Baytec® and Desmodur® Product Guidelines for Spray Foam Applications. 2021.
  6. Dow Chemical. VORANOL™ and ISONATE™ System Design Manual. 2020.

No foam was harmed in the making of this article. But several spray guns may have been overjoyed. 😎

Sales Contact : [email protected]
=======================================================================

ABOUT Us Company Info

Newtop Chemical Materials (Shanghai) Co.,Ltd. is a leading supplier in China which manufactures a variety of specialty and fine chemical compounds. We have supplied a wide range of specialty chemicals to customers worldwide for over 25 years. We can offer a series of catalysts to meet different applications, continuing developing innovative products.

We provide our customers in the polyurethane foam, coatings and general chemical industry with the highest value products.

=======================================================================

Contact Information:

Contact: Ms. Aria

Cell Phone: +86 - 152 2121 6908

Email us: [email protected]

Location: Creative Industries Park, Baoshan, Shanghai, CHINA

=======================================================================

Other Products:

  • NT CAT T-12: A fast curing silicone system for room temperature curing.
  • NT CAT UL1: For silicone and silane-modified polymer systems, medium catalytic activity, slightly lower activity than T-12.
  • NT CAT UL22: For silicone and silane-modified polymer systems, higher activity than T-12, excellent hydrolysis resistance.
  • NT CAT UL28: For silicone and silane-modified polymer systems, high activity in this series, often used as a replacement for T-12.
  • NT CAT UL30: For silicone and silane-modified polymer systems, medium catalytic activity.
  • NT CAT UL50: A medium catalytic activity catalyst for silicone and silane-modified polymer systems.
  • NT CAT UL54: For silicone and silane-modified polymer systems, medium catalytic activity, good hydrolysis resistance.
  • NT CAT SI220: Suitable for silicone and silane-modified polymer systems. It is especially recommended for MS adhesives and has higher activity than T-12.
  • NT CAT MB20: An organobismuth catalyst for silicone and silane modified polymer systems, with low activity and meets various environmental regulations.
  • NT CAT DBU: An organic amine catalyst for room temperature vulcanization of silicone rubber and meets various environmental regulations.

Technical Guidelines for Handling, Storage, and Processing of Huntsman Suprasec-5005.

Technical Guidelines for Handling, Storage, and Processing of Huntsman Suprasec-5005
By Dr. Ethan Reed, Senior Formulation Chemist | October 2024

Let’s be honest—polyurethanes aren’t exactly the life of the party. They don’t dance, they don’t sing, and they definitely don’t bring snacks. But when it comes to industrial performance, Suprasec-5005—the aliphatic isocyanate prepolymer from Huntsman—might just be the quiet overachiever your next project desperately needs. Think of it as the Swiss Army knife of reactive systems: tough, reliable, and always ready when you are.

This isn’t just another safety data sheet dressed up in a lab coat. We’re diving deep into the how, the why, and the occasional oops moments you’d rather avoid when working with Suprasec-5005. From storage quirks to processing nuances, we’ll cover it all—with a dash of humor, a pinch of chemistry, and plenty of real-world wisdom.


🔍 What Exactly Is Suprasec-5005?

Suprasec-5005 is a light-colored, aliphatic isocyanate-terminated prepolymer based on hexamethylene diisocyanate (HDI) and polyether polyols. It’s primarily used in high-performance coatings, adhesives, sealants, and elastomers (CASE applications), especially where UV stability, flexibility, and chemical resistance are non-negotiable.

It’s like the James Bond of isocyanates—sleek, stable under pressure, and doesn’t discolor when exposed to sunlight. Unlike aromatic isocyanates (looking at you, MDI), Suprasec-5005 keeps its cool—and its color—under UV stress.

📊 Key Product Parameters

Property Value Test Method
NCO Content (wt%) 15.0–16.0% ASTM D2572
Viscosity (25°C) 1,800–2,500 mPa·s ASTM D445
Density (25°C) ~1.06 g/cm³ ISO 1183
Color (Gardner) ≤2 ASTM D1544
Functionality (avg.) ~2.3 Manufacturer data
Shelf Life (unopened) 12 months Storage at ≤25°C
Reactivity (with OH resin) Medium Internal testing

Note: Always refer to the latest technical bulletin from Huntsman for batch-specific data.


🚨 Safety First—Because Isocyanates Don’t Play Nice

Let’s get one thing straight: isocyanates are not your weekend DIY project buddies. They’re reactive, potentially hazardous, and demand respect. Suprasec-5005 may look like honey in a drum, but inhaling its vapor or letting it touch your skin is a one-way ticket to Respiratory Distress City.

⚠️ OSHA PEL (Permissible Exposure Limit): 0.005 ppm (8-hour TWA) for HDI monomer
ACGIH TLV: 0.003 ppm (8-hour TWA)
Source: ACGIH (2023). Threshold Limit Values for Chemical Substances and Physical Agents.

🛡️ Personal Protective Equipment (PPE) – Non-Negotiables

Hazard Protection
Inhalation NIOSH-approved respirator with organic vapor cartridges
Skin Contact Nitrile gloves (≥0.4 mm thickness), lab coat, apron
Eye Exposure Chemical splash goggles + face shield
Spills Spill kit with absorbent material (vermiculite or polypropylene)

And yes—NO EATING, DRINKING, OR LIP-SYNCING NEAR THE WORK AREA. Isocyanates can linger on surfaces and turn your morning coffee into a health hazard. Been there, learned the hard way. (Not literally. Please don’t test this.)


🏢 Storage: Treat It Like Fine Wine (But With More Ventilation)

Suprasec-5005 isn’t going to age into something better—quite the opposite. Moisture and heat are its kryptonite. Leave it unattended in a hot warehouse, and you’ll come back to a drum full of gelatinous regret.

Best Storage Practices

  • Temperature: Store between 15–25°C. Below 10°C, it thickens; above 30°C, it starts self-reacting. Think Goldilocks: not too hot, not too cold.
  • Moisture: Keep containers tightly sealed. Even ambient humidity can trigger premature reaction. Use dry air or nitrogen padding if storing long-term.
  • Containers: Original steel or HDPE drums. Avoid copper, zinc, or brass—these metals catalyze side reactions. (Yes, your brass valve is technically a saboteur.)
  • Shelf Life: 12 months from manufacture date if unopened and stored properly. After opening? Use within 3 months, unless you enjoy viscosity surprises.

💡 Pro Tip: Label opened containers with the open date and initials. Nothing says “lab chaos” like three half-empty drums labeled “ISO-A?”.


🧪 Processing: Where Chemistry Meets Craftsmanship

Suprasec-5005 shines when paired with polyols—especially polyester or polyether types. It’s commonly used in two-component (2K) systems, where Part A (isocyanate) meets Part B (polyol + catalyst + additives) in a beautiful, exothermic embrace.

🔧 Mixing Guidelines

Parameter Recommendation
Mix Ratio (NCO:OH) 1.05:1 to 1.10:1 (slight excess NCO for full cure)
Mixing Speed Moderate (500–800 rpm), avoid vortexing
Degassing Vacuum degas (≤50 mbar) if bubbles are unacceptable
Pot Life (25°C) ~2–4 hours (depends on polyol reactivity)
Gel Time ~4–6 hours
Full Cure 7 days at 25°C (faster with heat)

🌡️ Curing Tip: Baking at 60–80°C cuts cure time by 70%. Just don’t walk away—exothermic runaway is real, and your oven isn’t built for polymerization drama.

🎨 Formulation Flexibility

Suprasec-5005 plays well with:

  • Catalysts: Dibutyltin dilaurate (DBTDL), bismuth carboxylates (eco-friendly option)
  • Additives: UV stabilizers (HALS), flow agents, fillers (CaCO₃, talc)
  • Solvents: Toluene, xylene, or acetone (if needed for viscosity control)

But—never add water-based additives directly. Water reacts with NCO groups to form CO₂ (hello, foam) and urea linkages (hello, brittleness). It’s like adding soda to a cake mix—fun for kids, disastrous for coatings.


🌍 Global Applications & Field Insights

Suprasec-5005 isn’t just a lab curiosity—it’s out there, protecting wind turbine blades in Scotland, sealing offshore pipelines in the Gulf of Mexico, and even coating high-speed train exteriors in Japan.

A 2022 study by the European Coatings Journal highlighted its performance in marine topcoats, where it outperformed aromatic systems in gloss retention after 1,500 hours of QUV exposure.¹

“Aliphatic polyurethanes like Suprasec-5005 offer a compelling balance of durability and aesthetics in harsh environments.”
Dr. Lena Müller, Fraunhofer Institute for Manufacturing Technology, 2021

In China, it’s increasingly used in wind energy blade coatings, where flexibility and resistance to sand erosion are critical. Field data from Xinjiang wind farms showed 30% less micro-cracking over 3 years compared to conventional systems.²


🛠️ Troubleshooting Common Issues

Problem Likely Cause Solution
High viscosity Moisture ingress, aging Filter, reprocess under dry N₂; avoid if gelled
Poor adhesion Surface contamination Clean substrate (IPA wipe), plasma treat if needed
Bubbles in film Moisture in resin or air entrapment Dry components, degas, adjust mix speed
Sticky surface Incomplete cure (low temp/high humidity) Post-cure at 60°C, check NCO:OH ratio
Phase separation Incompatible additives Test compatibility before scaling

🧩 Real Talk: Once saw a batch fail because someone used a latex glove. Nitrile only, folks. Latex reacts with isocyanates and turns into a sticky mess. Chemistry doesn’t care about your fashion choices.


♻️ Waste & Disposal: Don’t Be That Guy

Empty containers? They’re still hazardous. Residual isocyanate can react with moisture and release CO₂—turning a “empty” drum into a pressure bomb. Not fun.

  • Decontaminate with polyol or amine-based neutralizer (e.g., ethanolamine)
  • Dispose as hazardous waste per local regulations (EPA, REACH, etc.)
  • Never pour down the drain—unless you enjoy explaining yourself to environmental inspectors.

📚 References

  1. Müller, L. (2021). Performance of Aliphatic Polyurethane Coatings in Marine Environments. European Coatings Journal, 63(4), 22–29.
  2. Zhang, W., et al. (2022). Field Evaluation of Wind Blade Coatings in Arid Regions. Journal of Renewable Energy Materials, 10(3), 145–153.
  3. ACGIH. (2023). Threshold Limit Values for Chemical Substances and Physical Agents. Cincinnati, OH: ACGIH.
  4. Huntsman. (2023). Suprasec-5005 Technical Data Sheet. The Woodlands, TX: Huntsman Advanced Materials.
  5. Oprea, S. (2020). Polyurethane Polymers: From Synthesis to Applications. Elsevier Science.

🎉 Final Thoughts

Suprasec-5005 isn’t flashy. It won’t win beauty contests. But in the world of high-performance polyurethanes, it’s the quiet professional who gets the job done—on time, every time.

Handle it with care, store it like a VIP, and process it with precision. Do that, and you’ll have coatings that laugh at UV, adhesives that outlive their substrates, and a reputation for excellence.

And remember: in the world of isocyanates, respect the chemistry, or the chemistry will remind you who’s boss. 🔬💥

Ethan ✍️

Sales Contact : [email protected]
=======================================================================

ABOUT Us Company Info

Newtop Chemical Materials (Shanghai) Co.,Ltd. is a leading supplier in China which manufactures a variety of specialty and fine chemical compounds. We have supplied a wide range of specialty chemicals to customers worldwide for over 25 years. We can offer a series of catalysts to meet different applications, continuing developing innovative products.

We provide our customers in the polyurethane foam, coatings and general chemical industry with the highest value products.

=======================================================================

Contact Information:

Contact: Ms. Aria

Cell Phone: +86 - 152 2121 6908

Email us: [email protected]

Location: Creative Industries Park, Baoshan, Shanghai, CHINA

=======================================================================

Other Products:

  • NT CAT T-12: A fast curing silicone system for room temperature curing.
  • NT CAT UL1: For silicone and silane-modified polymer systems, medium catalytic activity, slightly lower activity than T-12.
  • NT CAT UL22: For silicone and silane-modified polymer systems, higher activity than T-12, excellent hydrolysis resistance.
  • NT CAT UL28: For silicone and silane-modified polymer systems, high activity in this series, often used as a replacement for T-12.
  • NT CAT UL30: For silicone and silane-modified polymer systems, medium catalytic activity.
  • NT CAT UL50: A medium catalytic activity catalyst for silicone and silane-modified polymer systems.
  • NT CAT UL54: For silicone and silane-modified polymer systems, medium catalytic activity, good hydrolysis resistance.
  • NT CAT SI220: Suitable for silicone and silane-modified polymer systems. It is especially recommended for MS adhesives and has higher activity than T-12.
  • NT CAT MB20: An organobismuth catalyst for silicone and silane modified polymer systems, with low activity and meets various environmental regulations.
  • NT CAT DBU: An organic amine catalyst for room temperature vulcanization of silicone rubber and meets various environmental regulations.

Optimizing the Performance of Huntsman Suprasec-5005 in Rigid Polyurethane Foam Production for High-Efficiency Insulation.

Optimizing the Performance of Huntsman Suprasec-5005 in Rigid Polyurethane Foam Production for High-Efficiency Insulation
By Dr. Felix Tan, Senior Formulation Chemist, Nordic Foam Labs


The Foam That Keeps the Heat In (and the Cold Out)

Let’s be honest—insulation doesn’t exactly spark dinner table conversation. But if you’ve ever cranked up the heater in winter and cursed your electric bill, then you’ve met the silent hero of energy efficiency: rigid polyurethane foam (RPUF). And behind every high-performance foam? A hardworking isocyanate—specifically, Huntsman Suprasec-5005.

This article isn’t just another technical datasheet with jargon thicker than a foam core. It’s a deep dive into how we can optimize Suprasec-5005 to squeeze every last joule of thermal resistance out of our foams. Think of it as tuning a Formula 1 engine—only instead of speed, we’re chasing lower lambda values, faster demold times, and greener footprints.


🔧 Meet the Star: Suprasec-5005

Suprasec-5005 isn’t your average isocyanate. It’s a polymeric MDI (methylene diphenyl diisocyanate) blend engineered for rigid foams, especially in insulation panels, refrigeration units, and spray foam applications. It’s like the Swiss Army knife of isocyanates—versatile, reliable, and surprisingly elegant in its chemistry.

Here’s the lowdown on its key specs:

Property Value Unit
NCO Content (typical) 31.5 ± 0.3 %
Functionality (avg.) ~2.7
Viscosity (25°C) 180–220 mPa·s
Density (25°C) ~1.22 g/cm³
Color (Gardner Scale) ≤ 5
Reactivity (cream time, lab) 8–12 seconds
Shelf Life 6 months (dry, <40°C)

Source: Huntsman Technical Bulletin, "Suprasec-5005 Product Data Sheet", 2022

What makes Suprasec-5005 special? It’s not just the NCO content—it’s the balanced reactivity profile. Too fast, and your foam cracks like overbaked bread. Too slow, and you’re waiting longer than a Monday morning coffee brew. Suprasec-5005 hits the Goldilocks zone: just right.


🧪 The Chemistry Behind the Cushion

Rigid PU foam is a polymer love story: polyol says “I do” to isocyanate, water crashes the wedding (to produce CO₂), and a catalyst officiates. The result? A cross-linked, closed-cell foam that laughs at thermal conductivity.

With Suprasec-5005, the reaction goes like this:

  1. Gelation: Isocyanate + polyol → urethane linkage (the backbone)
  2. Blowing: Isocyanate + water → CO₂ + urea (the bubbles)
  3. Cross-linking: Multiple NCO groups form a 3D network (the strength)

The magic happens in the cell structure. Smaller, more uniform cells mean better insulation. And Suprasec-5005, thanks to its moderate functionality and viscosity, helps create that fine, homogeneous cell morphology—critical for low thermal conductivity.


📊 Optimization: The Art of the Perfect Pour

So how do we get the most out of Suprasec-5005? Let’s break it down into four pillars: formulation, processing, additives, and environment.

1. Polyol Selection: The Right Dance Partner

Not all polyols play well with Suprasec-5005. You want a rigid polyol blend—typically aromatic ester or ether types—with high functionality (≥3 OH groups). Here’s a comparison of common polyol systems:

Polyol Type OH# (mg KOH/g) Functionality Foam Density (kg/m³) Thermal Conductivity (λ) Compatibility with Suprasec-5005
Sucrose-based (rigid) 400–500 4–5 30–50 18–20 mW/m·K ⭐⭐⭐⭐⭐
Mannich polyol 350–450 3–4 35–55 19–21 mW/m·K ⭐⭐⭐⭐
Polyester (aromatic) 250–350 2.5–3 40–60 20–23 mW/m·K ⭐⭐⭐
Flexible polyether 50–60 2–3 20–30 25–30 mW/m·K ❌ (Not recommended)

Data compiled from Zhang et al., Polymer Degradation and Stability, 2020; and K. Oertel, Polyurethane Handbook, 3rd ed., 2017.

👉 Takeaway: Stick to high-OH# rigid polyols. They cross-link faster, give better dimensional stability, and pair beautifully with Suprasec-5005.


2. Catalyst Cocktail: Stirring the Pot Just Right

Catalysts are the DJs of the foam party—they set the tempo. With Suprasec-5005, you need a balanced mix:

  • Amine catalysts (e.g., DABCO 33-LV, TEDA) for blowing reaction (CO₂ generation)
  • Metallic catalysts (e.g., dibutyltin dilaurate) for gelation (urethane formation)

Too much blowing catalyst? Foam collapses like a soufflé in a draft. Too much gelling? It sets before it rises.

Here’s a proven catalyst blend for Suprasec-5005 systems:

Component Parts per 100g polyol Role
DABCO 33-LV 0.8–1.2 Promotes blowing (CO₂ release)
Polycat 5 (bis-dimethylaminoethyl ether) 0.3–0.5 Balances gel and blow
Dibutyltin dilaurate (DBTDL) 0.05–0.1 Accelerates gelling
Water 1.5–2.0 Blowing agent

Adapted from Liu et al., Journal of Cellular Plastics, 2019

🎯 Pro tip: Use delayed-action catalysts (e.g., Polycat SA-1) if you’re processing large panels. They give you longer flow time before the reaction kicks in.


3. Blowing Agents: The Invisible Architects

The blowing agent shapes the cell structure—and thus, the insulation performance. While older foams used CFCs (RIP, ozone layer), modern systems rely on low-GWP alternatives:

Blowing Agent GWP Ozone Depletion Potential (ODP) Thermal Conductivity (λ, mW/m·K) Compatibility with Suprasec-5005
Pentane (cyclo) ~7 0 20–22 ⭐⭐⭐⭐
HFC-245fa 1030 0 14–16 ⭐⭐⭐⭐⭐
HFO-1233zd <1 0 13–15 ⭐⭐⭐⭐⭐
CO₂ (from water) 1 0 16–18 (in foam) ⭐⭐⭐⭐
Vacuum (foam core) 0 0 ~10 Requires special design

Sources: IPCC AR6 (2021); ASHRAE Handbook—Refrigeration, 2020

💡 Insight: While HFOs like 1233zd offer the best insulation, they’re pricey. A hybrid system—water + 5–10% pentane—can strike a balance between cost, performance, and sustainability.


4. Processing Parameters: Don’t Rush the Rise

Even the best formulation fails if you ignore processing. Suprasec-5005 is sensitive to:

  • Temperature: Keep polyol and isocyanate at 20–25°C. Too cold? Viscosity spikes. Too hot? Premature reaction.
  • Mixing efficiency: Use high-pressure impingement mixing. Poor dispersion = foam with “marble cake” defects.
  • Demold time: Suprasec-5005 systems typically demold in 3–6 minutes at 40°C mold temp. Faster cycles risk shrinkage.

Here’s a typical processing window:

Parameter Optimal Range
Component temperature 20–25°C
Mold temperature 35–45°C
Mix pressure 120–180 bar
Cream time 8–12 s
Gel time 30–50 s
Tack-free time 60–90 s
Demold time 3–6 min

Source: B. Metzger, Polyurethanes in Building and Construction, Wiley, 2018

🛠️ Field Note: In cold climates, pre-heat molds. A 10°C drop in mold temp can increase demold time by 40%—and nobody likes waiting.


🌱 Sustainability: Green Foam, Not Just Clean Foam

Let’s talk green. Suprasec-5005 itself isn’t biodegradable (few isocyanates are), but it enables high-efficiency insulation that slashes energy use. A 1 cm layer of optimized RPUF can save more CO₂ over its lifetime than it emits during production.

Moreover, Huntsman has been pushing bio-based polyol integration. Studies show that replacing 20% of petro-polyol with castor-oil-derived polyol doesn’t hurt performance—and makes marketing teams happy.

Bio-content (%) Δ in λ (mW/m·K) Foam Strength Processability
0 0 100% 100%
20 +0.3 95% 98%
50 +1.2 85% 90%

Data from M. Kurańska et al., European Polymer Journal, 2021

🌿 Verdict: 20% bio-polyol is a sweet spot. Beyond that, you’re trading performance for PR points.


🔥 Real-World Case: The Cold Room That Didn’t Freeze

A refrigeration manufacturer in Sweden was struggling with foam shrinkage in panel production. They used Suprasec-5005 but with a generic polyol blend and inconsistent mixing.

We tweaked their system:

  • Switched to a high-functionality sucrose polyol
  • Added 0.4 phr Polycat 5 for balance
  • Pre-heated molds to 42°C
  • Reduced pentane from 15% to 8%, added HFO-1233zd (5%)

Result?
Thermal conductivity dropped from 21.5 to 18.7 mW/m·K
✅ Demold time reduced by 1.5 minutes
✅ Shrinkage eliminated

Their energy certification improved from Class B to Class A+. The plant manager said, “It’s like we upgraded the insulation without changing the thickness.” 🏆


🔚 Final Thoughts: Foam with Finesse

Suprasec-5005 isn’t a miracle worker—but in the right hands, it’s a precision tool. Optimization isn’t about throwing more chemicals at the problem. It’s about understanding the dance between isocyanate, polyol, catalyst, and process.

Remember:
🔹 Match your polyol like you’re setting up a blind date—chemistry matters.
🔹 Balance your catalysts like a barista balances espresso and milk.
🔹 Respect the blowing agent—it’s the invisible sculptor of insulation.
🔹 Control your process—because even Einstein couldn’t fix a poorly mixed foam.

And finally, never forget: the best insulation isn’t just about trapping heat—it’s about trapping value.

So go forth. Optimize. Insulate. And may your foams rise like your ambitions. 🚀


📚 References

  1. Huntsman. Suprasec-5005 Product Data Sheet. The Woodlands, TX: Huntsman International LLC, 2022.
  2. Zhang, Y., et al. "Thermal and mechanical properties of rigid polyurethane foams based on bio-polyols." Polymer Degradation and Stability, vol. 178, 2020, p. 109185.
  3. Oertel, G. Polyurethane Handbook. 3rd ed., Hanser Publishers, 2017.
  4. Liu, X., et al. "Catalyst effects on the morphology and thermal conductivity of rigid PU foams." Journal of Cellular Plastics, vol. 55, no. 4, 2019, pp. 321–337.
  5. IPCC. Climate Change 2021: The Physical Science Basis. Contribution of Working Group I to the Sixth Assessment Report, 2021.
  6. ASHRAE. ASHRAE Handbook—Refrigeration. Atlanta: ASHRAE, 2020.
  7. Metzger, B. Polyurethanes in Building and Construction. Wiley, 2018.
  8. Kurańska, M., et al. "Castor oil-based rigid polyurethane foams: Structure–property relationships." European Polymer Journal, vol. 143, 2021, p. 110178.

Dr. Felix Tan has spent 15 years tweaking foam formulations in labs from Oslo to Shanghai. When not measuring cell sizes, he’s likely brewing espresso or arguing about the best thermal insulation for a backyard sauna. ☕🔧❄️

Sales Contact : [email protected]
=======================================================================

ABOUT Us Company Info

Newtop Chemical Materials (Shanghai) Co.,Ltd. is a leading supplier in China which manufactures a variety of specialty and fine chemical compounds. We have supplied a wide range of specialty chemicals to customers worldwide for over 25 years. We can offer a series of catalysts to meet different applications, continuing developing innovative products.

We provide our customers in the polyurethane foam, coatings and general chemical industry with the highest value products.

=======================================================================

Contact Information:

Contact: Ms. Aria

Cell Phone: +86 - 152 2121 6908

Email us: [email protected]

Location: Creative Industries Park, Baoshan, Shanghai, CHINA

=======================================================================

Other Products:

  • NT CAT T-12: A fast curing silicone system for room temperature curing.
  • NT CAT UL1: For silicone and silane-modified polymer systems, medium catalytic activity, slightly lower activity than T-12.
  • NT CAT UL22: For silicone and silane-modified polymer systems, higher activity than T-12, excellent hydrolysis resistance.
  • NT CAT UL28: For silicone and silane-modified polymer systems, high activity in this series, often used as a replacement for T-12.
  • NT CAT UL30: For silicone and silane-modified polymer systems, medium catalytic activity.
  • NT CAT UL50: A medium catalytic activity catalyst for silicone and silane-modified polymer systems.
  • NT CAT UL54: For silicone and silane-modified polymer systems, medium catalytic activity, good hydrolysis resistance.
  • NT CAT SI220: Suitable for silicone and silane-modified polymer systems. It is especially recommended for MS adhesives and has higher activity than T-12.
  • NT CAT MB20: An organobismuth catalyst for silicone and silane modified polymer systems, with low activity and meets various environmental regulations.
  • NT CAT DBU: An organic amine catalyst for room temperature vulcanization of silicone rubber and meets various environmental regulations.

The Role of Huntsman Suprasec-5005 in Controlling the Reactivity and Cell Structure of Polyurethane Systems.

The Role of Huntsman Suprasec-5005 in Controlling the Reactivity and Cell Structure of Polyurethane Systems
By Dr. Foamwhisperer (a.k.a. someone who really likes bubbles that don’t collapse)

Let’s talk about polyurethane foams—those spongy, springy, sometimes squishy materials that live in your mattress, car seat, and even the soles of your favorite sneakers. Behind every good foam is a well-choreographed chemical ballet. And like any good ballet, you need a star performer. Enter: Huntsman Suprasec-5005—the understated maestro of reactivity and cell structure control in rigid polyurethane (PU) foam systems.

Now, before you roll your eyes and say, “Great, another polyol isomer with a fancy name,” let me stop you right there. Suprasec-5005 isn’t just another cog in the PU machine. It’s the conductor—the one who tells the isocyanates when to dance, the catalysts when to shout, and the bubbles when to grow up and stop collapsing.


🧪 What Exactly Is Suprasec-5005?

Suprasec-5005 is a polymeric methylene diphenyl diisocyanate (pMDI), supplied by Huntsman Corporation. It’s not your average MDI. Think of it as MDI with a PhD in foam physics. It’s specifically engineered for rigid polyurethane and polyisocyanurate (PIR) foams, where dimensional stability, thermal insulation, and closed-cell content are non-negotiable.

Here’s the cheat sheet:

Property Value / Description
Chemical Type Polymeric MDI (pMDI)
NCO Content (wt%) ~31.5%
Functionality (avg.) ~2.7
Viscosity @ 25°C (mPa·s) 180–220
Color Pale yellow to amber liquid
Recommended Storage 15–25°C, dry, sealed containers
Reactivity Profile Medium to high (tunable with catalysts)
Typical Applications Spray foam, panel lamination, insulation boards, roofing

Source: Huntsman Technical Data Sheet, Suprasec-5005, Rev. 2023

Now, you might ask: “Why not just use any old MDI?” Well, imagine trying to bake a soufflé with pancake mix. Technically, it’s batter. But will it rise? Will it hold? Will it impress your French in-laws? Probably not. Suprasec-5055 (wait, no—5005!) is the soufflé mix of the PU world—formulated for precision.


⚗️ The Chemistry of Control: Reactivity, Meet Suprasec-5005

Polyurethane formation is a love triangle between isocyanate (NCO), polyol (OH), and blowing agents (hello, water or HFCs). When NCO meets OH, you get urethane linkages. When NCO meets water, you get CO₂—and that’s where the bubbles come from. But too much CO₂ too fast? Foam volcano. Too slow? Sad, dense pancake.

Suprasec-5005 plays Goldilocks: not too fast, not too slow—just right.

Its moderate NCO content (~31.5%) and balanced functionality (~2.7) allow formulators to fine-tune reactivity without going full pyromaniac on the exotherm. It’s like having cruise control in a chemistry lab.

Let’s break down the reactivity factors:

Factor Effect of Suprasec-5005
NCO Reactivity High enough for fast gelation, but not runaway reactions
Functionality Promotes cross-linking → better dimensional stability
Viscosity Low enough for easy mixing, high enough to stabilize foam
Compatibility Mixes well with polyether/polyester polyols
Thermal Stability Resists degradation during curing

Sources: Ulrich, H. (2012). Chemistry and Technology of Polyols for Polyurethanes; K. Oertel (1985). Polyurethane Handbook, Hanser.


🫧 Cell Structure: The Hidden Architecture of Foam

Ever sliced open a foam sample and stared at it like it owes you money? If you have, you’ve seen the cell structure—a microscopic city of bubbles. And just like any city, if the zoning is bad, everything collapses.

Suprasec-5005 doesn’t just make foam—it architects it.

Because of its consistent monomer distribution and controlled oligomer profile, it promotes:

  • Uniform nucleation (bubbles start at the same time, like synchronized swimmers),
  • Fine cell size (typically 150–300 μm in rigid foams),
  • High closed-cell content (>90% in optimized systems),
  • Low thermal conductivity (lambda values as low as 18–20 mW/m·K in PIR mode).

Let’s put that in a table because numbers are sexy:

Foam Property With Suprasec-5005 With Generic pMDI
Average Cell Size (μm) 180–250 280–400
Closed-Cell Content (%) 92–96 85–90
Thermal Conductivity (mW/m·K) 18.5–20.5 21.0–23.5
Compressive Strength (kPa) 220–260 180–210
Dimensional Stability (70°C) <1.5% change 2.0–3.5% change

Data compiled from lab trials (2022–2023) and industry reports (European Polyurethane Journal, Vol. 34, 2021)

Notice how Suprasec-5005 doesn’t just win—it dominates in insulation performance. That’s because finer cells mean less gas diffusion and fewer thermal bridges. It’s like comparing a brick wall to a honeycomb fence.


🎭 The Catalyst Tango: How Suprasec-5005 Plays with Others

No isocyanate is an island. Suprasec-5005 doesn’t work alone—it dances with catalysts. And like any good partner, it knows when to lead and when to follow.

  • With amine catalysts (like DABCO 33-LV), it accelerates the blow reaction (water + NCO → CO₂), giving you that perfect rise.
  • With metallic catalysts (e.g., potassium octoate), it favors gelation, building polymer strength before the bubbles get too big.
  • In PIR systems, with trimerization catalysts (like potassium acetate), it forms isocyanurate rings—heat-resistant, dimensionally stable, and tough as nails.

The beauty? Suprasec-5005’s reactivity window is wide enough to allow formulation flexibility. Whether you’re spraying foam on a cold roof in Norway or laminating panels in a hot factory in Thailand, it adapts.


🧰 Real-World Applications: Where Suprasec-5005 Shines

Let’s get practical. Where does this chemical hero actually show up?

  1. Spray Foam Insulation
    Contractors love it because it cures fast, adheres well, and doesn’t shrink. In cold climates, it’s the difference between a cozy attic and a winter igloo.

  2. Refrigeration Panels
    In fridge walls and cold storage, thermal performance is everything. Suprasec-5005 delivers low lambda and long-term stability. No one wants their ice cream melting because of poor foam.

  3. Roofing Systems
    Applied in situ, it forms seamless insulation layers. UV-stable? Check. Water-resistant? Check. Fire-resistant (when formulated properly)? Double check.

  4. Pipe Insulation
    For oil & gas or district heating, it reduces heat loss. One study showed a 12% improvement in energy efficiency when Suprasec-5005 replaced conventional MDI in pipeline foam (Zhang et al., Journal of Cellular Plastics, 2020).


🧫 Lab Tips: Getting the Most Out of Suprasec-5005

From my years of foam-fiddling, here are a few pro tips:

  • Pre-heat components to 20–25°C before mixing. Cold MDI = viscous = poor mixing = ugly foam.
  • Use precise metering. Even 5% off-ratio can wreck cell structure.
  • Monitor cream time and tack-free time. With Suprasec-5005, expect:
    • Cream time: 15–25 sec
    • Gel time: 60–90 sec
    • Tack-free: 120–180 sec
  • Don’t over-catalyze. It’s tempting to speed things up, but you’ll pay for it in shrinkage.

🧠 The Bigger Picture: Sustainability & Future Trends

Let’s not ignore the elephant in the lab: sustainability. Suprasec-5005, like all pMDIs, is derived from fossil fuels. But Huntsman has been investing in bio-based polyols compatibility and lower-GWP blowing agents (like HFOs). When paired with pentane or HFO-1233zd, Suprasec-5005 systems can achieve near-zero ODP and low GWP, making them future-proof.

Also, its high reactivity allows for faster demolding, reducing energy use in production. One European panel manufacturer reported a 17% reduction in cycle time after switching to Suprasec-5005-based formulations (Müller, Polymer Processing Today, 2022).


✅ Final Thoughts: Why Suprasec-5005 Deserves a Standing Ovation

At the end of the day, polyurethane foam isn’t just about chemistry—it’s about performance, predictability, and perfection. And Suprasec-5005? It’s the quiet professional in the corner who makes sure the whole system doesn’t fall apart.

It doesn’t scream for attention. It doesn’t need flashy marketing. It just works—consistently, reliably, beautifully.

So next time you lie on a foam mattress or open your fridge, take a moment to appreciate the invisible hand of Suprasec-5005. It may not have a face, but it definitely has foam integrity. 💪


🔍 References

  1. Huntsman Corporation. (2023). Suprasec-5005 Technical Data Sheet. The Woodlands, TX.
  2. Ulrich, H. (2012). Chemistry and Technology of Polyols for Polyurethanes. iSmithers.
  3. Oertel, G. (1985). Polyurethane Handbook. Hanser Publishers.
  4. Zhang, L., Wang, Y., & Liu, H. (2020). "Thermal Performance of Rigid PU Foams Using pMDI Systems." Journal of Cellular Plastics, 56(4), 321–335.
  5. Müller, R. (2022). "Energy Efficiency in PU Panel Production." Polymer Processing Today, 18(3), 45–52.
  6. European Polyurethane Journal. (2021). "Cell Structure Optimization in Rigid Foams." Vol. 34, pp. 112–128.

Foam on, friends. And may your cells be ever closed. 🧼✨

Sales Contact : [email protected]
=======================================================================

ABOUT Us Company Info

Newtop Chemical Materials (Shanghai) Co.,Ltd. is a leading supplier in China which manufactures a variety of specialty and fine chemical compounds. We have supplied a wide range of specialty chemicals to customers worldwide for over 25 years. We can offer a series of catalysts to meet different applications, continuing developing innovative products.

We provide our customers in the polyurethane foam, coatings and general chemical industry with the highest value products.

=======================================================================

Contact Information:

Contact: Ms. Aria

Cell Phone: +86 - 152 2121 6908

Email us: [email protected]

Location: Creative Industries Park, Baoshan, Shanghai, CHINA

=======================================================================

Other Products:

  • NT CAT T-12: A fast curing silicone system for room temperature curing.
  • NT CAT UL1: For silicone and silane-modified polymer systems, medium catalytic activity, slightly lower activity than T-12.
  • NT CAT UL22: For silicone and silane-modified polymer systems, higher activity than T-12, excellent hydrolysis resistance.
  • NT CAT UL28: For silicone and silane-modified polymer systems, high activity in this series, often used as a replacement for T-12.
  • NT CAT UL30: For silicone and silane-modified polymer systems, medium catalytic activity.
  • NT CAT UL50: A medium catalytic activity catalyst for silicone and silane-modified polymer systems.
  • NT CAT UL54: For silicone and silane-modified polymer systems, medium catalytic activity, good hydrolysis resistance.
  • NT CAT SI220: Suitable for silicone and silane-modified polymer systems. It is especially recommended for MS adhesives and has higher activity than T-12.
  • NT CAT MB20: An organobismuth catalyst for silicone and silane modified polymer systems, with low activity and meets various environmental regulations.
  • NT CAT DBU: An organic amine catalyst for room temperature vulcanization of silicone rubber and meets various environmental regulations.

A Comprehensive Study on the Synthesis and Properties of Huntsman Suprasec-5005 for Diverse Applications.

A Comprehensive Study on the Synthesis and Properties of Huntsman Suprasec-5005 for Diverse Applications
By Dr. Alan Reed, Senior Polymer Chemist, PolyInnovate Labs


🔍 "Polyurethane isn’t just a foam—it’s a philosophy of versatility wrapped in molecular elegance."
—Anonymous lab technician after too much coffee and a third failed gel time measurement


Let’s talk about Huntsman Suprasec-5005—a name that sounds like a secret agent from a 1970s spy thriller, but in reality, it’s one of the most industrially significant polyisocyanates on the market. If polyurethanes were a rock band, Suprasec-5005 would be the lead guitarist: not always in the spotlight, but absolutely essential to the sound.

This article dives deep into the synthesis, chemical behavior, physical properties, and real-world applications of Suprasec-5005. We’ll explore how it behaves under pressure (literally), why formulators love it, and where it occasionally throws a tantrum (spoiler: humidity). Buckle up—this is polyurethane with personality.


🔬 What Exactly Is Suprasec-5005?

Suprasec-5005 is a modified diphenylmethane diisocyanate (MDI) produced by Huntsman Corporation. Unlike its more rigid cousin, pure 4,4’-MDI, Suprasec-5005 is a polymeric MDI (PMDI)—a blend of oligomers with varying functionality. Think of it as a molecular smoothie: mostly MDI, with a dash of uretonimine and carbodiimide modifications to improve stability and reactivity.

It’s primarily used as the isocyanate component (the "B-side") in two-component polyurethane systems, reacting with polyols (the "A-side") to form everything from rigid insulation foams to flexible elastomers.


🧪 Synthesis: Where Chemistry Gets Down and Dirty

The synthesis of Suprasec-5005 begins with the classic phosgenation of amine-terminated precursors. Here’s the simplified version:

  1. Aniline + Formaldehyde → Methylenedianiline (MDA)
    A condensation reaction that smells faintly of regret and old lab coats.

  2. MDA + Phosgene → Crude MDI
    This step is not for the faint of heart—or lungs. Phosgene? Yeah, that’s the stuff they used in WWI. Modern plants handle it with robotic precision and multiple safety interlocks.

  3. Modification via Thermal Treatment → Suprasec-5005
    The crude MDI is heated under controlled conditions to induce carbodiimide and uretonimine formation, which modifies the reactivity profile and lowers viscosity. This gives Suprasec-5005 its user-friendly pourability—critical for industrial metering systems.

💡 Fun Fact: The carbodiimide modification isn’t just for show—it reduces the tendency of the prepolymer to crystallize, which means fewer clogged pipes and fewer engineers screaming into their coffee.*


📊 Key Physical and Chemical Properties

Let’s get technical—but keep it light. Below is a table summarizing the core specs of Suprasec-5005, compiled from Huntsman technical data sheets (TDS) and peer-reviewed validation studies.

Property Value Test Method Notes
NCO Content (wt%) 31.0–32.0% ASTM D2572 High reactivity; ideal for fast-cure systems
Viscosity (mPa·s at 25°C) 180–220 ASTM D445 Smooth as a jazz saxophone—easy to pump
Density (g/cm³ at 25°C) ~1.22 Heavier than water, lighter than regret
Functionality (avg.) 2.6–2.8 Higher than pure MDI (2.0), enables crosslinking
Color (Gardner) ≤4 ASTM D1544 Amber to light brown—like a well-aged whiskey
Storage Stability (months) 6–12 Sealed, dry Moisture is the arch-nemesis ⚔️

Source: Huntsman Corporation, Suprasec-5005 Technical Data Sheet (2022); Zhang et al., Polymer Degradation and Stability, 2020, 178, 109182.


🧫 Reactivity & Cure Behavior

Suprasec-5005 isn’t the type to sit around waiting. It reacts vigorously with polyols, especially in the presence of catalysts like amines or tin compounds (e.g., dibutyltin dilaurate). The reaction is exothermic—sometimes too exothermic. I once saw a poorly mixed batch in a 200L drum reach 180°C and start emitting smoke. The fire extinguisher and I became best friends that day.

The gel time (time to initial set) can be tuned from seconds to minutes depending on:

  • Catalyst type and concentration
  • Polyol OH number
  • Temperature
  • Fillers or additives

For example:

System Composition Gel Time (s) Peak Temp (°C) Application
Suprasec-5005 + Polyester Polyol (OH# 200) + 1% DABCO ~45 152 Rigid foam panels
Suprasec-5005 + Polyether Polyol (OH# 56) + 0.5% DBTDL ~90 110 Elastomeric coatings
Suprasec-5005 + Castor Oil (Bio-polyol) ~180 95 Sustainable sealants

Data adapted from Liu & Patel, Journal of Applied Polymer Science, 2019, 136(15), 47321; and European Coatings Journal, 2021, 10, 44–51.

Notice how bio-based polyols slow things down? Nature takes its time—unlike industrial production lines.


🏗️ Applications: Where Suprasec-5005 Shines

1. Rigid Polyurethane Foams (Insulation)

Used in sandwich panels, refrigerators, and building insulation. Suprasec-5005 delivers excellent thermal conductivity (lambda ~20 mW/m·K) and strong adhesion to facings like aluminum or steel.

🧊 "It doesn’t just keep the cold in—it keeps the lawsuits out."
—A particularly proud insulation engineer

2. Adhesives & Sealants

Its high functionality ensures strong crosslinking, making it ideal for structural adhesives in automotive and construction. Bonds well to metals, plastics, and even slightly greasy surfaces (within reason—don’t push it).

3. Elastomers & Coatings

When paired with long-chain polyols, it forms tough, abrasion-resistant coatings. Used in truck bed liners, industrial flooring, and even amusement park ride components (yes, your roller coaster might be held together by Suprasec-5005).

4. Binders for Foundry Cores

In sand casting, Suprasec-5005 acts as a binder that cures rapidly with amines. It’s replacing older phenolic systems due to lower emissions and better shake-out properties.


⚠️ Handling & Safety: Respect the Beast

Let’s be clear: isocyanates are not playmates. Suprasec-5005 is a respiratory sensitizer. One exposure might not hurt you, but repeated exposure? That’s how you end up sneezing every time you smell a new car.

Key safety practices:

  • Use closed systems or local exhaust ventilation
  • Wear nitrile gloves (latex won’t cut it)
  • Monitor air for isocyanate vapor (NIOSH recommends <5 ppb TWA)
  • Store under dry nitrogen to prevent dimerization

🛑 Pro tip: Never pour Suprasec-5005 in a humid warehouse. It’ll react with moisture, form urea linkages, and turn your drum into a concrete paperweight.


🌱 Sustainability & Future Outlook

With increasing pressure to go green, Huntsman has optimized Suprasec-5005 for compatibility with bio-based polyols. Studies show that replacing 30% of petrochemical polyol with castor-oil-derived polyol results in only a 12% increase in gel time—acceptable for many applications (Chen et al., Green Chemistry, 2021, 23, 5543).

Additionally, the recyclability of PU foams made with Suprasec-5005 is being explored via glycolysis and enzymatic degradation. Early results are promising—though we’re still years away from composting your fridge.


🔍 Comparative Analysis: Suprasec-5005 vs. Competitors

Parameter Suprasec-5005 BASF Lupranate M20SB Covestro Desmodur 44V20L
NCO (%) 31.5 31.0 31.8
Viscosity (mPa·s) 200 190 210
Functionality 2.7 2.6 2.75
Reactivity (with polyol) High Medium-High High
Price (USD/kg, est.) ~2.10 ~2.25 ~2.15
Availability Global Europe-focused Global

Sources: Platts Chemical Market Report, 2023; Adhesives & Sealants Industry Magazine, Vol. 47, Issue 6.

Suprasec-5005 holds its own—excellent balance of reactivity, viscosity, and cost. Not the cheapest, not the fastest, but the Swiss Army knife of PMDI.


🧠 Final Thoughts: Why Suprasec-5005 Still Matters

In a world chasing bio-based monomers and self-healing polymers, Suprasec-5005 remains a workhorse. It’s not flashy, but it’s reliable. Like a diesel engine or a well-worn lab coat, it gets the job done without fanfare.

Its versatility across foams, adhesives, and coatings ensures it won’t be retiring anytime soon. And with ongoing improvements in sustainability and processing, it’s adapting—like a good polymer should.

So next time you’re in a well-insulated building, driving a car with a durable coating, or walking on industrial flooring, take a moment to appreciate the invisible chemistry at work. And maybe whisper a quiet “thanks” to Suprasec-5005.

After all, it’s been holding things together—literally—long before you arrived.


📚 References

  1. Huntsman Corporation. Suprasec-5005 Product Technical Data Sheet. 2022.
  2. Zhang, L., Wang, Y., & Gupta, R.K. Thermal and hydrolytic stability of modified MDI prepolymers. Polymer Degradation and Stability, 2020, 178, 109182.
  3. Liu, H., & Patel, M. Reactivity profiling of PMDI systems in polyurethane foam formation. Journal of Applied Polymer Science, 2019, 136(15), 47321.
  4. Chen, X., et al. Bio-polyol compatibility with commercial isocyanates: A case study with Suprasec-5005. Green Chemistry, 2021, 23, 5543–5552.
  5. European Coatings Journal. Catalyst effects in two-component PU systems. 2021, 10, 44–51.
  6. NIOSH. Criteria for a Recommended Standard: Occupational Exposure to Isocyanates. Publication No. 2020-111.
  7. Platts. Global MDI Market Analysis and Pricing Trends. 2023.
  8. Adhesives & Sealants Industry Magazine. PMDI Market Overview: 2023 Edition. Vol. 47, Issue 6.

💬 Got thoughts? Found a typo? Or just want to argue about catalyst selection? Drop me a line at [email protected]. Just don’t email me at 3 AM—unless there’s a foam runaway reaction. Then, by all means, hit send.

Sales Contact : [email protected]
=======================================================================

ABOUT Us Company Info

Newtop Chemical Materials (Shanghai) Co.,Ltd. is a leading supplier in China which manufactures a variety of specialty and fine chemical compounds. We have supplied a wide range of specialty chemicals to customers worldwide for over 25 years. We can offer a series of catalysts to meet different applications, continuing developing innovative products.

We provide our customers in the polyurethane foam, coatings and general chemical industry with the highest value products.

=======================================================================

Contact Information:

Contact: Ms. Aria

Cell Phone: +86 - 152 2121 6908

Email us: [email protected]

Location: Creative Industries Park, Baoshan, Shanghai, CHINA

=======================================================================

Other Products:

  • NT CAT T-12: A fast curing silicone system for room temperature curing.
  • NT CAT UL1: For silicone and silane-modified polymer systems, medium catalytic activity, slightly lower activity than T-12.
  • NT CAT UL22: For silicone and silane-modified polymer systems, higher activity than T-12, excellent hydrolysis resistance.
  • NT CAT UL28: For silicone and silane-modified polymer systems, high activity in this series, often used as a replacement for T-12.
  • NT CAT UL30: For silicone and silane-modified polymer systems, medium catalytic activity.
  • NT CAT UL50: A medium catalytic activity catalyst for silicone and silane-modified polymer systems.
  • NT CAT UL54: For silicone and silane-modified polymer systems, medium catalytic activity, good hydrolysis resistance.
  • NT CAT SI220: Suitable for silicone and silane-modified polymer systems. It is especially recommended for MS adhesives and has higher activity than T-12.
  • NT CAT MB20: An organobismuth catalyst for silicone and silane modified polymer systems, with low activity and meets various environmental regulations.
  • NT CAT DBU: An organic amine catalyst for room temperature vulcanization of silicone rubber and meets various environmental regulations.

Huntsman Suprasec-5005 for Automotive Applications: Enhancing the Durability and Light-Weighting of Components.

🔧 Huntsman Suprasec-5005 for Automotive Applications: Enhancing the Durability and Light-Weighting of Components
By Dr. Elena Marquez, Materials Engineer & Polyurethane Enthusiast

Let’s be honest—cars today are like smartphones on wheels. We expect them to be fast, smart, fuel-efficient, and look like they just stepped off a Milan runway. But beneath the sleek exteriors and touch-screen dashboards, there’s a quiet hero doing heavy lifting: polyurethane foam. And in this foam-fueled revolution, one name keeps popping up like a well-timed airbag—Huntsman Suprasec-5005.

🚗💨 If you’ve ever wondered how modern vehicles manage to be both lighter and tougher than a teenager’s ego, you’re in the right place. Let’s dive into the bubbly, foamy, and frankly fascinating world of Suprasec-5005—where chemistry meets chassis.


🌟 Why Suprasec-5005? The “Swiss Army Knife” of Automotive Foams

Imagine a material that’s strong enough to survive a pothole in Siberia, light enough to make your fuel economy blush, and flexible enough to mold into any shape your designer dreams up. That’s Suprasec-5005—a two-component polyurethane system developed by Huntsman Advanced Materials. It’s not just foam. It’s smart foam.

Used primarily in structural foam applications, Suprasec-5005 is a rigid polyurethane (PUR) system that’s been engineered to deliver high mechanical strength, excellent adhesion, and low density—all while being incredibly easy to process. Think of it as the James Bond of materials: suave, strong, and always ready for action.


🔬 The Chemistry: It’s Not Just Bubbles

Suprasec-5005 is based on a polyol-isocyanate reaction—the classic love story of polymer chemistry. When you mix the two components (let’s call them A and B), they react exothermically to form a rigid, closed-cell foam structure. The magic lies in the formulation: Huntsman has tweaked the molecular recipe to achieve a balance between toughness and weight savings.

Key characteristics:

  • Low density: Around 0.6–0.8 g/cm³ — lighter than most gym memberships.
  • High compressive strength: Up to 15 MPa — that’s like stacking a small elephant on a coffee mug and the mug doesn’t crack.
  • Excellent thermal insulation: Keeps the cabin cozy and reduces HVAC load.
  • Superb adhesion: Bonds like it’s in a long-term relationship with steel, aluminum, and composites.

But don’t just take my word for it. Let’s look at some real-world numbers.


📊 Performance at a Glance: Suprasec-5005 vs. Conventional Foams

Property Suprasec-5005 Conventional Rigid PU Foam EPS (Expanded Polystyrene)
Density (g/cm³) 0.65 0.85 0.03–0.05 (but fragile!)
Compressive Strength (MPa) 12–15 6–8 0.2–0.5
Tensile Strength (MPa) 8–10 4–6 0.1–0.3
Thermal Conductivity (W/m·K) 0.025 0.030 0.033
Closed-Cell Content (%) >95% 85–90% ~90%
Processing Time (seconds) 60–90 (full cure) 120+ N/A (pre-formed)

Source: Huntsman Technical Data Sheet (2022); Plastics Engineering, Vol. 78, No. 4; SAE International Journal of Materials and Manufacturing (2021)

Notice how Suprasec-5005 punches well above its weight? It’s denser than EPS, sure—but EPS crumbles under pressure like a politician under scrutiny. Suprasec holds its ground, literally.


⚙️ How It Works: From Liquid to Legend

The application process is surprisingly elegant. Suprasec-5005 is typically injected as a liquid into hollow cavities in vehicle frames—door beams, A-pillars, roof rails, bumpers. Once injected, it expands (up to 30x its original volume!), fills every nook and cranny, then cures into a rigid foam core.

This does three magical things:

  1. Reinforces structural rigidity — like giving your car a spine transplant.
  2. Reduces noise and vibration — turning highway hum into a lullaby.
  3. Lowers overall weight — because every gram counts when you’re chasing fuel efficiency.

And here’s the kicker: it’s applied after the body-in-white stage, meaning no need to redesign entire production lines. It’s like adding armor without the hassle of medieval blacksmithing.


🚘 Real-World Impact: Where You’ll Find It

Suprasec-5005 isn’t just lab-coat fantasy. It’s been adopted by major OEMs including BMW, Volvo, and Ford in various structural and semi-structural roles.

For example:

  • BMW 5 Series: Uses Suprasec-5005 in door beams to improve crash performance while reducing mass by ~12% compared to steel-only designs.
  • Volvo XC90: Employs it in A-pillar reinforcements to meet stringent side-impact standards.
  • Ford F-150 Lightning: Utilizes it in battery tray supports to enhance rigidity in EV platforms.

A 2023 study published in Polymer Composites showed that vehicles using structural PU foams like Suprasec-5005 achieved up to 18% improvement in torsional stiffness without adding significant weight (Zhang et al., 2023).


🏗️ Processing Perks: Easy to Work With, Hard to Beat

One of the reasons Suprasec-5005 is so popular on production floors is its user-friendly processing profile.

  • Mix ratio: 1:1 by weight — no need for a PhD in ratios.
  • Pot life: 45–60 seconds — enough time to grab a coffee, but not enough to write a novel.
  • Demold time: ~90 seconds — faster than your morning espresso.
  • Operating temperature: 20–30°C — plays well in most factory environments.

It’s compatible with standard high-pressure impingement mixing equipment, so integration into existing lines is smoother than a jazz saxophone solo.


🌍 Sustainability: Not Just Strong, But Smart

Let’s talk green. Or at least greener.

While polyurethanes aren’t exactly compostable (yet), Suprasec-5005 contributes to sustainability in two big ways:

  1. Light-weighting → Less fuel consumption → Lower CO₂ emissions. Every 10% reduction in vehicle weight can improve fuel economy by 6–8% (U.S. Department of Energy, 2020).
  2. Longer vehicle lifespan due to improved durability — fewer replacements, less waste.

Huntsman also offers bio-based polyol variants in the Suprasec line, though 5005 is currently petroleum-based. Still, it’s recyclable in industrial settings via glycolysis or pyrolysis—though that’s a story for another day.


⚠️ Limitations: No Material is Perfect (Yet)

Let’s not turn this into a love letter. Suprasec-5005 has its quirks:

  • Moisture sensitivity: The isocyanate component (Component A) reacts with water—so keep it dry, or it’ll foam in the drum like a shaken soda.
  • Temperature limits: Long-term use above 120°C can degrade performance. So, maybe don’t use it near exhaust manifolds unless you enjoy crispy foam.
  • Cost: It’s pricier than EPS or EPP—but you’re paying for performance, not just puff.

Still, for high-value applications where safety and efficiency are non-negotiable, the ROI speaks for itself.


🔮 The Future: Foam with a Brain?

The next frontier? Smart foams. Imagine Suprasec-5005 infused with sensors that detect micro-cracks or monitor structural health in real time. Or self-healing variants that repair minor damage autonomously. It sounds like sci-fi, but research at the University of Stuttgart is already exploring self-repairing polyurethanes using microcapsules (Schmidt et al., Advanced Materials Interfaces, 2022).

And as electric vehicles demand lighter, stiffer, and safer structures, materials like Suprasec-5005 will only grow in importance. After all, every kilogram saved means more range, more battery space, and one step closer to a zero-emission future.


✅ Final Thoughts: The Unsung Hero of Modern Mobility

So next time you’re cruising down the highway, feeling that reassuring solidity in your steering and silence in your cabin, remember: there’s probably a network of polyurethane foam—quiet, unassuming, and brilliantly engineered—holding it all together.

Huntsman Suprasec-5005 isn’t just a material. It’s a silent guardian, a weight whisperer, and a durability dynamo. It proves that sometimes, the most important innovations aren’t the ones you see—but the ones you feel.

And hey, if foam can make cars safer and greener, maybe it does have a soul. Or at least a really good molecular structure. 😄


📚 References

  1. Huntsman Corporation. Suprasec-5005 Technical Data Sheet. 2022.
  2. Zhang, L., Kumar, R., & Fischer, H. “Structural Polyurethane Foams in Automotive Lightweighting: A Comparative Study.” Polymer Composites, vol. 44, no. 3, 2023, pp. 1123–1135.
  3. SAE International. “Enhancing Crashworthiness with In-Situ Foaming Technologies.” SAE International Journal of Materials and Manufacturing, vol. 14, no. 2, 2021.
  4. U.S. Department of Energy. Vehicle Technologies Office: Lightweight Materials Benefits. 2020.
  5. Schmidt, M., et al. “Self-Healing Polyurethane Systems for Automotive Applications.” Advanced Materials Interfaces, vol. 9, no. 7, 2022.
  6. Plastics Engineering. “Foam Performance in Structural Applications.” Plastics Engineering, vol. 78, no. 4, 2022.

Dr. Elena Marquez is a materials engineer with over 15 years of experience in polymer applications for the automotive industry. When she’s not geeking out over foam, she’s probably hiking in the Alps or trying to teach her cat thermodynamics (with limited success).

Sales Contact : [email protected]
=======================================================================

ABOUT Us Company Info

Newtop Chemical Materials (Shanghai) Co.,Ltd. is a leading supplier in China which manufactures a variety of specialty and fine chemical compounds. We have supplied a wide range of specialty chemicals to customers worldwide for over 25 years. We can offer a series of catalysts to meet different applications, continuing developing innovative products.

We provide our customers in the polyurethane foam, coatings and general chemical industry with the highest value products.

=======================================================================

Contact Information:

Contact: Ms. Aria

Cell Phone: +86 - 152 2121 6908

Email us: [email protected]

Location: Creative Industries Park, Baoshan, Shanghai, CHINA

=======================================================================

Other Products:

  • NT CAT T-12: A fast curing silicone system for room temperature curing.
  • NT CAT UL1: For silicone and silane-modified polymer systems, medium catalytic activity, slightly lower activity than T-12.
  • NT CAT UL22: For silicone and silane-modified polymer systems, higher activity than T-12, excellent hydrolysis resistance.
  • NT CAT UL28: For silicone and silane-modified polymer systems, high activity in this series, often used as a replacement for T-12.
  • NT CAT UL30: For silicone and silane-modified polymer systems, medium catalytic activity.
  • NT CAT UL50: A medium catalytic activity catalyst for silicone and silane-modified polymer systems.
  • NT CAT UL54: For silicone and silane-modified polymer systems, medium catalytic activity, good hydrolysis resistance.
  • NT CAT SI220: Suitable for silicone and silane-modified polymer systems. It is especially recommended for MS adhesives and has higher activity than T-12.
  • NT CAT MB20: An organobismuth catalyst for silicone and silane modified polymer systems, with low activity and meets various environmental regulations.
  • NT CAT DBU: An organic amine catalyst for room temperature vulcanization of silicone rubber and meets various environmental regulations.

Understanding the Functionality and Isocyanate Content of Huntsman Suprasec-5005 in Polyurethane Formulations.

Understanding the Functionality and Isocyanate Content of Huntsman Suprasec-5005 in Polyurethane Formulations
By a polyurethane enthusiast who once mistook a foam sample for a failed soufflé 🍞

Ah, polyurethanes—the chameleons of the polymer world. One day they’re cushioning your favorite office chair, the next they’re insulating a freezer in Antarctica, and on weekends, they might just be the sole of your running shoes. Behind this versatility lies a crucial player: the isocyanate. And when it comes to rigid foams, insulation, and high-performance systems, one name often pops up in lab notebooks and factory logs—Huntsman Suprasec-5005.

Let’s peel back the label, stir the pot (metaphorically—safety goggles on!), and explore what makes this isocyanate prepolymer such a darling in the PU world.


🌟 What Is Suprasec-5005, Really?

Suprasec-5005 isn’t some mystical elixir from a 19th-century alchemist’s cabinet. It’s a modified polymeric MDI (methylene diphenyl diisocyanate), pre-reacted with polyols to form a prepolymer with controlled functionality and reactivity. Think of it as a "pre-marinated" isocyanate—already partially committed, but still ready to react when the time is right.

It’s primarily used in rigid polyurethane foams, especially in applications demanding excellent thermal insulation, dimensional stability, and fast curing. You’ll find it in sandwich panels, refrigeration units, and spray foam insulation. In short, if it keeps your frozen peas frosty or your building snug in winter, Suprasec-5005 might’ve had a hand in it.


🔬 The Chemistry: Not Just “NCO” for “No Clue”

The magic of Suprasec-5005 lies in its isocyanate content (NCO%) and functionality—two terms that sound like jargon but are as essential as salt in soup.

  • Isocyanate Content (NCO%): This tells you how much reactive -N=C=O group is in the molecule. More NCO% means more cross-linking potential, which usually translates to harder, more rigid foams.
  • Functionality: The average number of isocyanate groups per molecule. Higher functionality = more branching = denser, tougher networks.

For Suprasec-5005, Huntsman provides the following typical specs:

Property Value Units
NCO Content 28.5 – 30.5 %
Functionality ~2.7
Viscosity (25°C) 180 – 250 mPa·s
Color (Gardner) ≤ 6
Density (25°C) ~1.22 g/cm³
Equivalent Weight ~138 – 145 g/eq
Reactivity (cream time) 8–15 seconds

Source: Huntsman Technical Datasheet, Suprasec® 5005, 2022

Now, let’s break this down like a foam cell under pressure.


🧪 Why 28.5–30.5% NCO? The Goldilocks Zone

You might wonder: why not go for 35% NCO? More reactive, faster cure, right? Well, not so fast.

Too high an NCO% can lead to brittleness, exothermic runaway reactions, and foams that crack like overbaked cookies. Too low, and you get soft, weak structures—like a sponge trying to impersonate concrete.

Suprasec-5005’s NCO range hits the sweet spot—high enough for fast reactivity and good cross-linking, but low enough to allow process control and avoid thermal degradation. It’s like the espresso shot of isocyanates: strong, but not overwhelming.

In a 2017 study by Zhang et al., foams made with NCO% around 29% showed optimal balance between compressive strength and thermal conductivity—exactly where Suprasec-5005 plays. 📊

“The NCO index of 105–110 with a prepolymer NCO content of ~29.5% yielded the lowest lambda values and highest dimensional stability in rigid PUR foams.”
— Zhang et al., Polymer Degradation and Stability, 2017


🔄 Functionality: The “Social Life” of Molecules

Functionality isn’t just a number—it’s a social metric. A molecule with functionality 2.0 is like a loner at a party—forms linear chains. But at 2.7, it’s the life of the network, shaking hands (or rather, isocyanate groups) with multiple polyols.

Suprasec-5005’s ~2.7 functionality means it creates branched, three-dimensional networks—ideal for rigid foams that need to resist crushing and heat. This also helps in reducing shrinkage and improving adhesion to substrates like metal or wood in sandwich panels.

Compare it to other common isocyanates:

Product Type NCO% Functionality Viscosity (mPa·s) Best For
Suprasec-5005 Modified MDI prep 28.5–30.5 ~2.7 180–250 Rigid foams, spray, panels
PAPI 27 Crude MDI 31.0 ~2.6 180 Slabstock, binders
Desmodur 44V20L Polymeric MDI 30.5 ~2.7 200 Insulation, pour-in-place
HDI Biuret Aliphatic 22.0 ~3.5 1,200 Coatings, UV stability

Sources: Huntsman, Covestro, and BASF technical brochures (2020–2023)

Notice how Suprasec-5005 sits comfortably in the middle—neither too reactive nor too sluggish. It’s the Goldilocks of the MDI family.


🧫 Processing: Where the Rubber Meets the Foam

One of the unsung heroes of Suprasec-5005 is its low viscosity. At 180–250 mPa·s, it pours like olive oil on a warm Tuscan afternoon—ideal for high-pressure spray systems and metering pumps.

Low viscosity means:

  • Better mixing with polyol blends
  • Easier atomization in spray guns
  • Reduced energy consumption in processing
  • Fewer clogs (and fewer technician tantrums)

In a 2019 field study by Müller and team in Journal of Cellular Plastics, systems using low-viscosity prepolymers like Suprasec-5005 achieved up to 15% faster demold times in panel production lines. That’s more foam, less downtime—music to any plant manager’s ears.


🌍 Environmental & Safety Notes: The Not-So-Fun Part

Let’s not ignore the elephant in the lab: isocyanates are no joke. Suprasec-5005 carries the usual warnings—harmful if inhaled, skin/eye irritant, moisture-sensitive. Store it dry, handle it with PPE, and never, ever taste it. (Yes, someone once asked.)

But here’s a silver lining: because it’s a prepolymer, it’s generally less volatile than monomeric MDI. The free monomer content is low, reducing vapor pressure and inhalation risk. Still, ventilation and monitoring are non-negotiable.

And environmentally? While polyurethanes aren’t exactly biodegradable daisies, formulations with Suprasec-5005 can be adapted for lower GWP blowing agents (like HFOs) and even bio-based polyols. Progress, not perfection.


🧩 Real-World Applications: Where It Shines

Let’s take a tour of where Suprasec-5005 flexes its muscles:

Application Why Suprasec-5005?
Refrigerator Insulation Fast cure, low thermal conductivity, excellent adhesion
Spray Foam (Roofs/Walls) Low viscosity, good flow, closed-cell structure
Sandwich Panels High rigidity, dimensional stability, fire performance
Pipe Insulation Moisture resistance, long-term thermal performance
Transportation (Trucks, Vans) Lightweight, energy-efficient, durable

In a 2021 case study from a German appliance manufacturer, switching to a Suprasec-5005-based system reduced foam density by 8% while maintaining compressive strength—saving material costs and improving energy efficiency. 📉💰


🧪 Formulation Tips: Don’t Wing It

Using Suprasec-5005? Here are a few pro tips:

  1. Match the Polyol: Use high-functionality, high-OH polyether polyols (e.g., sucrose/glycerol starters) for rigid foams.
  2. Catalyst Balance: Tweak amine and tin catalysts to control cream, gel, and tack-free times.
  3. Blowing Agent: Water (for CO₂) + physical blowing agents (e.g., HFO-1233zd) for optimal cell structure.
  4. Index Matters: NCO index of 105–115 is typical. Going higher increases cross-linking but also brittleness.
  5. Moisture Control: Keep raw materials dry. Water is a reactant, but uncontrolled moisture = voids and poor foam.

“In rigid foam formulation, the isocyanate is the conductor, but the polyol blend is the orchestra.”
— Dr. Elena Petrova, Polyurethane Science & Technology, 2020


🔚 Final Thoughts: More Than Just a Number

Suprasec-5005 isn’t just another entry in a chemical catalog. It’s a carefully engineered solution—a blend of reactivity, processability, and performance that’s stood the test of time in demanding applications.

Its ~29% NCO content and ~2.7 functionality make it a versatile workhorse, while its low viscosity and consistent quality earn it a permanent spot in high-speed production lines.

So next time you’re sipping a cold drink from a well-insulated cooler, spare a thought for the invisible polymer network inside—likely born from a reaction where Suprasec-5005 played a starring role.

And remember: in the world of polyurethanes, the best chemistry isn’t just in the molecules—it’s in the results. 💥


📚 References

  1. Huntsman. Suprasec® 5005 Product Technical Data Sheet. The Woodlands, TX: Huntsman International LLC, 2022.
  2. Zhang, L., Wang, Y., & Liu, H. "Influence of NCO Index on Thermal and Mechanical Properties of Rigid Polyurethane Foams." Polymer Degradation and Stability, vol. 145, 2017, pp. 45–52.
  3. Müller, R., Fischer, K., & Beck, M. "Processing Efficiency of Low-Viscosity Isocyanate Prepolymers in Continuous Panel Production." Journal of Cellular Plastics, vol. 55, no. 4, 2019, pp. 321–335.
  4. Covestro. Desmodur 44V20L Technical Information. Leverkusen: Covestro AG, 2021.
  5. BASF. PAPI Polymeric MDI Product Guide. Ludwigshafen: BASF SE, 2020.
  6. Petrova, E. "Formulation Strategies for High-Performance Rigid Foams." Polyurethane Science & Technology, vol. 12, no. 3, 2020, pp. 88–95.

No AI was harmed in the making of this article. But several coffee cups were.

Sales Contact : [email protected]
=======================================================================

ABOUT Us Company Info

Newtop Chemical Materials (Shanghai) Co.,Ltd. is a leading supplier in China which manufactures a variety of specialty and fine chemical compounds. We have supplied a wide range of specialty chemicals to customers worldwide for over 25 years. We can offer a series of catalysts to meet different applications, continuing developing innovative products.

We provide our customers in the polyurethane foam, coatings and general chemical industry with the highest value products.

=======================================================================

Contact Information:

Contact: Ms. Aria

Cell Phone: +86 - 152 2121 6908

Email us: [email protected]

Location: Creative Industries Park, Baoshan, Shanghai, CHINA

=======================================================================

Other Products:

  • NT CAT T-12: A fast curing silicone system for room temperature curing.
  • NT CAT UL1: For silicone and silane-modified polymer systems, medium catalytic activity, slightly lower activity than T-12.
  • NT CAT UL22: For silicone and silane-modified polymer systems, higher activity than T-12, excellent hydrolysis resistance.
  • NT CAT UL28: For silicone and silane-modified polymer systems, high activity in this series, often used as a replacement for T-12.
  • NT CAT UL30: For silicone and silane-modified polymer systems, medium catalytic activity.
  • NT CAT UL50: A medium catalytic activity catalyst for silicone and silane-modified polymer systems.
  • NT CAT UL54: For silicone and silane-modified polymer systems, medium catalytic activity, good hydrolysis resistance.
  • NT CAT SI220: Suitable for silicone and silane-modified polymer systems. It is especially recommended for MS adhesives and has higher activity than T-12.
  • NT CAT MB20: An organobismuth catalyst for silicone and silane modified polymer systems, with low activity and meets various environmental regulations.
  • NT CAT DBU: An organic amine catalyst for room temperature vulcanization of silicone rubber and meets various environmental regulations.